IP Library › Granted Patent US 7,208,358
Granted Patent B2
US 7,208,358 · App. 11/203,282 · Granted Apr 24, 2007

Laser annealing method

Assignee: Semiconductor Energy Laboratory Co., Ltd.
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Quick Facts
Patent No.
US 7,208,358
App. No.
11/203,282
Granted
Apr 24, 2007
Kind
B2
Abstract

In crystallizing an amorphous silicon film by illuminating it with linear pulse laser beams having a normal-distribution type beam profile or a similar beam profile, the linear pulse laser beams are applied in an overlapped manner. There can be obtained effects similar to those as obtained by a method in which the laser illumination power is gradually increased and then decreased in a step-like manner in plural scans.

Claims (60)

1. A method of manufacturing a thin film transistor comprising:

forming a semiconductor film including amorphous silicon having a thickness of 150 to 1000 Å over a substrate;

emitting a pulse laser light at a rate of N pulses per second;

shaping the pulse laser light into a beam having a cross section perpendicular to a propagation direction of the beam, said cross section having a width and a length, wherein the length is longer than the width, wherein the beam has a normal-distribution type energy profile of width L (m) perpendicular to the length direction, where L is larger than zero, and the beam having substantially a constant energy distribution along a lengthwise direction;

applying the beam to a portion of the semiconductor film; and

scanning the semiconductor film with the beam perpendicular to the lengthwise direction of the cross section at a speed V (m/s) in order to crystallize said semiconductor film,

wherein the number of beams applied to said portion in one scan satisfies a relationship 3≦LN/V≦100, and

wherein the width L (m) is defined as a beam in a region having 5% or more of an energy density with respect to a maximum energy density of the beam on the irradiation surface.

2. The method of claim 1 , wherein the width is 0.1 to 1 cm.

3. The method of claim 1 , wherein the length is 10 to 30 cm.

4. The method of claim 1 , wherein the scanning step is conducted in air.

5. The method of claim 1 , an average single-pulse energy density of the beam is set at 100 to 500 mJ/cm 2 .

6. The method of claim 1 , wherein the pulse laser comprises an excimer laser.

7. The method of claim 1 , wherein the number of beams applied to said portion in one scan satisfies a relationship 10≦LN/V≦30.

8. A method of manufacturing a thin film transistor comprising:

forming a semiconductor film including amorphous silicon having a thickness of 150 to 1000 Å over a substrate;

crystallizing the semiconductor film by performing a heat treatment to the semiconductor film;

emitting a pulse laser light at a rate of N pulses per second;

shaping the pulse laser light into a beam having a cross section perpendicular to a propagation direction of the beam, said cross section having a width and a length, wherein the length is longer than the width, wherein the beam has a normal-distribution type energy profile of width L (m) perpendicular to the length direction, where L is larger than zero, and the beam having substantially a constant energy distribution along a lengthwise direction;

applying the beam to a portion of the crystallized semiconductor film; and

enhancing a crystallinity of the crystallized semiconductor film by scanning with the beam perpendicular to the length direction of the cross section at a speed V (m/s),

wherein the number of beams applied to said portion in one scan satisfies a relationship 3≦LN/V≦100, and

wherein the width L (m) is defined as a beam in a region having 5% or more of an energy density with respect to a maximum energy density of the beam on the irradiation surface.

9. The method of claim 8 , wherein the width is 0.1 to 1 cm.

10. The method of claim 8 , wherein the length is 10 to 30 cm.

11. The method of claim 8 , wherein the scanning step is conducted in air.

12. The method of claim 8 , an average single-pulse energy density of the beam is set at 100 to 500 mJ/cm 2 .

13. The method of claim 8 , wherein the pulse laser comprises an excimer laser.

14. The method of claim 8 , wherein the number of beams applied to said portion in one scan satisfies a relationship 10≦LN/V≦30.

15. A method of manufacturing a thin film transistor comprising:

forming a semiconductor film including amorphous silicon having a thickness of 150 to 1000 Å over a substrate;

emitting a pulse laser light at a rate of N pulses per second;

shaping the pulse laser light into a beam having a cross section perpendicular to a propagation direction of the beam, said cross section having a width and a length, wherein the length is longer than the width, wherein the beam has a trapezoidal energy profile of width L (m) perpendicular to the length direction, where L is larger than zero, and the beam having substantially a constant energy distribution along a lengthwise direction;

applying the beam to a portion of the semiconductor film; and

scanning the semiconductor film with the beam perpendicular to the lengthwise direction of the cross section at a speed V (m/s) in order to crystallize said semiconductor film,

wherein the number of beams applied to said portion in one scan satisfies a relationship 3≦LN/V≦100, and

wherein the width L (m) is defined as a beam in a region having 5% or more of an energy density with respect to a maximum energy density of the beam on the irradiation surface.

16. The method of claim 15 , wherein the width is 0.1 to 1 cm.

17. The method of claim 15 , wherein the length is 10 to 30 cm.

18. The method of claim 15 , wherein the scanning step is conducted in air.

19. The method of claim 15 , an average single-pulse energy density of the beam is set at 100 to 500 mJ/cm 2 .

20. The method of claim 15 , wherein the pulse laser comprises an excimer laser.

21. The method of claim 15 , wherein the number of beams applied to said portion in one scan satisfies a relationship 10≦LN/V≦30.

22. The method of claim 15 , wherein the beam has substantially a constant energy distribution along the direction.

23. A method of manufacturing a thin film transistor comprising:

forming a semiconductor film including amorphous silicon having a thickness of 150 to 1000 Å over a substrate;

crystallizing the semiconductor film by performing a heat treatment to the semiconductor film;

emitting a pulse laser light at a rate of N pulses per second;

shaping the pulse laser light into a beam having a cross section perpendicular to a propagation direction of the beam, said cross section having a width and a length, wherein the length is longer than the width, wherein the beam has a trapezoidal energy profile of width L (m) perpendicular to the length direction, where L is larger than zero, and the beam having substantially a constant energy distribution along a lengthwise direction;

applying the beam to a portion of the crystallized semiconductor film; and

enhancing a crystallinity of the crystallized semiconductor film by scanning with the beam perpendicular to the lengthwise direction of the cross section at a speed V (m/s),

wherein the number of beams applied to said portion in one scan satisfies a relationship 3≦LN/V≦100, and

wherein the width L (m) is defined as a beam in a region having 5% or more of an energy density with respect to a maximum energy density of the beam on the irradiation surface.

24. The method of claim 23 , wherein the width is 0.1 to 1 cm.

25. The method of claim 23 , wherein the length is 10 to 30 cm.

26. The method of claim 23 , wherein the scanning step is conducted in air.

27. The method of claim 23 , an average single-pulse energy density of the beam is set at 100 to 500 mJ/cm 2 .

28. The method of claim 23 , wherein the pulse laser comprises an excimer laser.

29. The method of claim 23 , wherein the number of beams applied to said portion in one scan satisfies a relationship 10≦LN/V≦30.

30. The method of claim 23 , wherein the beam has substantially a constant energy distribution along the direction.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 15, 2005
From: KUSUMOTO, NAOTO; TANAKA, KOICHIRO
To: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Reel/Frame 016894/0891 →
Priority Claims (2)
JP 7-037705 · Feb 2, 1995 · national
JP 7-068670 · Mar 2, 1995 · national
Continuity (3)
Continuation 1060276200 · Jun 25, 2003
Continuation 0859467000 · Feb 2, 1996
Related Publication 20060030166A1 · Feb 9, 2006