Articles having an odor control system comprising a cationic polysaccharide and an odor controlling agent
The present invention relates to articles suitable for controlling odors, especially odors associated with bodily fluids, which comprise a cationic polysaccharide, preferably chitosan material, together with an odor controlling agent, preferably an odor absorbent agent and/or a chelating agent. This combination provides synergistic reduced odor control towards malodors associated with bodily fluids like menses.
1. A disposable absorbent article comprising a liquid pervious topsheet, a backsheet and an absorbent core intermediate to said backsheet and said topsheet; said absorbent core comprising an odour control system for controlling odours comprising a cationic polysaccharide together with an odor controlling agent; wherein said cationic polysaccharide is an aminopolysaccharide selected from the group consisting of chitosan, chitosan salt, chitosans that comprise carboxymethyl, memylpyrrolldinone or glycol pendant groups on a glucan chain, crosslinked chitosan and mixtures thereof.
2. An article according to claim 1 wherein said chitosan has a degree of deacetylation of more than 75%.
3. An article according to claim 1 wherein the cationic polysaccharide is selected from the group consisting of a chitosan salt of citric acid, formic acid, acetic acid, N-acetylglycine, acetylsalicylic acid, fumaric acid, glycolic acid, iminodiacetic acid, itaconic acid, lactic acid, maleic acid, malic acid, nicotinic acid, salicylic acid, succinamic acid, succinic acid, ascorbic acid, aspartic acid, glutamic acid, glutaric acid, malonic acid, pyruvic acid, sulfonyldiacetic acid, benzoic acid, epoxysuccinic acid, adipic acid, thiodiacetic acid, thioglycolic acid, alanine, valine, leucine, isoleucine, prolinephenylalanine, triptofane, metionine, glycine, serine, cysteine, tyrosine, asparagine, glutamine, lysine, arginine, histidine, hydroxyproline, pyrrolidone carboxylic acid, chitosonium pyrrolidone carboxylate and mixtures thereof.
4. An article according to claim 1 which comprises from about 0.5 gm −2 to about 500 gm −2 of cationic polysaccharide.
5. An article according to claim 1 wherein the odor controlling agent is a chelating agent and/or an odor absorbent agent.
6. An article according to claim 5 wherein said odor controlling agent is an odor absorbent agent selected from the group consisting of zeolites, carbons, diatomaceous earth, starches, cyclodextrin, kieselguhr, clays, ion exchange resins and combination thereof and preferably is zeolite, aipha-cyclodextrin, beta-cyclodextrin, gamma-cyclodextrin or a combination thereof.
7. An article according to claim 5 wherein the odor controlling agent is a chelating agent selected from the group consisting of phosphonate chelating agents, amino phosphonate chelating agents, polyfunctionally-substituted aromatic chelating agents, animo carboxylate chelating agents, ethylene diamine N,N′-disuccinic acid, aspartic acid, glutamic acid, malonic acid, glycine and mixtures thereof.
8. An article according to claim 7 wherein the chelating agent is selected from the group consisting of ethylene diamine tetracetate, -triacetate, -diacetate, and -monoacetate, ethylenediamine N,N,-disuccinic acid, ethylenediamine penta methylene phosphonic acid, ethylenediamine tetra methylene phosphonic acid and mixtures thereof.
9. An article according to claim 1 which comprises from about 1 to about 600 gm −2 of the odor controlling agent.
10. An article according to claim 1 further comprising an absorbent gelling material.
11. An article according to claim 5 further comprising an absorbent gelling material.
12. An article according to claim 10 , wherein the absorbent gelling material is present at a level from about 5 gm −2 to about 250 gm −2 .