Charging roll or developing roll for electrophotographic device
An elastic body layer is composed of a conductive rubber composition containing an isoprene rubber, a rubber other than the isoprene rubber, and carbon black. The elastic body layer is phase-separated into a first rubber phase containing the isoprene rubber and a second rubber phase containing the rubber other than the isoprene rubber; in the range of a 5 μm×5 μm square of an arbitrary cross section of the elastic body layer, the area ratio of the first rubber phase is within a range of 10 to 90%. The resistance value of the elastic body layer is within a range of 1.0×10 3 to 1.0×10 6 Ω. A surface layer contains an electronic conductive agent and a crosslinked body of at least one polyurethane resin of an ether polyurethane resin and a carbonate polyurethane resin, and the glass transition point of the surface layer is within a range of −10 to −70° C.
1. A charging roll for an electrophotographic device, comprising:
a shaft body, an elastic body layer formed on the outer periphery of the shaft body, and a surface layer formed on the outer periphery of the elastic body layer;
wherein the elastic body layer is composed of a conductive rubber composition containing an isoprene rubber, a rubber other than the isoprene rubber, and carbon black;
the elastic body layer is phase-separated into a first rubber phase containing the isoprene rubber and a second rubber phase containing the rubber other than the isoprene rubber, wherein the rubber other than the isoprene rubber is an acrylonitrile butadiene rubber; in the range of a 5 μm×5 μm square of an arbitrary cross section of the elastic body layer, the area ratio of the first rubber phase with respect to a total of the first rubber phase and the second rubber phase is within a range of 10 to 90%, the carbon black is eccentrically located in the second rubber phase than in the first rubber phase;
the resistance value of the elastic body layer is within a range of 1.0×10 3 to 1.0×10 6 Ω, a surface roughness Sa of the elastic body layer is 0.05 to 1.6 μm;
the surface layer contains an electronic conductive agent, an associative thickener and a crosslinked body of at least one polyurethane resin of an ether polyurethane resin and a carbonate polyurethane resin, and the glass transition point of the surface layer is within a range of −10 to −70° C., the polyurethane resin of the surface layer is an aqueous polyurethane resin, the associative thickener has a nonionic hydrophilic group and a hydrophobic group consisting of alkyl group, a content of the associated thickener in the composition constituting the surface layer is in a range of 0.5 to 10 parts by mass with respect to 100 parts by mass of the aqueous polyurethane resin,
the surface layer contains particles for roughness formation, a line roughness Rz at a portion of the surface layer containing the particles for roughness formation is 5.0 to 15.0 μm, and a product Sz·Sm of the surface roughness Sz and the line roughness Sm at a portion of the surface layer that does not contain the particles for roughness formation is 7.5 to 250 μm.
2. A developing roll for an electrophotographic device, comprising:
a shaft body, an elastic body layer formed on the outer periphery of the shaft body, and a surface layer formed on the outer periphery of the elastic body layer;
wherein the elastic body layer is composed of a conductive rubber composition containing an isoprene rubber, a rubber other than the isoprene rubber, and carbon black;
the elastic body layer is phase-separated into a first rubber phase containing the isoprene rubber and a second rubber phase containing the rubber other than the isoprene rubber, wherein the rubber other than the isoprene rubber is an acrylonitrile butadiene rubber; in the range of a 5 μm×5 μm square of an arbitrary cross section of the elastic body layer, the area ratio of the first rubber phase with respect to a total of the first rubber phase and the second rubber phase is within a range of 10 to 90%, the carbon black is eccentrically located in the second rubber phase than in the first rubber phase;
the resistance value of the elastic body layer is within a range of 1.0×10 3 to 1.0×10 6 Ω, a surface roughness Sa of the elastic body layer is 0.05 to 1.6 μm;
the surface layer contains an electronic conductive agent, an associative thickener and a crosslinked body of at least one polyurethane resin of an ether polyurethane resin and a carbonate polyurethane resin, and the glass transition point of the surface layer is within a range of −10 to −70° C., the polyurethane resin of the surface layer is an aqueous polyurethane resin, the associative thickener has a nonionic hydrophilic group and a hydrophobic group consisting of alkyl group, a content of the associated thickener in the composition constituting the surface layer is in a range of 0.5 to 10 parts by mass with respect to 100 parts by mass of the aqueous polyurethane resin,
the surface layer contains particles for roughness formation, a line roughness Rz at a portion of the surface layer containing the particles for roughness formation is 5.0 to 15.0 μm, and a product Sz·Sm of the surface roughness Sz and the line roughness Sm at a portion of the surface layer that does not contain the particles for roughness formation is 7.5 to 250 μm.