Electronic device, dielectric ceramic composition and the production method
A production method of a dielectric ceramic composition having a step of firing dielectric material including a main component ingredient and a subcomponent ingredient, wherein said main component ingredient before firing is barium titanate ingredient powder having the perovskite type crystal structure expressed by ABO 3 , and a ingredient powder having a ratio A/B of A site components and B site components of 1.006≦A/B≦1.035 and the specific surface area of 8 to 50 m 2 /g is used. According to the invention, a dielectric ceramic composition having preferable electric characteristics and temperature characteristic can be provided even in the case of being composed of fine particle and a capacitor made to be a thin layer.
1. A production method of a dielectric ceramic composition having dielectric particles comprising:
preparing a dielectric material including a main component ingredient and a subcomponent ingredient; and
firing said dielectric material, wherein
said subcomponent ingredient contains an oxide of Mg and/or a compound which becomes oxide of Mg after firing, at least one of oxides of Mn and Cr and/or compounds which become oxides of these after firing, one or more of oxides selected from V, W, Ta, and Nb and/or compounds which become oxides of these after firing, oxides of R (note that R is one or more selected from Sc, Er, Tm, Yb, Lu, Y, Dy, Ho, Tb, Gd, and Eu) and/or compounds which become the oxides of R after firing, an oxide of Si and/or a compound which becomes oxide of Si after firing, and at least two of oxides of Ba, Sr, and Ca and/or compounds which become oxides of these after firing;
MgO is in an amount of 0.1 to 3 moles,
MnO+Cr 2 O 3 is in an amount greater than 0 to 0.5 moles,
V 2 O 5 +WO 3 +Ta 2 O 5 +Nb 2 O 5 is in an amount greater than 0 to 0.5 moles,
R 2 O 3 is in an amount greater than 0 to 5 moles,
SiO 2 is in an amount of 0.5 to 12 moles, and
BaO+SrO+CaO is in an amount of 0.5 to 12 moles,
in terms of MgO, MnO, Cr 2 O 3 , V 2 O 5 , WO 3 , Ta 2 O 5 , Nb 2 O 5 , R 2 O 3 , SiO 2 , BaO, SrO, and CaO with respect to 100 moles of the main component ingredient; and
said main component ingredient before firing is barium titanate ingredient powder having the perovskite type crystal structure expressed by ABO 3 , and having a ratio A/B of A site components and B site components of 1.006≦A/B≦1.035 and a specific surface area of 15 to 50 m 2 /g.
2. The production method of a dielectric ceramic composition as set forth claim 1 , wherein:
said oxides of R and/or compounds which become the oxides of R are oxides of one or more selected from Y, Dy, and Ho and/or compounds which become oxides of these after firing.
3. The production method of a dielectric ceramic composition as set forth in claim 1 , wherein:
components of said A site contain Ba and one or more selected from Sr and Ca, and components of said B site contain Ti and optionally Zr in said barium titanate ingredient powder.