Metal coordination compound, luminescence device and display apparatus
An electroluminescence device having a layer containing a specific metal coordination compound is provided. The metal coordination compound is represented by formula (1) below: ML m L′ n (1), wherein M is a metal atom of Ir, Pt, Rh or Pd; L and L′ are mutually different bidentate ligands; m is 1, 2 or 3 and n is 0, 1 or 2 with the proviso that m+n is 2 or 3; a partial structure MLm is represented by formula (2) shown below and a partial structure ML′ n is represented by formula (3) or (4) shown below: at least one of the optional substituent(s) of the cyclic groups, and the cyclic groups CyC 1 and CyC2 include an aromatic group capable of having a substituent represented by the following formula (5): The metal coordination compound having the aromatic group is effective in providing high-efficiency luminescence and long-term high luminance.
1. A metal coordination compound represented by the following formula (6):
wherein X denotes CRR′, O or S where R and R′ are independently a linear or branched alkyl group of formula: C n H 2n+1 — in which n is an integer of 1-20, the alkyl group can include one or non-neighboring two or more methylene groups that can be replaced with —O— and also can include a hydrogen atom that can be optionally replaced with a fluorine atom;
R2 denotes a hydrogen atom; a fluorine atom; a linear or branched alkyl group of formula: C n H 2n+1 — in which n is an integer of 1-20, the alkyl group can include one or non-neighboring two or more methylene groups that can be replaced with —O— and also can include a hydrogen atom that can be optionally replaced with a fluorine atom; a phenyl group optionally having a substituent; a 9,9-dialkylfluorenyl group (of which the alkyl groups are independently a linear or branched alkyl group of formula: C n H 2n+1 — in which n is an integer of 1-20, the alkyl group can include one or non-neighboring two or more methylene groups that can be replaced with —O— and also can include a hydrogen atom that can be optionally replaced with a fluorine atom); a dibenzofuranyl group optionally having a substituent; and a dibenzothienyl group optionally having a substituent; and R1 and R4 independently denote a hydrogen atom; a fluorine atom; a phenyl group optionally having a substituent; and a linear or branched alkyl group of formula: C n H 2n+1 — in which n is an integer of 1-20, the alkyl group can include one or non-neighboring two or more methylene groups that can be replaced with —O— and also can include a hydrogen atom that can be optionally replaced with a fluorine atom; the said optional substituent of said phenyl group, said 9,9-dialkylfluorenyl group, said dibenzofuranyl group and said dibenzothienyl group is a fluorine atom or a linear or branched alkyl group of formula: C n H 2n+1 — in which n is an integer of 1-20, the alkyl group can include one or non-neighboring two or more methylene groups that can be replaced with —O— and also can include a hydrogen atom that can be optionally replaced with a fluorine atom.
2. An electroluminescence device, comprising: a pair of electrodes disposed on a substrate, and a luminescence unit comprising at least one organic compound disposed between the electrodes, wherein the organic compound comprises a metal coordination compound represented by the formula (6) in claim 1 .
3. An electroluminescence device according to claim 2 , wherein a voltage is applied between the electrodes to emit light.
4. An electroluminescence device according to claim 2 , wherein a voltage is applied between the electrodes to emit phosphorescense.
5. A picture display apparatus, comprising an electroluminescence device according to claim 2 , and a means for supplying electric signals to the electroluminescence device.