Composition and method to form a composite core material
A composite core material and methods for making same are disclosed herein. The composite core material comprises mineral filler discontinuous portions disposed in a continuous encapsulating resin. Further, the method for forming a composite core material comprises the steps of forming a mixture comprising mineral filler, an encapsulating prepolymer, and a polymerization catalyst; disposing the mixture onto a moving belt; and polymerizing said encapsulating prepolymer to form a composite core material comprising mineral filler discontinuous portions disposed in a continuous encapsulating resin.
1. A method to form a composite core material, comprising
polymerizing an encapsulating prepolymer of a first mixture to form a sheet of composite material comprising calcium sulfate or calcium sulfate hydrate discontinuous portions disposed in a continuous encapsulating resin, wherein the first mixture is comprised of (a) one or more of a calcium sulfate and a hydrate of the calcium sulfate; (b) the encapsulating prepolymer; and (c) a first polymerization catalyst;
cutting the sheet of composite material into a plurality of pieces of the composite material;
applying a gel coat having a second polymerization catalyst to a mold and drying the gel coat without completely curing the gel coat;
forming a second mixture to create a laminate, the second mixture comprising: (a) one or more of a calcium sulfate and a hydrate of the calcium sulfate; (b) an encapsulating prepolymer; (c) a third polymerization catalyst; and (d) a plurality of fiberglass pieces;
applying a first layer of the laminate to the dried gel coat;
without curing the first layer of the laminate applied to the dried gel coat, applying at least a portion of the plurality of pieces of the composite material to the first layer of the laminate;
applying a second layer of the laminate to the portion of the plurality of pieces of the composite material, which is atop the first layer of the laminate; and
curing the second layer of the laminate to enclose the mold.
2. The method of claim 1 , wherein the first polymerization catalyst of the first mixture is comprised of 2-Butanone peroxide.
3. The method of claim 1 , wherein polymerizing the encapsulating prepolymer of the first mixture includes curing the one or more of the calcium sulfate and the hydrate of the calcium sulfate, the encapsulating prepolymer and the first polymerization catalyst of the first mixture.
4. The method of claim 1 , wherein the encapsulating prepolymer of the first mixture is selected from the group consisting of polyester resins, vinyl ester resins, fire retardant resins and any combinations thereof.
5. The method of claim 1 , wherein the calcium sulfate hydrate of the first mixture is selected from the group consisting of calcium sulfate hemihydrate having a formula of CaSO4 ·(nH20), wherein n is equal to or greater than 0.5 and equal to or less than 0.8; and calcium sulfate dihydrate having a formula of CaSO4·2H20.
6. The method of claim 1 , wherein the sheet of composite core material has a thickness of 0.0625 inches to 1 inch.
7. The method of claim 1 , wherein, prior to polymerizing the encapsulating prepolymer of the first mixture, the method further comprises:
forming the first mixture, which is comprised of: (a) the one or more of the calcium sulfate and the hydrate of the calcium sulfate; (b) the encapsulating prepolymer; and (c) the first polymerization catalyst; and
disposing the first mixture onto a heated moving belt.
8. The method of claim 7 , wherein the heated moving belt comprises a mesh assembly.
9. The method of claim 1 , wherein the encapsulating prepolymer of the second mixture is selected from the group consisting of polyester resins, vinyl ester resins, fire retardant resins and any combinations thereof.
10. The method of claim 1 , wherein applying the gel coat to the mold comprises spraying the gel coat on the mold.
11. The method of claim 1 , wherein the applying the gel coat to the mold comprises brushing the gel coat on the mold.
12. The method of claim 1 , wherein the gel coating is pigmented.