IP Library Granted Patent US 12,365,610
Granted Patent B2
US 12,365,610 · App. 18/593,360 · Granted Jul 22, 2025

Scalable floating micro-aeration unit, devices and methods

Inventors: Sofia Malinova Babanova (San Diego, CA); Orianna Bretschger (San Diego, CA); Jaime Octavio García Cornejo (La Mesa, CA); Jason Daniel Jones (Cardiff By The Sea, CA)
Assignee: AQUACYCL, INC.
C02F3/08C02F3/005C02F3/006C02F3/10C02F3/103C02F3/345H01M8/16C02F2101/101C02F2209/22C02F2209/38
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Quick Facts
Patent No.
US 12,365,610
App. No.
18/593,360
Granted
Jul 22, 2025
Kind
B2
Abstract

Disclosed are floating micro-aeration unit (FMU) devices, systems and methods for biological sulfide removal from water/wastewater bodies and streams. In some aspects, a system includes a manifold structure including one or more opening to flow air out of an interior of the manifold structure; one or more support structures connected to the manifold structure, in which the one or more support structures are floatable on a surface of a fluid that includes water or a wastewater; and an air source that flows air to the manifold structure, such that the manifold structure supplies the air containing a predetermined amount of oxygen (e.g., less than 0.1 mg/L of oxygen) to oxidize sulfide of the fluid.

Claims (39)

1. A method of removing sulfide from a fluid containing water or wastewater, the method comprising:

providing a plurality of micro-aeration devices in a container comprising a fluid that is a water or wastewater, wherein each micro-aeration device of the plurality of micro-aeration devices comprises:

a manifold structure including one or more openings to flow air out of an interior of the manifold structure, and

one or more support structures connected to the manifold structure, wherein the one or more support structures is configured to float the manifold structure on a surface of the fluid or to partially submerge the manifold structure below the surface of the fluid;

contacting the fluid with the manifold structure of each of the micro-aeration devices, wherein the one or more support structures of each of the manifold structures positions the manifold structure to (i) float on the fluid or (ii) partially submerge the manifold structure below the surface of the fluid;

micro-aerating the fluid in the container by expelling air out of the interior of the manifold structures of each of the micro-aeration devices to supply the air (i) at a top surface of the fluid, (ii) at a shallow depth within a range between 0 cm to 5 cm below the top surface of the fluid, or (iii) both at the top surface and at the shallow depth of the fluid, such that an amount of oxygen gas within the shallow depth of the fluid comprises less than 0.1 mg/L of oxygen (O 2 ) in the fluid; and

converting sulfide of the fluid in the container to elemental sulfur.

2. The method of claim 1 , wherein the fluid includes sulfide-oxidizing bacteria.

3. The method of claim 1 , further comprising:

regulating air flow to the plurality of micro-aeration device with a flow meter for flowing air out of the interior of the manifold structure of each micro-aeration device of the plurality.

4. The method of claim 3 , wherein the air flow is regulated such that a concentration of oxygen introduced into the fluid does not exceed about 0.1 mg/L.

5. The method of claim 1 , wherein the method does not convert sulfide to sulfate, thiosulfate, or combination thereof.

6. The method of claim 1 , wherein the sulfide is hydrogen sulfide.

7. The method of claim 1 , further comprising:

providing a support material that is coupled to the manifold structure of at least one of the micro-aeration devices to facilitate growth of sulfide oxidizing bacteria and thereby create a biofilm.

8. The method of claim 7 , wherein the support material includes a plurality of openings voids such that the support material has an open structure up to 90% of the structure enables the sulfide-oxidizing bacteria to be in direct contact with the fluid at or below the surface.

9. A system for sulfide removal from and treatment of wastewater, comprising:

a container configured to hold a fluid including a wastewater, wherein the container is interfaced with an inlet line through which the fluid can flow into the container and an outlet line through which, once pre-treated, the fluid can flow out of the container as a pre-treated fluid; and

a plurality of micro-aeration devices configured to float on the fluid, wherein each of the micro-aeration devices comprises (i) a manifold structure including one or more openings to flow air out of an interior of the manifold structure, and (ii) one or more support structures connected to the manifold structure, wherein the one or more support structures is configured to float the manifold structure over a surface of the fluid to prevent the manifold structure to not be from being in direct contact with the fluid in the container,

wherein the plurality of micro-aeration devices is configured to expel the air from the one or more openings of the manifold structure at the fluid to remove sulfide from the fluid by micro-aeration, such that the air expelled by the micro-aeration devices is capable of providing an amount of oxygen gas within a shallow depth of the fluid between 0 cm to 5 cm from a top surface of the fluid, and wherein the amount of the oxygen gas in the air expelled from the plurality of micro-aeration devices within the shallow depth of the fluid comprises less than 0.1 mg/L of oxygen (O 2 ).

