IP Library Granted Patent US 7,227,176
Granted Patent B2
US 7,227,176 · App. 10/603,852 · Granted Jun 5, 2007

Etch stop layer system

Assignees: Massachusetts Institute of Technology; The Charles Stark Draper Laboratory, Inc.
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Quick Facts
Patent No.
US 7,227,176
App. No.
10/603,852
Granted
Jun 5, 2007
Kind
B2
Abstract

A semiconductor structure including a uniform etch-stop layer. The uniform etch stop layer has a relative etch rate which is less than approximately the relative etch rate of Si doped with 7×10 19 boron atoms/cm 3 . A method for forming a semiconductor structure includes forming a uniform etch-stop layer providing a handle wafer, and bonding the uniform etch-stop layer to the handle wafer. The uniform etch-stop layer has a relative etch rate which is less than approximately the relative etch rate of Si doped with 7×10 19 boron atoms/cm 3 .

Claims (194)

1. A semiconductor structure comprising:

a layer structure comprising a uniform etch-stop layer having a doping level below 10 18 atoms/cm 3 and a substantially relaxed graded layer,

wherein the uniform etch-stop layer comprises substantially relaxed Si 1−y and y>0.19.

2. A semiconductor structure comprising:

a layer structure including a uniform etch-stop layer having a doping level below 10 18 atoms/cm 3 ,

wherein the layer structure comprises a substantially relaxed layer disposed under the uniform etch-stop layer and a first strained layer disposed over the uniform etch-stop layer.

3. The semiconductor structure of claim 2 , wherein the first strained layer comprises Si 1−z Ge z and 0≦z<1.

4. A semiconductor structure, comprising

a layer structure including a strained Si 1−z Ge z layer, and

a handle wafer comprising an insulator, the layer structure being bonded to the handle wafer,

wherein 0≦z<1, the layer structure includes a substantially relaxed uniform etch-stop layer disposed over a substantially relaxed layer comprising graded Si 1−x Ge x , the strained Si 1−z Ge z layer is disposed over the uniform etch-stop layer, and the uniform etch-stop layer has a relative etch rate which is less than approximately the relative etch rate of Si doped with 7×10 19 boron atoms/cm 3 .

5. A semiconductor structure comprising:

a layer structure including a strained Si 1−z Ge z layer;

a handle wafer comprising an insulator, the layer structure being bonded to the handle wafer; and

an insulator layer disposed over the layer structure,

wherein 0≦z<1, the layer structure includes a substantially relaxed uniform etch-stop layer disposed over a substantially relaxed layer, the strained Si 1−z Ge z layer is disposed over the uniform etch-stop layer, and the uniform etch-stop layer has a relative etch rate which is less than approximately the relative etch rate of Si doped with 7×10 19 boron atoms/cm 3 .

6. A semiconductor structure comprising:

a layer structure including a strained Si 1−z Ge z layer; and

a handle wafer comprising an insulator, the layer structure being bonded to the handle wafer,

wherein 0≦z<1, the layer structure comprises a substantially relaxed uniform etch-stop layer and substantially relaxed graded layer disposed over the substantially relaxed layer, the strained Si 1−z Ge z layer is disposed over the uniform etch-stop layer, and the uniform etch-stop layer has a relative etch rate which is less than approximately the relative etch rate of Si doped with 7×10 19 boron atoms/cm 3 .

7. The semiconductor structure of claim 6 , wherein the substantially relaxed graded layer comprises Si 1−x Ge x .

8. A semiconductor structure comprising:

a first uniform etch-stop layer;

a second etch-stop layer disposed over the uniform etch-stop layer;

a substantially relaxed layer disposed over the second etch-stop layer;

a substrate disposed over the relaxed layer; and

an insulator layer disposed over the substantially relaxed layer, between the relaxed layer and the substrate,

wherein the first uniform etch-stop layer has a relative etch rate which is less than approximately the relative etch rate of Si doped with 7×10 19 boron atoms/cm 3 .

9. A semiconductor structure comprising:

a first uniform etch-stop layer;

a second etch-stop layer disposed over the uniform etch-stop layer;

a substantially relaxed layer disposed over the second etch-stop layer; and

a substantially relaxed graded layer,

wherein the first uniform etch-stop layer is disposed over the graded layer and the first uniform etch-stop layer has a relative etch rate which is less than approximately the relative etch rate of Si doped with 7×10 19 boron atoms/cm 3 .

