Analysis of elemental composition and thickness in multilayered materials
A method and computer program software product for establishing an areal density of an elemental constituent of one layer of a stack of layers of material overlying a substrate. Incident penetrating radiation excites characteristic x-ray fluorescent radiation in multiple lines associated with each of one or more elements. Areal densities of successive layers are determined by self-consistent solution of equations relating the ratios of intensities of the characteristic fluorescence lines of successive elements.
1. A method for establishing an areal density of an elemental constituent of a plurality of layers of material in a multilayer structure comprising a plurality of layers of material, the method comprising:
irradiating a calibration sample of known elemental composition with penetrating radiation;
calibrating absolute intensities of at least a first and a second x-ray characteristic fluorescence lines emitted by the calibration sample from a single element or two elements present in at least a layer of the multilayer structure;
irradiating the multilayer structure with penetrating radiation;
detecting fluorescent radiation emanating from the layer;
determining a fluorescence intensity at each of the first and second characteristic fluorescence lines;
solving separately for the areal densities of the elemental constituents of the layer and absorption due to overlayers on the basis of known differential functional dependence of absorption at energies of the first and second characteristic fluorescence lines; and
repeating the step of solving with respect to a second layer of the multilayer structure.
2. A method in accordance with claim 1 , wherein the step of solving includes successive solution for areal density and absorption, layer by layer.
3. A method in accordance with claim 1 , further including dividing the areal density of a layer by a known density of the elemental constituent in such a manner as to obtain a thickness of the layer.
4. A computer program product for use on a computer system for establishing an areal density of an elemental constituent of a plurality of layers of material among a stack comprising a plurality of layers of material, the computer program product comprising a computer usable medium having computer readable program code thereon, the computer readable program code including:
program code for calibrating absolute intensities of at least a pair of x-ray characteristic fluorescence lines emitted by a calibration sample irradiated by a beam of penetrating radiation; and
program code for solving separately for the areal densities of the elemental constituents of a layer and absorption due to overlayers on the basis of known differential functional dependence of absorption at energies of the first and second characteristic fluorescence lines.
5. A method for establishing an areal density of an elemental constituent of a plurality of layers of material in an entire multilayer structure comprising a plurality of layers of material, the method comprising:
irradiating a calibration sample of known elemental composition with penetrating radiation;
calibrating absolute intensities of at least a first and a second x-ray characteristic fluorescence lines emitted by the calibration sample from a single element or two elements present in at least a layer of the multilayer structure;
irradiating the multilayer structure with penetrating radiation;
detecting fluorescent radiation emanating from the layer;
determining a fluorescence intensity at each of the first and second characteristic fluorescence lines;
solving separately for the areal density of an elemental constituent of the layer and absorption due to overlayers on the basis of known differential functional dependence of absorption at energies of the first and second characteristic fluorescence lines prior to any solution, exact or approximate, for the entire multilayer structure; and
repeating the step of solving with respect to a second layer of the multilayer structure.
6. A method in accordance with claim 5 , wherein the step of solving includes successive solution for areal density and absorption, layer by layer.
7. A method in accordance with claim 5 , further including dividing the areal density of the layer by a known density of the elemental constituent in such a manner as to obtain a thickness of the layer.