Highly filled polymer compositions
This invention pertains to highly filled polymer compositions comprising a low molecular weight ethylene and/or alpha olefin homopolymers and copolymers, or blends therefrom, filled with high concentrations of fillers or additives. Examples of such fillers or additives include fire retardants, talc, ceramic manufacturing agents, color concentrates, crosslinking agents, and blowing agents. Because of the low crystallinity (and therefore high percentage of amorphous phase) and low viscosities of the base polymers, highly processable compositions can be formed containing even if containing relatively high loadings of fillers or additives. Such highly filled compositions are thus ideally suited as concentrates or masterbatch formulations for a variety of different compounding applications.
1. A polymer composition comprising a blend of Component A) and Component B);
A) one or more fillers, present in an amount greater than, or equal to, 40 percent by weight (based on the combined weights of Component A and B); and
B) one or more base polymers present in an amount less than 60 percent by weight (based on the combined weights of Component A and B); and
wherein said one or more base polymers are homogeneous ethylene/C3-C20 alpha-olefin interpolymers, and have
1) a total crystallinity from 0 to 30 percent; and
2) a Brookfield viscosity from 500 to 50,000 cP, measured at 350° F. (177° C.).
2. The polymer composition of claim 1 , wherein;
A) Component A is present in an amount of greater than, or equal to, 60 percent by weight (based on the combined weights of Component A and B); and
B) Component B is present in an amount of less than 40 percent by weight (based on the combined weights of Component A and B); and
wherein Component B has
1) a total crystallinity from 3 to 25 percent; and
2) a Brookfield viscosity from 2,000 to 30,000 cP, measured at 350° F. (177° C.).
3. The polymer composition of claim 1 , wherein;
A) Component A is present in an amount of greater than, or equal to, 80 percent by weight (based on the combined weights of Component A and B); and
B) Component B is present in an amount of less than 20 percent by weight (based on the combined weights of Component A and B); and
wherein Component B has
1) a total crystallinity from 5 to 20 percent; and
2) a Brookfield viscosity from 5,000 to 20,000 cP, measured at 350° F. (177° C.).
4. The polymer composition of claim 1 , wherein
A) Component A is selected from the group consisting of glass fibers, talc, calcium carbonate, alumina trihydrate, marble dust, cement dust, clay, feldspar, silica or glass, fumed silica, alumina, magnesium oxide, magnesium hydroxide, antimony oxide, zinc oxide, barium sulfate, aluminum silicate, calcium silicate, titanium dioxide, titanates, glass microspheres or chalk, hindered phenolics, phosphites, light stabilizers, plasticizers; tackifiers, waxes; processing aids, stearic acid or a metal salt thereof, crosslinking agents, colorants or pigments, carbon black, graphite, carbon fibers, blowing agents, and any and all combinations thereof.
5. The polymer composition of claim 1 , wherein
i) calcium carbonate is said filler, and the highest ultimate filler loading is greater than 90 weight percent; or
ii) alumina trihydrate is said filler, and the highest ultimate filler loading is greater than 80 weight percent.
6. The polymer composition of claim 1 , wherein B) said one or more base polymers, Component B, is an interpolymer of ethylene and at least one of propylene; isobutylene; 1-butene; 1-pentene; 3-methyl-1-penetene; 4-methyl-1-pentene; 1-hexene and 1-octene.
7. The polymer composition of claim 6 , wherein B) is an interpolymer of ethylene and at least one of propylene and 1-octene.
8. A polymer composition comprising a filler and
polymer, and wherein the polymer is selected from the group consisting of homogeneous ethylene/C3-C20 alpha-olefin interpolymers, C3-C20 alpha-olefin homopolymers, and C3-C20 alpha-olefin interpolymers, and wherein when said polymer is mixed with calcium carbonate at a concentration of 89 weight percent calcium carbonate to form a mixture, the viscosity of the mixture (when measured on a Rheometrics RMS-800, with 25 mm parallel plates, at frequency of 100 rad/s, at 230° C., in a nitrogen purge) is greater than 1.3×10 4 poise.
9. The composition of claim 1 , wherein the one or more interpolymers, Component B, has a density from 0.865 g/cm 3 to 0.885 g/cm 3 .
10. The composition of claim 1 , wherein the one or more interpolymers, Component B, comprise a diene.
11. The polymer composition of claim 1 , wherein
A) Component A is selected from the group consisting of glass fibers, talc, calcium carbonate, alumina trihydrate, marble dust, cement dust, clay, feldspar, silica or glass, fumed silica, alumina, magnesium oxide, magnesium hydroxide, antimony oxide, zinc oxide, barium sulfate, aluminum silicate, calcium silicate, titanium dioxide, titanates, glass microspheres, chalk, and combinations thereof.
12. An article comprising at least one component formed from the
composition of claim 1 .
13. A multilayered structure comprising at least one layer formed
from the composition of claim 1 .
14. A film or sheet formed from the composition of claim 1 .
15. An injection molded or blow molded part formed from the
composition of claim 1 .
16. A polymer composition comprising a blend of Component A) and Component B);
A) one or more fillers, present in an amount greater than, or equal to, 40 percent by weight (based on the combined weights of Component A and B); and
B) one or more base polymers present in an amount less than 60 percent by weight (based on the combined weights of Component A and B); and
wherein Component A is carbon black; alumina trihydrate, calcium carbonate or any and all combinations thereof; and
wherein Component B is a homogenous ethylene/propylene copolymer, ethylene/octene-1 copolymer, or polypropylene, and has
1) a total crystallinity from 0 to 30 percent; and
2) a Brookfield viscosity from 500 to 50,000 cP, measured at 350° F. (177° C.).
17. An article comprising at least one component formed from the composition of claim 16 .
18. A multilayered structure comprising at least one layer formed from the composition of claim 16 .
19. A film or sheet formed from the composition of claim 16 .
20. An injection molded or blow molded part formed from the composition of claim 16 .