10. The semiconductor structure of claim 9 , wherein the substantially relaxed graded layer comprises Si 1−x Ge x .

11. The semiconductor structure of claim 9 , further comprising:

a first substrate,

wherein the substantially relaxed graded layer is disposed on the first substrate.

12. A method for forming a semiconductor structure, the method comprising:

forming a uniform etch-stop layer;

providing a handle wafer; and

bonding the uniform etch-stop layer directly to the handle wafer,

wherein said uniform etch-stop layer has a relative etch rate which is less than approximately the relative etch rate of Si doped with 7×10 19 boron atoms/cm 3 .

13. The method of claim 12 , wherein the uniform etch-stop layer comprises substantially relaxed Si 1−y Ge y .

14. The method of claim 12 , further comprising:

planarizing a surface of the uniform etch-stop layer prior to bonding.

15. A method for forming a semiconductor structure, the method comprising:

forming a uniform etch-stop layer;

providing a handle wafer;

bonding the uniform etch-stop layer to the handle wafer; and

forming a substantially relaxed graded layer before forming the uniform etch-stop layer,

wherein the uniform etch-stop layer is formed over the substantially relaxed graded layer and said uniform etch-stop layer has a relative etch rate which is less than approximately the relative etch rate of Si doped with 7×10 19 boron atoms/cm 3 .

16. The method of claim 15 , wherein the relaxed graded layer comprises Si 1−x Ge x .

17. The method of claim 15 , further comprising:

releasing the etch-stop layer by removing at least a portion of the graded layer.

18. The method of claim 15 , wherein releasing the etch-stop layer comprises a wet etch.

19. The method of claim 15 , further comprising:

providing a semiconductor substrate,

wherein the substantially relaxed graded layer is formed over the semiconductor substrate.

20. A method for forming a semiconductor substrate, the method comprising:

providing a first substrate;

forming a layer structure over the first substrate by:

forming a uniform etch-stop layer over the first substrate; and

forming a strained layer over the uniform etch-stop layer; and

releasing the strained layer by removing at least a portion of the uniform etch-stop layer,

wherein the uniform etch-stop layer has a relative etch rate which is less than approximately the relative etch rate of Si doped with 7×10 19 boron atoms/cm 3 .

21. The method of claim 20 , wherein releasing the strained layer comprises a wet etch.

22. A method comprising:

providing a first substrate;

forming a layer structure over the first substrate by:

forming a substantially relaxed graded layer over the first substrate;

forming a uniform etch-stop layer over the graded layer;

forming a strained layer over the uniform etch-stop layer; and

releasing the strained layer by removing at least a portion of the graded layer and at least a portion of the uniform etch-stop layer,

wherein the uniform etch-stop layer has a relative etch rate which is less than approximately the relative etch rate of Si doped with 7×10 19 boron atoms/cm 3 .

23. The method of claim 22 , wherein releasing the strained layer comprises a wet etch.

24. A method for forming a semiconductor structure, the method comprising:

forming a layer structure by:

forming a uniform etch-stop layer; and

forming a strained Si 1−z Ge z layer over the uniform etch-stop layer, and

bonding the layer structure to a handle wafer comprising an insulator; and

releasing the strained layer by removing at least a portion of the uniform etch-stop layer,

wherein 0≦z<1 and the uniform etch-stop layer has a relative etch rate which is less than approximately the relative etch rate of Si doped with 7×10 19 boron atoms/cm 3 .

25. The method of claim 24 , wherein releasing the strained layer comprises a wet etch.

26. A method for forming a semiconductor structure, the method comprising:

forming a layer structure by:

forming a substantially relaxed graded layer;

forming a uniform etch-stop layer over the substantially graded layer; and

forming a strained Si 1−z Ge z layer over the uniform etch-stop layer, and

bonding the layer structure to a handle wafer comprising an insulator,

wherein 0≦z<1 and the uniform etch-stop layer has a relative etch rate which is less than approximately the relative etch rate of Si doped with 7×10 19 boron atoms/cm 3 .

27. The method of claim 26 , wherein the relaxed graded layer comprises Si 1−x Ge x .

28. The method of claim 26 , further comprising:

releasing the strained layer by removing at least a portion of the graded layer and at least a portion of the uniform etch-stop layer.

