Heat transfer sheet, method for producing heat transfer sheet, heat transfer sheet package, and method for producing heat transfer sheet package
A heat transfer sheet includes: at least one of a carbon fiber and a boron nitride flake; an inorganic filler, and a binder resin. The at least one of the carbon fiber and the boron nitride flake is oriented in a thickness direction of the heat transfer sheet. When the heat transfer sheet is in a sealed state under a reduced pressure of 150 to 300 torr for one minute or more and removed from the sealed state, a tack force of the heat transfer sheet satisfies condition 1: the tack force of the heat transfer sheet is 100 gf or more when a probe having a diameter of 5.1 mm presses in the heat transfer sheet at a force of 200 gf at 2 mm/sec and pulls it off at 10 mm/sec.
1 . A heat transfer sheet, comprising:
at least one of a carbon fiber and a boron nitride flake;
an inorganic filler; and
a binder resin,
wherein the at least one of the carbon fiber and the boron nitride flake is oriented in a thickness direction of the heat transfer sheet, and
when the heat transfer sheet is in a sealed state under a reduced pressure of 150 to 300 torr for one minute or more and removed from the sealed state, a tack force of the heat transfer sheet satisfies condition 1,
condition 1: the tack force of the heat transfer sheet is 100 gf or more when a probe having a diameter of 5.1 mm presses in the heat transfer sheet at a force of 200 gf at 2 mm/sec and pulls it off at 10 mm/sec.
2 . The heat transfer sheet according to claim 1 , wherein the binder resin is a silicone resin.
3 . The heat transfer sheet according to claim 2 , wherein the silicone resin is a two-component addition-reaction silicone resin which comprises: a main component comprising a silicone having an alkenyl group and a curing catalyst; and a curing agent having a hydrosilyl group.
4 . The heat transfer sheet according to claim 1 , wherein a difference between a thermal resistance value of the heat transfer sheet removed from the sealed state and a thermal resistance value of the heat transfer sheet prior to sealing is within ±5% of the thermal resistance value of the heat transfer sheet prior to sealing.
5 . The heat transfer sheet according to claim 1 , wherein a content of the binder resin in the heat transfer sheet is 11 to 60 mass % relative to 100 mass % of the heat transfer sheet.
6 . The heat transfer sheet according to claim 1 , wherein a content of the binder resin in the heat transfer sheet is 25 to 50 mass % relative to 100 mass % of the heat transfer sheet.
7 . The heat transfer sheet according to claim 1 , wherein the inorganic filler comprises at least one selected from the group consisting of an aluminum oxide, an aluminum hydroxide, and an aluminum nitride.
8 . The heat transfer sheet according to claim 1 , wherein the tack force of the heat transfer sheet satisfies condition 2,
condition 2: the tack force of the heat transfer sheet is 108-201 gf when the probe having a diameter of 5.1 mm presses in the heat transfer sheet at the force of 200 gf at 2 mm/sec and pulls it off at 10 mm/sec, and
the difference between the thermal resistance value of the heat transfer sheet removed from the sealed state and the thermal resistance value of the heat transfer sheet prior to sealing is within ±0.5% of the thermal resistance value of the heat transfer sheet prior to sealing.
9 . A heat transfer sheet package, comprising:
the heat transfer sheet according to claim 1 held in a vacuum state.
10 . The heat transfer sheet package according to claim 9 , further comprising thermoplastic resin films, wherein the heat transfer sheet is sealed with the thermoplastic resin films.