Method of manufacturing nano-sized lithium-cobalt oxides by flame spraying pyrolysis
View Patent ↗A method for producing nano-sized lithium-cobalt oxide is provided by using flame-spray pyrolysis. The method comprises the steps of: spraying minute droplets, which is a solution dissolved lithium salt with cobalt salt at room temperature; atomizing the minute droplets through rapid expansion into a high temperature environment generated by combusting oxygen and hydrogen; decomposing and oxidizing the atomized minute droplets thermally at high temperature to produce nano-sized oxides in gaseous phase: and collecting the produced nano-sized composite oxides particles. The produced nano-sized lithium-cobalt oxide can be applied to a highly efficient lithium battery as the electrode materials and a thin film type of battery as well as to a miniaturized battery.
1. A method of producing nano-sized lithium-cobalt oxide by utilizing a flame spray pyrolysis, the method comprises the step of:
spraying minute droplets, which is a solution of dissolved lithium salt and cobalt salt at a temperature below 100° C.,
atomizing the minute droplets by rapidly expanding into an environment of high temperature in the range of 800° C. to 1700° C. provided by combusting oxygen and hydrogen,
decomposing the atomized droplets thermally at said environment of high temperature in a few seconds to produce nano-sized oxides in gaseous phase, and
condensing and collecting the produced nano-sized lithium-cobalt oxides.
2. The method as claimed in claim 1 , wherein said solution of dissolved lithium salt and cobalt salt has 1.2-2.0 mole ratio of lithium salt to cobalt salt.
3. The method as claimed in claim 2 , wherein said lithium salt is selected from the group consisting of lithium acetate (LiCH 3 COO), lithium nitrate (LiNO 3 ), lithium hydroxide (LiOH) and lithium carbonate (Li 2 CO 3 ), and said cobalt salt is selected from the group consisting of cobalt acetate (Co(CH 3 COO) 2 ), cobalt nitrate (Co(NO 3 ) 2 ), cobalt hydroxide (Co(OH) 2 ) and cobalt carbonate (CoCO 3 ).
4. The method as claimed in claim 1 , wherein said minute droplets are produced by utilizing an ultrasonic generator disposed in a fluid reservoir.
5. The method as claimed in claim 1 , wherein said high temperature is generated by a heat source which has five gas injection tubes, wherein the five gas injection tubes are arranged in sequential order starting from the center tube and moving outward, so that the center tube supplies said minute droplets and argon, and the remaining tubes in subsequent sequential order supply argon, hydrogen, oxygen plus air, and air.