10. The system of claim 9 , further comprising:

an air source configured to supply air to the manifold structure of each of the micro-aeration devices to be flowed out through the one or more openings at the fluid by the plurality of the micro-aeration devices.

11. The system of claim 9 , further comprising:

a plurality of air sources configured to supply air to one or some of the micro-aeration devices of the plurality of micro-aeration devices, wherein the supplied air by an air source of the plurality of air sources is provided to the manifold structure of the one or the some of the micro-aeration devices to be flowed out through the one or more openings at the fluid by the respective one or the respective some of the micro-aeration devices.

12. The system of claim 9 , wherein one or more of the micro-aeration devices of the plurality of micro-aeration devices comprises a support material coupled to the manifold structure of the respective one or more of the micro-aeration devices to facilitate growth of sulfide-oxidizing bacteria to create a biofilm.

13. The system of claim 12 , wherein the support material includes a plurality of openings of the respective one or more of the micro-aeration devices such that the support material has an open structure up to 90% of the structure.

14. The system of claim 12 , wherein the support material includes at least one of a perforated carbon textile, a plastic mesh, or a perforated foam.

15. The system of claim 9 , further comprising:

a lid to at least partially cover the container and define a volume in the container between the plurality of micro-aeration devices and the lid that allows for uniform distribution of the air (i) at the top surface of the fluid, (ii) at the shallow depth below the top surface of the fluid, or (iii) both at the top surface and at the shallow depth of the fluid.

16. The system of claim 9 , wherein the plurality of micro-aeration devices is operable to convert the sulfide in the fluid to the elemental sulfur without conversion of the sulfide to sulfate, thiosulfate, or a combination thereof.

17. A system for sulfide removal from and treatment of wastewater, comprising:

a container configured to hold a fluid including a wastewater, wherein the container is interfaced with an inlet line through which the fluid can flow into the container and an outlet line through which, once pre-treated, the fluid can flow out of the container as a pre-treated fluid; and

a micro-aeration device configured to float on the fluid, the micro-aeration device comprising (i) a manifold structure including one or more openings to flow air out of an interior of the manifold structure, and (ii) one or more support structures connected to the manifold structure, wherein the one or more support structures is configured to float the manifold structure over a surface of the fluid to prevent the manifold structure from being in direct contact with the fluid in the container,

wherein the micro-aeration device is configured to expel the air from the one or more openings of the manifold structure at the fluid to remove sulfide from the fluid by micro-aeration, such that the air expelled by the micro-aeration device is capable of providing an amount of oxygen gas within a shallow depth of the fluid between 0 cm to 5 cm from a top surface of the fluid, and wherein the amount of the oxygen gas in the air expelled from the micro-aeration device within the shallow depth of the fluid comprises less than 0.1 mg/L of oxygen (O 2 ).

18. The system of claim 17 , further comprising:

an air source configured to supply air to the manifold structure of the micro-aeration device to be flowed out through the one or more openings at the fluid.

19. The system of claim 17 , wherein the micro-aeration device comprises a support material coupled to the manifold structure to facilitate growth of sulfide-oxidizing bacteria to create a biofilm.

20. The system of claim 17 , further comprising:

a lid to at least partially cover the container and define a volume in the container between the micro-aeration device and the lid that allows for uniform distribution of the air (i) at the top surface of the fluid, (ii) at the shallow depth below the top surface of the fluid, or (iii) both at the top surface and at the shallow depth of the fluid.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 15, 2024
From: BABANOVA, SOFIA MALINOVA; BRETSCHGER, ORIANNA; CORNEJO, JAIME OCTAVIO GARCIA; JONES, JASON DANIEL
To: AQUACYCL LLC
Reel/Frame 068293/0411 →
Continuity (4)
Continuation 17464478 · Sep 1, 2021
Continuation 16803119 · Feb 27, 2020
Provisional Application 62811496 · Feb 27, 2019
Related Publication 20240391809A1 · Nov 28, 2024
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