Chemical conversion film of tantalum or niobium, method for forming the same and electrolytic capacitor using the same
The present invention provides an electrolytic capacitor that operates stably even when used for a long period of time under severe conditions, and forms an intermediate composition portion of metal and oxide within a chemical conversion film to a thickness of 40 nm or more so as to suppress the migration of oxygen atoms within a chemical conversion film of a valve metal. This intermediate composition portion is obtained by subjecting a base metal comprised by containing nitrogen in a valve action metal to anodic oxidation treatment.
1. A chemical conversion film comprising an intermediate composition portion of (a) tantalum and tantalum oxide or (b) niobium and niobium oxide wherein the intermediate portion has a thickness of 40 nm or more, and wherein the intermediate portion is located between an upper portion having a higher oxygen concentration and a lower portion having a lower oxygen concentration.
2. A chemical conversion film of tantalum or niobium according to claim 1 , wherein the intermediate composition portion contains nitrogen.
3. An electrolytic capacitor having the chemical conversion film of tantalum or niobium according to claim 2 .
4. The chemical conversion film of claim 2 , wherein said intermediate portion is tantalum and tantalum oxide.
5. An electrolytic capacitor having the chemical conversion film of tantalum or niobium according to claim 1 .
6. The electrolytic capacitor of claim 5 , wherein the chemical conversion film is tantalum and tantalum oxide and is located on a base material of tantalum.
7. The electrolytic capacitor of claim 6 , wherein said base material of tantalum has a nitrogen content.
8. The electrolytic capacitor of claim 7 , wherein said nitrogen content is from 2,000 ppm to 12,000 ppm.
9. The electrolytic capacitor of claim 6 , wherein said base material of tantalum is a powdered, sintered compact of tantalum.
10. The electrolytic capacitor of claim 6 , wherein said base material of tantalum is tantalum foil.
11. A method for forming the chemical conversion film of claim 1 comprising chemical conversion treatment of a base material of tantalum when forming a chemical conversion film of tantalum, or niobium when forming a chemical conversion film of niobium having a nitrogen content of 2000 ppm to 12000 ppm.
12. A method for forming a chemical conversion film of tantalum or niobium according to claim 11 , wherein the base material of the tantalum or niobium is a powdered sintered compact.
13. The chemical conversion film of claim 1 , wherein said upper portion has an oxygen concentration of 60 atomic percent or more.
14. The chemical conversion film of claim 1 , wherein said lower portion has an oxygen concentration of 10 atomic percent or less.
15. The chemical conversion film of claim 1 , wherein said intermediate portion has an oxygen concentration of from about 60 atomic percent to 10 atomic percent.
16. The chemical conversion film of claim 1 , wherein said thickness is 80 nm or more.
17. The chemical conversion film of claim 1 , wherein said thickness is 40 nm to 129 nm.
18. The chemical conversion film of claim 1 , wherein said thickness is 100 nm or more.
19. The chemical conversion film of claim 1 , wherein said intermediate portion accounts for 40% to 60% of the overall thickness of the chemical conversion film.
20. The chemical conversion film of claim 1 , wherein said intermediate portion is tantalum and tantalum oxide.
21. The chemical conversion film of claim 1 , wherein said lower portion has a thickness of from 5 to 30 nm.