Emulsions including polymers, treatment fluids including emulsions, and methods for treating subterranean formations
View Patent ↗Emulsions, treatment fluids and methods for treating subterranean formations are provided, wherein the emulsions comprise water, a water-immiscible liquid, one or more polymers, and an inverting surfactant composition comprising one or more surfactants selected from the group consisting of ethoxylated amine compounds, ethoxylated fatty acid compounds, and alkyl polyethyleneglycol ether carboxylic acid compounds, alkyl polyglycol ether carboxylic acid compounds, and salts or esters thereof. The emulsions are particularly suitable for use in brine.
1 . A treatment fluid comprising an emulsion, the emulsion comprising:
water;
a water-immiscible liquid;
about 10% to about 80% one or more polymers by weight of the emulsion; and
about 0.1% to about 5% of an inverting surfactant composition by weight of the emulsion, said inverting surfactant composition comprising one or more surfactants selected from the group consisting of alkyl polyethyleneglycol ether carboxylic acid compounds.
2 . The treatment fluid of claim 1 , wherein the inverting surfactant composition further comprises at least one surfactant selected from the group consisting of ethoxylated amine compounds and salts or esters thereof.
3 . The treatment fluid of claim 2 , wherein the ethoxylated amine compound is present in an amount of from about 5 wt % to about 75 wt % of the inverting surfactant composition.
4 . The treatment fluid of claim 2 , wherein the ethoxylated amine compounds are compounds of Formula I:
wherein R 1 is H, aryl, or C(═O)-aryl; and X and Y are each independently 1-20.
5 . The treatment fluid of claim 2 , wherein the ethoxylated amine compound is polyoxyethylene tallow amine.
6 . The treatment fluid of claim 2 , wherein the inverting surfactant composition comprises about 5 to about 95 wt % one or more ethoxylated amine compounds, and about 5 to about 95 wt % one or more alkyl polyethyleneglycol ether carboxylic acid compounds, alkyl polyglycol ether carboxylic acid compounds, and salts or esters thereof.
7 . The treatment fluid of claim 1 , wherein the one or more of the polymers is an acrylamide-containing polymer.
8 . The treatment fluid of claim 1 , wherein the one or more polymers comprises acrylamide or partially hydrolyzed acrylamide and one or more anionic monomers.
9 . The treatment fluid of claim 1 , wherein the one or more polymers comprises acrylamide or partially hydrolyzed acrylamide and one or more cationic monomers.
10 . The treatment fluid of claim 1 , wherein the one or more polymers comprises acrylamide or partially hydrolyzed acrylamide and one or more monomers selected from the group consisting of acrylic acid and salts thereof.
11 . The treatment fluid of claim 1 , wherein the one or more polymers comprises acrylamide or partially hydrolyzed acrylamide, and acryloyloxyethyltrimethylammonium chloride.
12 . The treatment fluid of claim 1 , wherein the alkyl polyethyleneglycol ether carboxylic acid compounds is glycolic acid ethoxylate oleyl ether.
13 . The treatment fluid of claim 1 , wherein the inverting surfactant composition comprises or consists essentially of about 5 to about 95 wt % one or more alkyl polyethyleneglycol ether carboxylic acid compounds, alkyl polyglycol ether carboxylic acid compounds, and salts or esters thereof; and about 5 to about 75 wt % one or more ethoxylated fatty acid compounds.
14 . The treatment fluid of claim 1 , wherein the one or more polymers are present in the treatment fluid in an amount of about 10% to about 35% by weight of the emulsion.
15 . The treatment fluid of claim 14 , further comprising a proppant.
16 . A method of treating a subterranean formation, comprising: providing a treatment fluid of claim 1 ; and introducing the treatment fluid into a subterranean formation.
17 . A method of fracturing a subterranean formation, comprising:
(i) providing a treatment fluid of claim 1 ;
(ii) mixing the emulsion with additional water or brine to form a treatment fluid, wherein the one or more polymers are present in the treatment fluid in an amount of about 0.01% to about 1% by weight of the treatment fluid; and
introducing the treatment fluid into a subterranean formation at or above a pressure sufficient to create one or more fractures in the subterranean formation.
18 . The method of claim 16 , wherein the treatment fluid comprises brine.
19 . The method of claim 16 , further comprising adding a proppant.