Red color emitting compounds for organic electroluminescent device and an organic electroluminescent device using them
The present invention relates to red color emitting compounds for an organic electroluminescent device (OELD), particularly to red color emitting compounds represented by the following formula (1) having high luminescence efficiency and enhanced thermal-stability: R 1 —CH═CH—X—CH═CH—R 2 wherein, R 1 , R 2 and X each are as defined below.
1. A compound represented by the following formula (1):
R 1 —CH═CH—X—CH═CH—R 2
wherein,
X is
R 1 , R 2 and R 3 each are independently formula (2), formula (3), or formula (4) or formula (5), with the proviso that R 1 and R 2 each are not formula (5) when x is 1,4-dicyanophenyl, and at least one of R 1 , R 2 and R 3 are not formula (5) when X is 1,3,5-tricyanophenyl,
wherein,
R 4 , R 5 , R 6 , R 7 , R 8 and R 9 each are independently a hydrogen atom, a halogen group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted alkyl group, or a substituted or unsubstituted allyl group.
2. The compound according to claim 1 , wherein the compound is selected from the group consisting of:
3. An organic electroluminescent device having one or more organic thin layers formed between a first electrode and a second electrode, wherein at least any one layer of the organic thin layers comprises one or more compounds represented by the following formula (1):
R 1 —CH═CH—X—CH═CH—R 2
wherein,
X is
R 1 , R 2 and R 3 each are independently formula (2), formula (3), or formula (4) or formula (5), with the proviso that R 1 and R 2 each are not formula (5) when x is 1,4-dicyanophenyl,
wherein
R 4 , R 5 , R 6 , R 7 , R 8 and R 9 each are independently a hydrogen atom, a halogen group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted alkyl group, or a substituted or unsubstituted allyl group.
4. The organic electroluminescent device according to claim 3 , wherein the organic thin layer comprises one or more layers selected from the group consisting of a hole transport layer, an emission layer, a hole blocking layer, an electron transport layer, and an electron injection layer.
5. The organic electroluminescent device according to claim 4 , wherein at least one or more compounds represented by the formula (1):
R 1 —CH═CH—X—CH═CH—R 2
wherein,
X is
R 1 , R 2 and R 3 each are independently formula (2), formula (3), or formula (4) or formula (5), with the proviso that R 1 and R 2 each are not formula (5) when x is 1,4-dicyanophenyl,
wherein,
R 4 , R 5 , R 6 , R 7 , R 8 and R 9 each are independently a hydrogen atom, a halogen group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted alkyl group, or a substituted or unsubstituted allyl group are used as dopant of the emission layer.
6. The organic electroluminescent device according to claim 4 , wherein at least one or more compounds represented by the formula (1):
R 1 —CH═CH—X—CH═CH—R 2
wherein,
X is
R 1 , R 2 and R 3 each are independently formula (2), formula (3), or formula (4) or formula (5), with the proviso that R 1 and R 2 each are not formula (5) when x is 1,4-dicyanophenyl,
wherein,
R 4 , R 5 , R 6 , R 7 , R 8 and R 9 each are independently a hydrogen atom, a halogen group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted alkyl group, or a substituted or unsubstituted allyl group are used as host of the emission layer.
7. The organic electroluminescent device according to claim 4 , wherein at least one or more compounds represented by the formula (1):
R 1 —CH═CH—X—CH═CH—R 2
wherein,
X is
R 1 , R 2 and R 3 each are independently formula (2), formula (3), or formula (4) or formula (5), with the proviso that R 1 and R 2 each are not formula (5) when x is 1,4-dicyanophenyl,
wherein,
R 4 , R 5 , R 6 , R 7 , R 8 and R9 each are independently a hydrogen atom, a halogen group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted alkyl group, or a substituted or unsubstituted allyl group are used as both host and dopant of the emission layer.