Charging roll for electrophotographic equipment
Provided is a charging roll for electrophotographic equipment with which any increase in resistance and any bleeding of ionic electroconductive agent while energization persists can be minimized. A charging roll 10 for electrophotographic equipment, the charging roll 10 comprising a shaft body 12 and an elastic layer 14 that is formed on the outer peripheral surface of the shaft body 12 , the elastic layer 14 being a crosslinked article of a rubber composition containing the following components (a) to (e). (a) One or more selected from hydrin rubber and nitrile rubber, (b) a crosslinking agent, (c) an ionic electroconductive agent, (d) one or more selected from piperidinyloxy radical compounds and phenolic antioxidants, and (e) one or more selected from salts of cyclic amidine compounds and thiophthalimide compounds.
1 . A charging roll for electrophotographic equipment, comprising a shaft body and an elastic layer formed on an outer peripheral surface of the shaft body,
wherein the elastic layer is a crosslinked product of a rubber composition that contains the following (a) to (e):
(a) one or two or more selected from hydrin rubber and nitrile rubber,
(b) a crosslinking agent,
(c) an ionic electroconductive agent,
(d) one or two or more selected from piperidinyloxy radical compounds, and
(e) one or two or more selected from salts of cyclic amidine compounds and thiophthalimide compounds.
2 . The charging roll for electrophotographic equipment according to claim 1 , wherein the (e) is a naphthoic acid salt of a cyclic amidine compound.
3 . The charging roll for electrophotographic equipment according to claim 1 , wherein the (e) is N-cyclohexylthiophthalimide.
4 . The charging roll for electrophotographic equipment according to claim 1 , wherein the (c) is an ammonium-based, phosphonium-based, or imidazolium-based ionic electroconductive agent.
5 . The charging roll for electrophotographic equipment according to claim 1 , wherein the (c) is an ionic electroconductive agent that contains sulfonate anions having fluorine atoms, bis(sulfonyl)imide anions having fluorine atoms, or perchlorate anions.
6 . The charging roll for electrophotographic equipment according to claim 1 , wherein the rubber composition further contains carbon black that has a specific surface area of 40 m 2 /g or more and 300 m 2 /g or less.