Hybrid carbon dioxide removal systems
In a general aspect, a carbon dioxide removal system is presented. In some cases, a gas-liquid contactor is wetted with an alkaline capture solution. A first flow from a first gaseous feed including CO 2 from a first source is directed to interact with the alkaline capture solution in the gas-liquid contactor, which forms a first CO 2 -rich alkaline capture solution. A second flow from a second gaseous feed including CO 2 from a second, distinct source is directed to interact with the first CO 2 -rich alkaline capture solution, which forms a second CO 2 -rich alkaline capture solution. In some cases, the second flow is independent of the first gaseous feed, and a concentration of CO 2 in the second CO 2 -rich alkaline capture solution is higher than a concentration of CO 2 in the first CO 2 -rich alkaline capture solution. CO 2 can be separated from the second CO 2 -rich alkaline capture solution.
1. A method to remove carbon dioxide (CO 2 ) gas from a first gaseous feed and a second gaseous feed, the method comprising:
wetting a gas-liquid contactor with an alkaline capture solution;
receiving the first gaseous feed from a first source, the first gaseous feed comprising CO 2 ;
directing a first flow from the first gaseous feed to interact with the alkaline capture solution in the gas-liquid contactor, wherein directing the first flow causes a first portion of CO 2 from the first gaseous feed to dissolve into the alkaline capture solution forming a first CO 2 -rich alkaline capture solution;
receiving the second gaseous feed from a second, distinct source, the second gaseous feed comprising CO 2 ;
directing a second flow from the second gaseous feed to interact with the first CO 2 -rich alkaline capture solution, wherein the second flow is independent of the first gaseous feed, and directing the second flow causes a second portion of CO 2 from the second gaseous feed to dissolve into the first CO 2 -rich alkaline capture solution forming a second CO 2 -rich alkaline capture solution, and a concentration of CO 2 in the second CO 2 -rich alkaline capture solution is higher than a concentration of CO 2 in the first CO 2 -rich alkaline capture solution; and
separating a third portion of CO 2 from the second CO 2 -rich alkaline capture solution.
2. The method of claim 1 , wherein the alkaline capture solution comprises:
an aqueous ionic base (M + Y − ),
a phase transfer catalyst,
an amine or a mixture of amines, and
a carboxylic acid salt of an amino acid.
3. The method of claim 1 , wherein the first gaseous feed comprises ambient air, and a concentration of the CO 2 gas in the first gaseous feed is equal to or less than 1000 parts per million (ppm).
4. The method of claim 1 , wherein the second gaseous feed comprises a flue gas, and a concentration of the CO 2 gas in the second gaseous feed is in a range of 1000 ppm to 40 weight percent.
5. The method of claim 1 , wherein separating the third portion of CO 2 from the second CO 2 -rich alkaline capture solution comprises:
passing the second CO 2 -rich alkaline capture solution to a desorption column; and
heating the second CO 2 -rich alkaline capture solution in the desorption column to a temperature to separate the third portion of CO 2 .
6. The method of claim 5 , wherein heating the second CO 2 -rich alkaline capture solution in the desorption column to a temperature to separate the third portion of CO 2 comprises heating the second CO 2 -rich alkaline capture solution to a temperature below 200 degrees Celsius.
7. The method of claim 5 , comprising:
prior to passing the second CO 2 -rich alkaline capture solution to the desorption column, passing the second CO 2 -rich alkaline capture solution and a CO 2 -lean alkaline capture solution through a heat exchanger, wherein the heat exchanger transfers heat from the CO 2 -lean alkaline capture solution to the second CO 2 -rich alkaline capture solution.
8. The method of claim 5 , comprising:
prior to passing the second CO 2 -rich alkaline capture solution to the desorption column, passing the second CO 2 -rich alkaline capture solution and the second gaseous feed through a heat exchanger, wherein the heat exchanger transfers heat from the second gaseous feed to the second CO 2 -rich alkaline capture solution.
9. The method of claim 1 , comprising:
wetting the gas-liquid contactor with the first CO 2 -rich alkaline capture solution, wherein directing the second flow to interact with the first CO 2 -rich alkaline capture solution comprises directing the second flow to interact with the first CO 2 -rich alkaline capture solution in the gas-liquid contactor.
