Biaxially oriented polyester film, and a production method thereof
An object of the present invention is to provide a biaxially oriented high quality polyester film excellent in thermal dimensional stability and clarity and also excellent in productivity, and also to provide a production process thereof. Another object is to provide a biaxially oriented polyester film greatly improved in the practical properties respected in various applications of the polyester film, such as the recording track shift in magnetic recording tape application, curling in magnetic recording card application, dimensional change during process in printing plate application, printing shift in ribbon application, thermostability in capacitor application, and perforation sensitivity and low temperature curling in heat-sensitive mimeograph stencil application. The objects of the present invention can be achieved by a biaxially oriented polyester film, comprising a polyester (A) mainly composed of ethylene terephthalate and a polyether imide (B), having a single glass transition temperature, and having a refractive index of 1.60 to 1.80 at least in either the machine direction or the transverse direction.
1. A process for producing a biaxially oriented polyester film, comprising the steps of:
preparing a raw material blend of a polyester (A) mainly composed of ethylene terephthalate and a polyether imide (B) of 70/30–10/90 as (A/8) ratio by weight;
melt-extruding polyester (A) with said raw material blend to mold a resin sheet with a single glass transition temperature; and
stretching the resin sheet at a ratio of 3.0 to 10 times in the machine direction and at a ratio of 3.0 to 10 times in the transverse direction, wherein the biaxially oriented polyester film has a refractive index of 1.60 to 1.80 at least in either the machine direction or the transverse direction.
2. A process for producing a biaxially oriented polyester film, according to claim 1 , wherein the biaxially oriented film is heat-set at 100° C. to 260° C.
3. A process for producing a biaxially oriented polyester film, according to claim 1 , wherein the melt extrusion is effected by an extruder (1) at a screw shear rate of 30 second −1 to less than 300 second −1 , (2) at a polymer temperature of 280° C. to 320° C., (3) with the polymer discharge time set at 60 seconds to 10 minutes.