29. The method of claim 28 , wherein releasing the strained layer comprises a wet etch.

30. The method of claim 26 , further comprising:

forming an insulator layer over the layer structure.

31. The method of claim 26 , further comprising:

providing a substrate,

wherein the layer structure is formed over the substrate.

32. The method of claim 31 , further comprising:

releasing the strained layer by removing at least a portion of the substrate, at least a portion of the graded layer, and at least a portion of the uniform etch-stop layer.

33. The method of claim 32 , wherein releasing the strained layer comprises a wet etch.

34. A method for forming a semiconductor structure, the method comprising:

forming a strained etch-stop layer; and

forming a substantially relaxed Si 1−w Ge w layer directly over and in contact with the etch-stop layer,

wherein w>0, the etch-stop layer comprises Si 1−z , Ge z , and z=0.

35. A method for forming a semiconductor structure, the method comprising:

forming a first uniform etch-stop layer;

forming a second etch-stop layer over the uniform etch-stop layer; and

forming a substantially relaxed layer over the second etch-stop layer,

wherein the first uniform etch-stop layer has a relative etch rate which is less than approximately the relative etch rate of Si doped with 7×10 19 boron atoms/cm 3 , the second etch-stop layer comprises strained Si 1−z Ge z , and z=0.

36. A method for forming a semiconductor structure, the method comprising:

forming a first uniform etch-stop layer;

forming a second etch-stop layer over the uniform etch-stop layer;

forming a substantially relaxed layer over the second etch-stop layer;

bonding the substantially relaxed layer to a substrate comprising an insulator; and

releasing the second etch-stop layer by removing at least a portion of the first etch-stop layer,

wherein the first uniform etch-stop layer has a relative etch rate which is less than approximately the relative etch rate of Si doped with 7×10 19 boron atoms/cm 3 .

37. The method of claim 36 , wherein releasing the second etch-stop layer comprises a wet etch.

38. The method of claim 36 , further comprising:

releasing the substantially relaxed layer by removing at least a portion of the second etch-stop layer.

39. The method of claim 36 , wherein releasing the substantially relaxed layer comprises a wet etch.

40. A method for forming a semiconductor structure, the method comprising:

forming a first uniform etch-stop layer;

forming a second etch-stop layer over the uniform etch-stop layer; and

forming a substantially relaxed layer over the second etch-stop layer,

forming a substantially relaxed graded layer,

wherein the first uniform etch-stop layer has a relative etch rate which is less than approximately the relative etch rate of Si doped with 7×10 19 boron atoms/cm 3 , and the first uniform etch-stop layer is formed on the graded layer.

41. The method of claim 40 , wherein the substantially relaxed graded layer comprises Si 1−x Ge x .

42. The method of claim 40 , further comprising:

bonding the substantially relaxed layer to a substrate comprising an insulator.

43. The method of claim 40 , further comprising:

releasing the first etch-stop layer by removing at least a portion of the relaxed graded layer.

44. The method of claim 43 ,

wherein releasing the first etch-stop layer comprises a wet etch.

45. The method of claim 43 , further comprising:

releasing the second etch-stop layer by removing at least a portion of the first etch-stop layer.

46. The method of claim 45 , further comprising:

releasing the relaxed layer by removing at least a portion of the second etch-stop layer.

47. The method of claim 46 , wherein releasing the relaxed layer comprises a wet etch.

48. The method of claim 43 , wherein releasing the second etch-stop layer comprises a wet etch.

49. A method for forming a semiconductor structure, the method comprising:

providing a first substrate; and

forming a layer structure over the first substrate by:

forming a substantially relaxed graded layer over the first substrate,

forming a first uniform etch-stop layer over the graded layer,

forming a second etch-stop layer over the uniform etch-stop layer, and

forming a substantially relaxed layer over the second etch-stop layer,

wherein the first uniform etch-stop layer has a relative etch rate which is less than approximately the relative etch rate of Si doped with 7×10 19 boron atoms/cm 3 , and the layer structure comprises the substantially relaxed graded layer, the first uniform etch-stop layer, the second etch-stop layer, and the substantially relaxed layer.

