Chemical amplification type positive resist composition
A chemical amplification type positive resist composition, which can reduce cost steeply without significantly decreasing basic abilities, is provided, and the chemical amplification type positive resist composition includes (A) a resin having a polymerization unit derived from p-hydroxystyrene and a polymerization unit of the formula (1) or formula (2) which is insoluble or poorly soluble itself in an alkali aqueous solution but becomes soluble in an alkali aqueous solution by the action of an acid, (B) a resin obtained by protecting a portion of the hydroxyl groups in poly(p-hydroxystyrene) with a protective group not dissociating by the action of an acid or a resin obtained by substituting a portion of the hydroxyl groups in poly(p-hydroxystyrene) with hydrogen, and (C) an acid generating agent.
1. A chemical amplification type positive resist composition comprising
(A) a resin having a polymerization unit derived from p-hydroxystyrene and a polymerization unit of the formula (1) or formula (2)
wherein, R 1 and R 2 each independently represent hydrogen or methyl group, and R 3 to R 5 each independently represent an alkyl group having 1 to 8 carbon atoms, wherein the resin is insoluble or poorly soluble itself in an alkali aqueous solution but becomes soluble in an aqueous solution by the action of an acid;
(B) a resin obtained by protecting a portion of hydroxyl groups in poly(p-hydroxystyrene) with a protective group not dissociating by the action of an acid; and
(C) an acid generating agent,
wherein the protective group is an isopropoxy group or 1-pivaloyloxy group.
2. The chemical amplification type positive resist composition according to claim 1 , wherein R 1 and R 2 are methyl, and R 3, R 4 and R 5 are each independently methyl or ethyl.
3. The chemical amplification type positive resist composition according to claim 1 , wherein the resin (B) is obtained by protecting 10 to 50 mol % of hydroxyl groups in poly(p-hydroxystyrene) with a protective group not dissociating by the action of an acid.
4. The chemical amplification type positive resist composition according to claim 1 , which comprises 50 to 90% by weight of (A) a resin component having a polymerization unit derived from p-hydroxystyrene and a polymerization unit of the formula (1) or formula (2), 10 to 50% by weight of (B) a resin component obtained by protecting a portion of hydroxyl groups in poly(p-hydroxystyrene) with a protective group not dissociating by the action of an acid and 0.1 to 20% by weight of an acid generating agent, based on the total solid content.