Cucurbiturils and method for binding gases and volatiles using cucurbiturils
In accordance with the invention, there is provided a method of binding a gas or volatile compound in a cucurbituril, by contacting the gas or volatile compound with the cucurbituril to form a cucurbituril-gas/volatile complex. There is also provided a method of separating a gas or volatile compound from a mixture of compounds wherein the mixture is contacted with a cucurbituril and whereby at least some of the gas or volatile compound is bound to the cucurbituril to form a cucurbituril complex, followed by the release of at least some of the bound gas or volatile compound from that complex. The present invention is thus advantageous in that it allows use of cucurbiturils in binding gases and volatile compounds for storage, safety, delivery or other uses, such as the trapping of an unpleasant or toxic gas or volatile compound.
1. A method of binding a gas in a cucurbituril, said method comprising contacting the gas with the cucurbituril to form a cucurbituril complex of the gas.
2. A method according to claim 1 wherein the cucurbituril is in solution and the gas is contacted with the cucurbituril by passing the gas through the solution containing the cucurbituril.
3. A method according to claim 2 wherein the cucurbituril is in an aqueous solution.
4. A method according to claim 3 wherein the aqueous solution comprises a solubilising agent for increasing the solubility of the cucurbituril in the aqueous solution.
5. A method according to claim 4 wherein the solubilising agent is selected from the group consisting of metal salts, ammonium salts, acids and polyhydroxylated organic compounds.
6. A method according to claim 1 wherein the gas is the gaseous phase of a volatile compound.
7. A method according to claim 1 wherein the cucurbituril is a solid.
8. A method of separating a gas from a gaseous mixture of compounds containing the gas, said method comprising the steps of:
1) contacting the mixture with a cucurbituril whereby at least some of the gas is bound to the cucurbituril to form a cucurbituril complex of the gas; and
2) releasing at least some of the bound gas from the complex.
9. A method according to claim 8 wherein, in step 1), the cucurbituril is in solution and the mixture is contacted with the cucurbituril by passing the mixture through the solution containing the cucurbituril.
10. A method according to claim 9 wherein the cucurbituril is in an aqueous solution.
11. A method according to claim 10 wherein the aqueous solution comprises a solubilising agent for increasing the solubility of the cucurbituril in the aqueous solution.
12. A method according to claim 11 wherein the solubilising agent is selected from the group consisting of metal salts, ammonium salts, acids and polyhydroxylated organic compounds.
13. A method according to claim 8 wherein the gas is the gaseous phase of a volatile compound.
14. A method according to claim 8 wherein the cucurbituril is a solid.
15. A method according to claim 14 wherein the gas is released from the complex by dissolving the complex in a solvent and heating the resultant solution to release the gas from the complex.
16. A method of binding acetylene in a cucurbituril, said method comprising contacting acetlylene with a cucurbituril selected from the group consisting of unsubstituted cucurbit[5]uril, decamethylcucurbit[5]uril, dimethylcucurbit[1,4]uril and tetramethylcucurbit[2,3]uril, to form a cucurbituril complex of acetylene.
17. A method of binding dioxane in a cucurbituril, said method comprising contacting dioxane with a cucurbituril selected from the group consisting of unsubstituted cucurbit[6]uril, unsubstituted cucurbit[7]uril and hexamethylcucurbit[3,3]uril, to form a cucurbituril complex of dioxane.
18. A method of binding carbon monoxide in a cucurbituril, said method comprising contacting carbon monoxide with unsubstituted cucurbit[5]uril to form a cucurbituril complex of carbon monoxide.