10. The method of claim 1 , comprising:
transferring the first CO 2 -rich alkaline capture solution from the gas-liquid contactor to a bubbling column, wherein directing the second flow from the second gaseous feed to interact with the first CO 2 -rich alkaline capture solution comprises directing the second flow from the second gaseous feed to interact with the first CO 2 -rich alkaline capture solution in the bubbling column.
11. The method of claim 10 , comprising:
prior to transferring the first CO 2 -rich alkaline capture solution from the gas-liquid contactor to the bubbling column, determining the concentration of CO 2 of the first CO 2 -rich alkaline capture solution; and
in response to the concentration of CO 2 of the first CO 2 -rich alkaline capture solution being equal to or less than a predetermined threshold value, determining to transfer the first CO 2 -rich alkaline capture solution from the gas-liquid contactor to the bubbling column.
12. A hybrid carbon dioxide removal system for removing carbon dioxide (CO 2 ) gas from a first gaseous feed and a second gaseous feed, the system comprising:
a first gas-liquid contactor comprising
a first inlet that receives an alkaline capture solution; and
a first flow path that receives the first gaseous feed from a first source and directs a first flow of the first gaseous feed to interact with an alkaline capture solution in the first gas-liquid contactor, wherein directing the first flow causes a first portion of CO 2 from the first gaseous feed to dissolve into the alkaline capture solution and form a first CO 2 -rich alkaline capture solution;
a second gas-liquid contactor comprising:
a second inlet that receives the first CO 2 -rich alkaline capture solution from the first gas-liquid contactor; and
a second flow path that receives the second gaseous feed from a second source and directs a second flow of the second gaseous feed to interact with the first CO 2 -rich alkaline capture solution, wherein directing the second flow causes a second portion of CO 2 from the second gaseous feed to dissolve into the first CO 2 -rich alkaline capture solution and form a second CO 2 -rich alkaline capture solution, wherein the second flow is independent of the first gaseous feed, and a concentration of CO 2 in the second CO 2 -rich alkaline capture solution is higher than a concentration of CO 2 in the first CO 2 -rich alkaline capture solution; and
a third gas-liquid contactor comprising:
a third inlet that receives the second CO 2 -rich alkaline capture solution from the second gas-liquid contactor; and
a vessel that separates a third portion of CO 2 from the second CO 2 -rich alkaline capture solution.
13. The system of claim 12 , wherein the alkaline capture solution comprises:
an aqueous ionic base (M + Y − ),
a phase transfer catalyst,
an amine or a mixture of amines, and
a carboxylic acid salt of an amino acid.
14. The system of claim 12 , wherein the first gaseous feed comprises ambient air, and a concentration of the CO 2 gas in the first gaseous feed is equal to or less than 1000 parts per million (ppm).
15. The system of claim 12 , wherein the second gaseous feed comprises a flue gas, and a concentration of the CO 2 gas in the second gaseous feed is in a range of 1000 ppm to 40 weight percent.
16. The system of claim 12 , wherein the third gas-liquid contactor comprises a heating element configured to heat the second CO 2 -rich alkaline capture solution to a temperature sufficient to separate the third portion of CO 2 .
17. The system of claim 16 , wherein the third gas-liquid contactor comprises a desorption column, and the heating element is configured to heat the second CO 2 -rich alkaline capture solution to a temperature below 200 degrees Celsius.
18. The system of claim 16 , wherein the third gas-liquid contactor is configured to generate a CO 2 -lean alkaline capture solution when the third portion of CO 2 is separated from the second CO 2 -rich alkaline capture solution, and the system further comprises a heat exchanger configured to allow heat transfer from the CO 2 -lean alkaline capture solution to the second CO 2 -rich alkaline capture solution.
19. The system of claim 16 , further comprising:
a heat exchanger configured to transfer heat from the second gaseous feed to the second CO 2 -rich alkaline capture solution.
20. The system of claim 12 , wherein the first gas-liquid contactor further comprises a sensor configured to measure the concentration of CO 2 of the first CO 2 -rich alkaline capture solution, and the system further comprises a control system communicably coupled to the sensor and configured to:
determine the concentration of CO 2 of the first CO 2 -rich alkaline capture solution;
compare the determined concentration of CO 2 of the first CO 2 -rich alkaline capture solution with a predetermined threshold value; and
in response to the concentration of CO 2 of the first CO 2 -rich alkaline capture solution being equal to or less than the predetermined threshold value, determine to transfer the first CO 2 -rich alkaline capture solution from the first gas-liquid contactor to the second gas-liquid contactor.