Phospholipid lubricating agents in aqueous based drilling fluids
A method of improving the lubricity of an aqueous based drilling fluid composed of an aqueous base fluid, and a weighting agent. The method involves the addition of an effective amount of a phospholipid to substantially reduce the coefficient of friction when compared to the fluid absent the phospholipids. Preferably the phospholipids have the structure: in which R and R′ are C 6 to C 25 hydrocarbon groups; and A is an anion to counter the cationic charge.
1. A method of drilling a subterranean formation utilizing an aqueous based drilling fluid, wherein the drilling fluid is composed of an aqueous base fluid, and a weighting agent, wherein the weighting agent is a salt selected from the group consisting of alkali metal halides, alkali metal nitrates; alkali metal sulfates, alkali metal formates; alkali metal acetates, alkali metal propionates, alkaline earth metal halides, alkaline earth metal nitrates; alkaline earth metal sulfates, alkaline earth metal formates; alkaline earth metal acetates, alkaline earth metal propionates, rare earth metal halides, rare earth metal nitrates; rare earth metal sulfates, rare earth metal formates; rare earth metal acetates, rare earth metal propionates, transition metal halides, transition metal nitrates; transition metal sulfates, transition metal formates; transition metal acetates, transition metal propionates, and combinations thereof, wherein the improvement comprising, adding an effective amount of one or more phospholipid to substantially reduce the coefficient of friction when compared to the fluid absent the phospholipids, and
wherein the phospholipid has the structure:
in which R and R′ are C 6 to C 25 hydrocarbon groups and A is an anion to counter the cationic charge.
2. The method of claim 1 , wherein the anion is selected from the group consisting of halide, nitrate, sulfate, phosphate, anions of C 1 to C 10 organic acids, and combinations of these.
3. The method of claim 1 , wherein the drilling fluid further includes a solid weighting agents.
4. The method of claim 1 , wherein the drilling fluid further includes a fluid loss control agent.
5. The method of claim 1 , A method of drilling a subterranean formation utilizing an aqueous based drilling fluid, wherein the drilling fluid is composed of an aqueous base fluid, and a weighting agent, wherein the weighting agent is a salt selected from the group consisting of alkali metal halides, alkali metal nitrates; alkali metal sulfates, alkali metal formates; alkali metal acetates, alkali metal propionates, alkaline earth metal halides, alkaline earth metal nitrates; alkaline earth metal sulfates, alkaline earth metal formates; alkaline earth metal acetates, alkaline earth metal propionates, rare earth metal halides, rare earth metal nitrates; rare earth metal sulfates, rare earth metal formates; rare earth metal acetates, rare earth metal propionates, transition metal halides, transition metal nitrates; transition metal sulfates, transition metal formates; transition metal acetates, transition metal propionates, and combinations thereof, wherein the improvement comprising, adding an effective amount of one or more phospholipid to substantially reduce the coefficient of friction when compared to the fluid absent the phospholipids, and wherein the phospholipid is a fatty acid amidopropyl propylene glycol dimonium phosphate salt in which the fatty acid is a C 10 to C 25 fatty acid.
6. The method of claim 5 , wherein the drilling fluid further comprises a solid weighting agent.
7. The method of claim 5 , wherein the drilling fluid further comprises a fluid loss control agent.