Granted Patent B2

US 12,202,743 · App. 18/611,463 · Granted Jan 21, 2025

Inventors: Soomin Kim (Thousand Oaks, CA); Ibadillah Ardhi Digdaya (Whittier, CA); Sreevalli Bokka (Montebello, CA); Chengxiang Xiang (San Marino, CA)

Assignee: Captura Corp.

C02F1/20B01D69/02B01D69/107B01D69/108B01D69/12B01D71/26B01D71/261B01D71/36B01D71/701C02F1/44C02F1/66B01D2325/04C02F2103/08

Abstract

Claims (40)

1. A system for separating dissolved carbon dioxide gas from an aqueous solution, comprising:

a contactor module comprising a composite membrane that separates a first chamber from a second chamber in the contactor module, the composite membrane configured to selectively transport, from the first chamber to the second chamber, dissolved carbon dioxide from an aqueous solution in the first chamber, the composite membrane comprising:

a supporting layer having a first surface and a second, opposite surface; and

a carbon dioxide selective layer disposed on the first surface, the carbon dioxide selective layer configured to contact the aqueous solution and to selectively transport the dissolved carbon dioxide through the supporting layer; and

a control system configured to perform operations comprising:

adjusting a pH value of the aqueous solution;

feeding the aqueous solution with the adjusted pH value to the first chamber of the contactor module such that the aqueous solution flows through the first chamber from a first end to a second opposite end of the contactor module;

adjusting a partial pressure in the second chamber of the contactor module; and

evaluating a carbon dioxide gas concentration collected from the second chamber of the contactor module.

2. The system of claim 1 , wherein the carbon dioxide selective layer has a selectivity for the dissolved carbon dioxide gas in the aqueous solution over other dissolved gases in the aqueous solution.

3. The system of claim 1 , wherein the carbon dioxide selective layer comprises a silicone-based polymer.

4. The system of claim 1 , wherein the carbon dioxide selective layer comprises a polyolefins-based polymer.

5. The system of claim 1 , wherein the carbon dioxide selective layer comprises a polyacetylene derived polymer.

6. The system of claim 1 , wherein the carbon dioxide selective layer comprises a fluoropolymer.

7. The system of claim 1 , wherein the supporting layer has a hollow fiber structure, the first surface is an inner surface of the hollow fiber structure, and the second, opposite surface is an outer surface of the hollow fiber structure.

8. The system of claim 1 , wherein the supporting layer has a porous structure.

9. The system of claim 8 , wherein the carbon dioxide selective layer partially fills the porous structure of the supporting layer and terminates at a depth between the first and second surfaces of the supporting layer.

10. The composite membrane of claim 1 , wherein the carbon dioxide selective layer is a first carbon dioxide selective layer, and the composite membrane comprises a second carbon dioxide selective layer distinct from the first carbon dioxide selective layer.

11. The composite membrane of claim 10 , wherein the second carbon dioxide selective layer comprises at least one of the following:

a silicone-based polymer;

a polyolefins-based polymer;

a polyacetylene derived polymer; or

a fluoropolymer.

12. The system of claim 1 , comprising:

a means for providing a driving force between first and second surfaces of the composite membrane to cause the dissolved carbon dioxide gas to be selectively transported through the carbon dioxide selective layer from the aqueous solution to the second surface of the support layer.

13. The system of claim 12 , wherein the means for providing the driving force between the first and second surfaces of the composite membrane comprises:

a pressure differential across the first and second surfaces of the composite membrane.

14. The system of claim 13 , wherein the pressure differential is equal to or greater than 10 4 pascals.

15. The system of claim 1 , comprising:

a liquid inlet on the contactor module configured to introduce the aqueous solution to the first chamber;

a liquid outlet on the contactor module configured to receive a liquid retentate from the first chamber;

a pump configured to pass the aqueous solution from the liquid inlet to the liquid outlet; and

a gas outlet on the contactor module configured to collect a permeated carbon dioxide gas from the second chamber.

16. The system of claim 1 , comprising multiple contactor modules, each contactor module comprises a plurality of composite membranes, and the multiple contactor modules are connected to one another in series.

17. The system of claim 1 , comprising multiple contactor modules, each contactor module comprises a plurality of composite membranes, and the multiple contactor modules are connected to one another in parallel.

18. The system of claim 1 , wherein the aqueous solution comprises dissolved inorganic carbon, adjusting the pH value of the aqueous solution comprises acidifying the aqueous solution to the adjusted pH value, and acidifying the aqueous solution comprises:

mixing an acid with the aqueous solution; and

converting the dissolved inorganic carbon in the aqueous solution to the dissolved carbon dioxide.

19. The system of claim 18 , wherein the aqueous solution comprises oceanwater.

20. The system of claim 19 , wherein the adjusted pH of the acidified oceanwater is equal to or greater than 4.

Assignments (2)

Continuity (2)

References Cited (49)