50. The method of claim 49 , wherein the substantially relaxed graded layer comprises Si 1−x Ge x .

51. The method of claim 49 , wherein the first uniform etch-stop layer comprises substantially relaxed Si 1−y G y , the second etch-stop layer comprises strained Si 1−z Ge z , 0≦z<1, and the substantially relaxed layer comprises Si 1−w Ge w .

52. The method of claim 49 , further comprising:

bonding the layer structure to a second substrate including an insulator.

53. The method of claim 52 , wherein the second substrate comprises a material selected from the group consisting of silicon, glass, quartz, and silicon dioxide.

54. The method of claim 49 , the method further comprising:

releasing the first etch-stop layer by removing at least a portion of the first substrate and at least a portion of the graded layer; and

releasing the second etch-stop layer by removing at least a portion of the first etch-stop layer.

55. The method of claim 54 , further comprising:

bonding the layer structure to a second substrate prior to releasing the first etch-stop layer.

56. The method of claim 54 , further comprising:

releasing at least a portion of the relaxed layer by removing at least a portion of the second etch-stop layer.

57. A method for forming a semiconductor structure, the method comprising:

providing a first substrate;

forming a layer structure on the first substrate by:

forming a substantially relaxed graded layer on the first substrate; and

forming a uniform etch-stop layer on the graded layer; and

releasing the etch-stop layer by removing at least a portion of the substrate and at least a portion of the graded layer,

wherein the uniform etch-stop layer of Si 1−y Ge y has a relative etch rate which is less than approximately the relative etch rate of Si doped with 7×10 19 borons/cm 3 .

58. The method of claim 57 , wherein the substantially relaxed graded layer comprises Si 1−x Ge x .

59. The method of claim 57 , wherein the uniform etch-stop layer comprises substantially relaxed Si 1−y Ge y .

60. The method of claim 57 , further comprising:

bonding the layer structure to a second substrate prior to releasing the etch-stop layer.

61. A semiconductor structure comprising:

a layer structure including a uniform etch-stop layer having a doping level below 10 18 atoms/cm 3 ,

wherein the etch-stop layer comprises n-type dopants.

62. A semiconductor structure comprising:

a layer structure including a uniform etch-stop layer,

wherein the etch-stop layer comprises p-type dopants and the doping level is below 4×10 16 atoms/cm 3 .

63. A method for forming a semiconductor structure, the method comprising:

forming a layer structure including a uniform etch-stop layer;

providing a handle wafer; and

bonding the layer structure directly to the handle wafer,

wherein said uniform etch-stop layer has a relative etch rate which is less than approximately the relative etch rate of Si doped with 7×10 19 boron atoms/cm 3 .

64. A semiconductor structure comprising:

a layer structure comprising a uniform etch-stop layer, the etch-stop layer comprising SiGe and having a doping level below 10 18 atoms/cm 3 , and a substantially relaxed layer,

wherein the relaxed layer is graded.

65. A semiconductor structure comprising:

a layer structure comprising a uniform etch-stop layer, the etch-stop layer comprising SiGe and having a doping level below 10 18 atoms/cm 3 , and a substantially relaxed layer comprising Si 1−x Ge x ,

wherein the relaxed layer is graded and x<0.2.

66. A method for forming a semiconductor structure comprising:

providing a first substrate; and

forming a layer structure over the first substrate by:

forming a substantially relaxed graded layer over the first substrate, and forming a uniform etch-stop layer over the graded layer, the uniform etch-stop layer comprising SiGe and having a doping level below 10 18 atoms/cm 3 .

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 18, 2010
From: MASSACHUSETTS INSTITUTE OF TECHNOLOGY
To: THE CHARLES STARK DRAPER LABORATORY, INC.
Reel/Frame 024402/0009 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 31, 2004
From: BORENSTEIN, JEFFREY T.
To: CHARLES STARK DRAPER LABORATORY, INC., THE
Reel/Frame 015157/0757 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 31, 2004
From: WU, KENNETH C.; FITZGERALD, EUGENE A.; TARASCHI, GIANNI
To: MASSACHUSETTS INSTITUTE OF TECHNOLOGY
Reel/Frame 015157/0761 →
Continuity (4)
Continuation 0959926000 · Jun 22, 2000
Continuation In Part 0928951400 · Apr 9, 1999
Provisional Application 6008130100 · Apr 10, 1998
Related Publication 20040000268A1 · Jan 1, 2004