Packaging material for battery
Disclosed is a packaging material for forming an armor body for a battery, the armor body being adapted for use in such a manner that a battery body is inserted into the armor body and the peripheral edge of the armor body is then heat sealed for hermetic sealing, the packaging material being a laminate comprising at least a substrate layer, an adhesive layer, a barrier layer, a dry laminate layer, and a sealant layer, characterized in that at least the sealant layer comprises a low-fluidity polypropylene layer having low susceptibility to collapse upon exposure to heat and pressure at the time of heat sealing and a high-fluidity polypropylene layer having high susceptibility to collapse upon exposure to heat and pressure at the time of heat sealing, and the innermost layer is the high-fluidity polypropylene layer. This battery packaging material can impart moisture barrier properties and resistance to contents of the battery.
1. A packaging material for forming an armor body for a battery, said armor body being adapted for use in such a manner that a battery body is inserted into the armor body and the peripheral edge of the armor body is then heat sealed for hermetic sealing, said packaging material being a laminate comprising at least a substrate layer, an adhesive layer, a barrier layer, a dry laminate layer, and a sealant layer, characterized in that
at least the sealant layer comprises a low-fluidity polypropylene layer having low susceptibility to collapse upon exposure to heat and pressure at the time of heat sealing and a high-fluidity polypropylene layer having high susceptibility to collapse upon exposure to heat and pressure at the time of heat sealing, and the innermost layer is the high-fluidity polypropylene layer.
2. The packaging material for a battery according to claim 1 , characterized in that the barrier layer comprises at least a conversion treated layer provided on its dry laminate layer side.
3. The packaging material for a battery according to claim 1 , characterized in that the sealant layer has a two-layer structure of the low-fluidity polypropylene layer and the high-fluidity polypropylene layer and the high-fluidity polypropylene layer is the innermost layer.
4. The packaging material for a battery according to claim 1 , characterized in that the sealant layer has a three-layer structure of the high-fluidity polypropylene layer, the low-fluidity polypropylene layer, and the high-fluidity polypropylene layer.
5. The packaging material for a battery according to claim 1 , characterized in that a film for a lead is interposed between the armor body for a battery and a lead part in the battery body.
6. A packaging material for forming an armor body for a battery, said armor body being adapted for use in such a manner that a battery body is inserted into the armor body and the peripheral edge of the armor body is then heat sealed for hermetic sealing, said packaging material being a laminate comprising at least a substrate layer, an adhesive layer, a barrier layer, an adhesive resin layer, and a sealant layer, characterized in that
at least the sealant layer comprises a low-fluidity polypropylene layer having low susceptibility to collapse upon exposure to heat and pressure at the time of heat sealing and a high-fluidity polypropylene layer having high susceptibility to collapse upon exposure to heat and pressure at the time of heat sealing, and the innermost layer is the high-fluidity polypropylene layer.
7. The packaging material for a battery according to claim 6 , characterized in that the barrier layer comprises at least a conversion treated layer provided on its adhesive resin layer side.
8. The packaging material for a battery according to claim 6 , characterized in that the sealant layer has a two-layer structure of the low-fluidity polypropylene layer and the high-fluidity polypropylene layer and the high-fluidity polypropylene layer is the innermost layer.
9. The packaging material for a battery according to claim 6 , characterized in that the sealant layer has a three-layer structure of the high-fluidity polypropylene layer, the low-fluidity polypropylene layer, and the high-fluidity polypropylene layer.
10. The packaging material for a battery according to claim 6 , characterized in that the adhesive resin layer is a baked layer of an emulsion of an acid-modified polyolefin, and the sealant layer has been adhered to the baked layer by heat lamination.
11. The packaging material for a battery according to claim 6 , characterized in that the adhesive resin layer is formed of acid-modified polypropylene and the sealant layer has been previously formed and has been stacked onto the adhesive resin layer by sandwich lamination.
12. The packaging material for a battery according to claim 6 , characterized in that the adhesive resin layer is formed of acid-modified polypropylene and the sealant layer has been stacked onto the adhesive resin layer by coextrusion lamination.
13. The packaging material for a battery according to claim 6 , characterized in that an adhesive film is interposed between the armor body for a battery and a lead part in the battery body.
14. A packaging material for forming an armor body for a battery, said armor body being adapted for use in such a manner that a battery body is inserted into the armor body and the peripheral edge of the armor body is then heat sealed for hermetic sealing, said packaging material being a laminate comprising at least a substrate layer, an adhesive layer, aluminum, a conversion treated layer, an adhesive resin layer, and a polypropylene resin-based sealant layer, characterized in that
the adhesive resin layer is formed of a resin having a melt index in the range of 5 to 20 g/10 min.
15. The packaging material for a battery according to claim 14 , characterized in that the adhesive resin layer comprises a polypropylene resin.
16. The packaging material for a battery according to claim 14 , characterized in that the adhesive resin layer comprises acid-modified polypropylene.
17. The packaging material for a battery according to claim 14 , characterized in that the adhesive resin layer comprises an acid-modified polypropylene resin and, added to the acid-modified polypropylene resin, at least one component selected from a low-density polyethylene resin, a low crystalline ethylene-butene-propylene copolymer with a density of 900 kg/M 3 , a noncrystalline ethylene-propylene copolymer, a propylene-α-olefin copolymer, and a rubber component.
18. The packaging material for a battery according to claim 14 , characterized in that the adhesive resin layer is formed of a blend of at least two polypropylene resins with different melt indexes.
19. The packaging material for a battery according to claim 18 , characterized in that at least one of the at least two polypropylene resins constituting the adhesive resin layer is an acid-modified polypropylene resin.
20. The packaging material for a battery according to claim 14 , characterized in that the laminate comprises at least the substrate layer, the adhesive layer, a conversion treated layer ( 1 ), aluminum, a conversion treated layer ( 2 ), the adhesive resin layer, and the polypropylene resin-based sealant layer.
21. A battery characterized by comprising a battery body housed and hermetically sealed into an armor body formed of the packaging material for a battery according to claim 14 .
22. A packaging material for forming an armor body for a battery, said armor body being adapted for use in such a manner that a battery body is inserted into the armor body and the peripheral edge of the armor body is then heat sealed for hermetic sealing, said packaging material being a laminate comprising at least a substrate layer, an adhesive layer 1 , a barrier layer, an adhesive layer 2 , and a sealant layer, characterized in that
the sealant layer comprises one resin layer or a laminate of two or more resin layers comprising metallocene linear low-density polyethylene.
23. The packaging material for a battery according to claim 22 , characterized in that the sealant layer is formed of a metallocene linear low-density polyethylene resin.
24. The packaging material for a battery according to claim 22 , characterized in that the sealant layer is formed of a polyethylene resin containing not less than 10% of a metallocene linear low-density polyethylene resin.
25. The packaging material for a battery according to claim 22 , characterized in that the sealant layer has a multilayer structure comprising at least a layer formed of a metallocene linear low-density polyethylene resin.
26. The packaging material for a battery according to claim 22 , characterized in that the sealant layer has a multilayer structure comprising a polyethylene resin layer containing not less than 10% of a metallocene linear low-density polyethylene resin.
27. The packaging material for a battery according to claim 22 , characterized in that the adhesive layer 2 has been formed by dry lamination.
28. The packaging material for a battery according to claim 22 , characterized in that the adhesive layer 2 is an acid-modified polyolefin coating-baked layer.
29. The packaging material for a battery according to claim 22 , characterized in that the adhesive layer 2 is an extruded layer of an acid-modified polyolefin.