Plant seeds treated with N,N′-substituted ureas
The present invention is directed to new compositions of matter comprising the reaction products of a carboxylic acid and a urea having the formula where R 1 , R 2 , R 3 and R 4 are the same or different and are selected from the group consisting of hydrogen, substituted and unsubstituted alkyl, allyl, vinyl and alkoxyl groups having from 1–6 carbon atoms, substituted and unsubstituted phenyl groups and the halides. Preferably, the reaction product of the present invention is N,N′-diformylurea or N,N′-diacetylurea. These reaction products, e.g., diformylurea, have been found to produce significantly improved growth in a variety of agricultural products when applied to the seed, to the surrounding soil or to the foliage of the emerging plant. Because of the similarity in the carbon, nitrogen, oxygen structure of these reaction products with many biological compounds, it is believed that the reaction products of the present invention may find use in a variety of biological applications.
1. A treated seed comprising a plant seed to which has been applied an N,N′-substituted urea having the formula
where R 1 and R 2 are the same or different and are selected from the group consisting of hydrogen, substituted and unsubstituted alkyl, allyl, vinyl and alkoxyl groups having from 1 to 6 carbon atoms, substituted and unsubstituted phenyl groups and the halides.
2. The treated seed of claim 1 wherein R 1 and R 2 are selected from the group consisting of hydrogen and unsubstituted alkyl groups having from 1 to 3 carbon atoms.
3. The treated seed of claim 1 wherein said plant seed has been soaked in an aqueous solution containing said N,N′-substituted urea.
4. The treated seed of claim 1 wherein R 1 and R 2 are hydrogen.
5. An improved plant seed comprising a seed to which has been applied an N,N′-substituted urea having the formula
where R 1 and R 2 are the same or different and are selected from the carbonyl groups derived from the acids consisting of formic, acetic, propionic, butyric, valeric, caproic, heptanoic and citric acids.
6. The treated seed of claim 5 wherein R 1 and R 2 are selected from the group consisting of hydrogen and unsubstituted alkyl groups having from 1 to 3 carbon atoms.
7. The treated seed of claim 5 wherein said plant seed has been soaked in an aqueous solution containing said N,N′-substituted urea.
8. A treated seed comprising a plant seed to which has been added diformylurea having the formula
9. The treated seed of claim 8 wherein said plant seed has been soaked in an aqueous solution containing said diformylurea.