IP Library › Granted Patent US 7,316,994
Granted Patent B2
US 7,316,994 · App. 10/695,282 · Granted Jan 8, 2008

Perfume polymeric particles

Assignee: The Procter & Gamble Company
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Quick Facts
Patent No.
US 7,316,994
App. No.
10/695,282
Granted
Jan 8, 2008
Kind
B2
Abstract

Perfume polymeric particles, polymeric particles having affinities for certain perfume raw materials, compositions containing them and methods for making the same are provided.

Claims (18)

1. A method for making an aqueous fabric softening compostion having pH from about 2 to about 8 with improved delivery of perfume raw material, said method comprising preparing a perfume polymeric particle by mixing:

a) a polymeric particle comprising a monomer which is in its protonated cationic form in aqueous media at a pH within the range of about 2 to about 8 having the formula:

wherein each of R 1 , R 2 and R 3 are independently selected from hydrogen or C 1 to C 6 alkyl; T is a carboxylic moiety; Z is —(CH 2 )—; z is 2; A is NR 6 R 7 wherein R 6 and R 7 are independently selected from H, C 1 -C 8 linear or branched alkyl, or alkyleneoxy having the formula:

—(R 9 O) y R 10

wherein R 9 is C 2 -C 4 linear or branched alkylene, carbonyl alkyl, or mixtures thereof; R 10 is hydrogen, C 1 -C 4 alkyl carbonyl alkyl, or mixtures thereof; y is an integer from 1 to 10; and

b) a perfume comprising a perfume raw material having a Kovats Index value of from about 1000 to about 1400 and optionally one or more of the following characteristics:

a molecular weight of less than about 200;

a boiling point of less than about 250° C.; or

a ClogP of less than about 3;

wherein the polymeric particle has a net cationic charge at a pH from about 2 to about 8 from about 20 mV to about 80 mV, a particle size in the range from about 100 nanometers to about 50 micrometers and a Response Factor (RF) of the perfume polymeric material is at least about 1.5, as measured by Longevity Test Protocols I or II, said perfume being non-encapsulated by and non-polymerically associated with the polymer, and

c) adding said perfume polymeric particles to a product matrix comprising a fabric softening agent.

2. The method according to claim 1 wherein the cationic monomer of said polymer is dimethylaminoethyl methacrylate.

3. The method according to claim 1 wherein the polymeric particle further comprises a non-cationic monomer.

4. The method according to claim 3 wherein the non-cationic monomer is selected from the group consisting of: methyl methacrylate, methyl acrylate, ethyl acrylate, n-propyl acrylate, iso-propyl acrylate, n-butyl acrylate, isobutyl acrylate, hydroxyethyl acrylate, hydroxypropyl acrylate, benzyl acrylate, ethylhexyl acrylate, n-propyl methacrylate, ethyl methacrylate, iso-propyl methacrylate, isobutyl methacrylate, n-butyl methacrylate, methacrylic acid, acrylic acid, acrylamide, methacrylamide, styrene, α-methyl styrene, hydroxyethyl methacrylate, hydroxypropyl methacrylate, hydroxybutyl acrylate, hydroxybutyl methacrylate, PEG acrylate, phenyl methacrylamide, t-butyl methacrylamide, p-hydroxyphenyl methacrylamide, vinyl ethers, vinyl ketones, vinyl acetates, vinyl phenols, acylamido-2-methylpropanesulfonic acid, vinlysulfonate, vinylpropionate, methylallylsulfonic acid, N-vinyl formamide and N-vinylpyrrolidone, and mixtures thereof.

5. The method according to claim 1 wherein the perfume polymeric particle has an average particle size of from about 1 μm to about 39 μm.

6. The method according to claim 1 wherein the perfume polymeric particle has an average particle size of from about 200 nm to about 900 nm.

7. The method according to claim 1 wherein the polymer is a water-insoluble polymer.

8. The method according to claim 1 wherein the perfume raw material comprises at least about 10% by weight of the perfume.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 12, 2003
From: JORDAN, GLENN THOMAS IV; KLUESENER, BERNARD WILLIAM; SIVIK, MARK ROBERT; SANTAMARINA, VICENTE; DYKSTRA, ROBERT RICHARD; LEBEDEV, NATALIA; GALLON, LOIS SARA; BAKER, ELLEN SCHMIDT; AMRHEIN, PATFICK; BOECKH, DIETER; FRENZEL, STEFAN; JAHNS, EKKEHARD; SCHWENDEMANN, VOLKER
To: PROCTER & GAMBLE COMPANY, THE; BASF AKTIENGELLSCHAFT
Reel/Frame 014191/0482 →
Continuity (2)
Provisional Application 6042310700 · Nov 1, 2002
Related Publication 20040110648A1 · Jun 10, 2004