Lignin removal from lignocellulosic waste using rejected brine solution
Lignocellulosic waste, such as date palm seeds, is treated with industrial waste such as rejected brine solution waste from a water treatment desalination plant to break down lignin and isolate and recover cellulose. Such a method is more cost effective and less toxic than other current and prior methods. Such a method concurrently solves two problems—usage of lignocellulose waste and usage of brine solution waste from a desalination treatment plant—to isolate and recover biocompatible, biodegradable versatile cellulose.
1. A method for the removal of lignin from a lignocellulose material to extract cellulose from the lignocellulose material, the method comprising:
providing a lignocellulose material;
crushing the lignocellulose material;
providing rejected brine solution waste from a water treatment desalination plant;
mixing the crushed lignocellulose material with the rejected brine solution waste while heating to obtain a mixture; and
filtering the mixture to obtain the cellulose;
wherein the rejected brine solution comprises a sodium ion concentration greater than 20,000 ppm, a chlorine concentration greater than 45,000 ppm, a magnesium ion concentration greater than 2,500 ppm, and a calcium ion concentration greater than 1,000 ppm.
2. The method of claim 1 , wherein the lignocellulose material comprises a waste lignocellulose material.
3. The method of claim 1 , wherein the lignocellulose material comprises waste date seeds, date seeds, or a combination thereof.
4. The method of claim 3 , wherein crushing the lignocellulose material comprises crushing the waste date seeds, the date seeds, or the combination thereof.
5. The method of claim 1 , wherein the lignocellulose material is crushed to a size of about 180 μm.
6. The method of claim 5 , wherein the mixing comprises mixing the crushed lignocellulose material with the rejected brine solution waste by mechanical stirring.
7. The method of claim 6 , wherein the crushed lignocellulose material and the rejected brine solution waste are mixed at a ratio of about 1:90-110, w/v.
8. The method of claim 7 , wherein the crushed lignocellulose material and the rejected brine solution waste are mixed at a ratio of about 1:100, w/v.
9. The method of claim 6 , wherein the heating comprises heating at about 90° C. and the mechanical stirring is conducted for about 4 hours to produce the mixture comprising a dark brown slurry.
10. The method of claim 1 , wherein filtering the mixture produces a lignin-rich filtrate solution and a cellulose filter cake.
11. The method of claim 10 , wherein the filtering comprises vacuum filtering.
12. The method of claim 10 , wherein the cellulose filter cake is oven dried at about 105° C. for about 24 hours to obtain the cellulose.
13. Cellulose produced by the method of claim 1 .
14. The method of claim 1 , wherein the rejected brine solution comprises a sodium ion concentration of about 23,836 ppm, a chlorine ion concentration of about 48,072 ppm, a magnesium ion concentration of about 2,802 ppm, and a calcium ion concentration of about 1,342 ppm.
15. The method of claim 1 , wherein the rejected brine solution comprises a sodium ion concentration of about 23,836 ppm, a chlorine ion concentration of about 48,072 ppm, a magnesium ion concentration of about 2,802 ppm, a potassium ion concentration of about 782 ppm, a calcium ion concentration of about 1,342 ppm, and a sulfate ion concentration of about 6,062 ppm.