Polyetherimide composite nanofiltration membrane and preparation method thereof
The present invention relates to a polyetherimide composite nanofiltration membrane and a preparation method thereof, the method comprises the following steps: (1) dissolving polyetherimide and an additive into an organic solvent, stirring and keeping aside for deaeration to prepare a casting solution, blade coating of the casting solution onto a smooth surface of a nonwoven fabric, and placing under an air atmosphere and then putting into deionized water to obtain a support membrane 1 , wherein the surface of the nonwoven fabric coated with the casting solution is referred to as surface A; (2) immersing the surface A of the support membrane 1 into an aqueous solution of m-phenylenediamine, taking out and drying in the air, then immersing the surface A into a solution of 1,2,4,5-benzene tetracarbonyl chloride in n-hexane or cyclohexane, and taking out and drying in the air to obtain a support membrane 2 ; and (3) immersing the surface A of the support membrane 2 into an aqueous solution of EDC.HCl, then adding NHS into the aqueous solution of EDC.HCl, then adding an aqueous solution of ethylene diamine and keeping aside, and then rinsing with deionized water to obtain a polyetherimide composite nanofiltration membrane. The method of the invention has the advantages of low cost, low energy consumption and low pollution; and also has high rejection towards low-molecular-weight compound, stable performance and a longer lifetime.
1. A method for preparing a polyetherimide composite nanofiltration membrane, comprising the following steps:
(1) dissolving polyetherimide with a molecular weight at a range from 35000 to 55000 and an additive into an organic solvent in a manner that the weight percentage of the polyetherimide is at a range from 15% to 27% and the weight percentage of the additive is at a range from 1% to 6%, stirring at a temperature ranges from 40 to 80° C. for 3 to 8 hours and then keeping aside for deaeration for 8 to 24 hours to prepare a casting solution, blade coating at a range from 12 g to 20 g of the casting solution onto a smooth surface of a nonwoven fabric of 20 cm×30 cm according to a certain proportion, placing under an air atmosphere for 0 to 60 seconds and putting into deionized water for 5 to 60 min of immersion, taking out and drying in the air to obtain a support membrane 1 , wherein the surface of the nonwoven fabric coated with the casting solution is referred to as surface A;
(2) immersing the surface A of the support membrane 1 into an aqueous solution of m-phenylenediamine with a weight percentage at a range from 0.5% to 4% for 30 to 120 seconds, taking out and drying in the air, then immersing the surface A into a solution of 1,2,4,5-benzene tetracarbonyl chloride in n-hexane or cyclohexane with a weight percentage at a range from 0.02% to 0.2% for 30 to 120 seconds, and taking out and drying in the air to obtain a support membrane 2 ; and
(3) immersing the surface A of the support membrane 2 into an aqueous solution of EDC.HCl with a weight percentage at a range from 4% to 8% for 10 to 20 min, then adding NHS into the aqueous solution of EDC.HCl to obtain a weight percentage at a range from 2% to 4%, shaking to dissolve NHS, then adding an aqueous solution of ethylene diamine with a weight percentage at a range from 2% to 8%, keeping aside to react for 4 to 16 hours, and rinsing with deionized water to obtain a polyetherimide composite nanofiltration membrane, wherein the volume ratio of the aqueous solution of ethylene diamine to the aqueous solution of EDC.HCl is 1:1, the EDC.HCl is an abbreviation of 1-(3-dimethylamino propyl)-3-ethylcarbodiimide hydrochloride, and NHS is an abbreviation of N-hydroxysuccinimide;
wherein the additive is selected from polyethylene glycol 200, polyethylene glycol 400, or polyvinylpyrrolidone.
2. The method as claimed in claim 1 , wherein the organic solvent is selected from N,N-dimethyl formamide, N,N-dimethyl acetamide or N-methyl pyrrolidone.
3. The method as claimed in claim 1 , wherein the material of the nonwoven fabric is selected from polypropylene, polyester or polyacrylonitrile.
4. The method as claimed in claim 1 , wherein the weight percentage of the polyetherimide in step (1) is 25%.
5. The method as claimed in claim 1 , wherein the weight percentage of the additive in step (1) is 2%.
6. The method as claimed in claim 1 , wherein the placement time under the air atmosphere in step (1) is 1-10 seconds.