Method for simultaneously abating nitric oxides and nitrous oxides in gases containing them
View Patent ↗The invention concerns a method for purifying flue gases before they are released into the atmosphere of their nitrogen oxides N 2 O and NO x by reaction with ammonia by causing them to circulate at temperatures between 200 and 600° C. on a catalyst based on beta-zeolite loaded with iron. The invention is particularly useful for treating tail gases from factories producing nitric acid.
1. Process for removing nitric oxides (NO x ) and nitrous oxide (N 2 O) from a gas comprising:
adding an amount of ammonia to said gas, said gas comprising NO x , N 2 O, oxygen and water, such that the amount of ammonia is at a value 0.7<X<1.4, wherein X is the voluminal ratio of ammonia/nitrogen oxides;
causing said gas to circulate at temperatures ranging between 200 and 600° C., on a catalyst comprising a iron beta-zeolite.
2. Process according to claim 1 , wherein said gas comprises between 100 and 7000 ppmv of NO x and N 2 O.
3. Process according to claim 1 , wherein said iron beta-zeolite comprises an iron beta-zeolite granule and an agglomeration binder.
4. Process according to claim 1 in which the iron beta-zeolite is a beta zeolite of Si/Al molar ratio ranging between 8 and 100, charged with iron by impregnation or exchange, in which the content by weight of iron ranges between 0.02 and 8%.
5. Process according to claim 4 , wherein the Si/Al molar ratio ranges between 8 and 20.
6. Process according to claim 4 , wherein the content by weight of iron ranges between 0.5-3%.
7. Process according to claim 1 , in which said gas circulates over the iron beta catalyst at voluminal velocities per hour (VVH) from 1000 to 50000 h −1 .
8. Process according to claim 1 , wherein the volume content of oxygen ranges between 1.5 and 5% and the volume content of water between 0.5 and 5%.
9. Process according to claim 1 , in which the gas is a tail gas from a nitric acid production factory.