IP Library › Granted Patent US 7,375,151
Granted Patent B2
US 7,375,151 · App. 10/962,728 · Granted May 20, 2008

Highly-resilient thermoplastic compositions

Assignee: E. I. du Pont de Nemours and Company
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Quick Facts
Patent No.
US 7,375,151
App. No.
10/962,728
Granted
May 20, 2008
Kind
B2
Abstract

A thermoplastic composition is provided, comprising (a) an acid copolymer, (b) a salt of a high molecular weight, monomeric organic acid; (c) a thermoplastic resin; (d) a cation source; and (e) optionally, a filler. Also provided are one-, two- and three-piece golf balls, and multi-layered golf balls comprising the composition of the invention.

Claims (22)

1. A golf ball comprising a cover and a core, said core comprising

a) an acid copolymer of the composition E/X/Y wherein E represents copolymerized residues of ethylene, X represents copolymerized residues of an α,β ethylenically unsaturated carboxylic acid, and Y represents copolymerized residues of a C 1 -C 8 alkyl acrylate or alkyl methacrylate, and further wherein the amount of X is 4-35 wt. % of the acid copolymer, and the amount of Y is 0-50 wt. % of the acid copolymer;

b) about 10 to about 45 wt. % of a high molecular weight, monomeric organic acid or salt thereof based on total weight of components a), b), and c) provided that component (b) does not exceed 50 wt. % of (a) plus (b);

c) about 1 to about 35 wt. % of a thermoplastic resin;

d) a cation source present at a level sufficient to neutralize 95 to 110% of the combined acid content of components a) and b); and

e) zero to about 60 wt. % of a filler based on weight of components a) plus b) plus c) plus e);

wherein the filler (e) is present in a type and amount sufficient to achieve a density between the density of the composition without filler and 1.8 grams per cubic centimeter; and

wherein the core has a dimple pattern such that when positioned in the ball and covered by the cover having a dimple pattern, the cover thickness in the dimple areas is the about the same as the cover thickness in the non-dimpled areas.

2. A center, core, or mantle of a golf ball or a one-piece golf ball, said center, core mantle or one-piece golf ball comprising

a) an acid copolymer of the composition E/X/Y wherein E represents copolymerized residues of ethylene, X represents copolymerized residues of an α,β ethylenically unsaturated carboxylic acid, and Y represents copolymerized residues of a C 1 -C 8 alkyl acrylate or alkyl methacrylate, and further wherein X is present in an amount of 4-35 wt. % of the acid copolymer, and Y is present in a finite amount up to 50 wt. % of the acid copolymer;

b) about 10 to about 45 wt. % of a high molecular weight, monomeric organic acid or salt thereof based on total weight of components a), b), and c) provided that component (b) does not exceed 50 wt. % of (a) plus (b);

c) about 1 to about 35 wt. % of a thermoplastic resin;

d) a cation source present at a level sufficient to neutralize about 50 to about 110% of the combined acid content of components a) and b); and

e) zero to about 60 wt. % of a filler based on weight of components a) plus b) plus c) plus e).

3. The center, core, or mantle of a golf ball or the one-piece golf ball of claim 2 wherein the thermoplastic resin is selected from the group consisting of copolyetheresters, copolyetheramides, elastomeric polyolefins, styrene diene block copolymers, polyurethanes, polyamides, polyesters, polyolefins, ethylene copolymers, anhydride modified ethylene or propylene homopolymers and copolymers, and metallocene polyethylene.

4. The center, core, or mantle of a golf ball or the one-piece golf ball of claim 2 wherein the thermoplastic resin is a thermoplastic elastomer.

5. The center, core, or mantle of a golf ball or the one-piece golf ball of claim 4 wherein the thermoplastic elastomer is selected from the group consisting of copolyetheresters, copolyetheramides, elastomeric polyolefins, styrene diene block copolymers and thermoplastic polyurethanes.

6. The center, core, or mantle of a golf ball or the one-piece golf ball of claim 2 wherein the filler (e) is present in a type and amount sufficient to achieve a density between the density of the composition without filler and 1.8 grams per cubic centimeter.

7. A multi-layer golf ball having a core and a cover with one or more intermediate layers or mantles between the core and the cover, the core and the mantles being independently or both selected from the cores and mantles of claim 6 wherein the filer is sufficient to adjust the density of the core or mantle or both in which the composition is used to a level such that the golf ball has a density of 1.14 gms/cc.

8. The multi-layer golf ball of claim 7 wherein the mantle(s) and the core independently or both comprise an acid copolymer (a) selected from ethylene acrylic acid and ethylene methacrylic acid, about 10 to about 30 wt. % of monomeric organic acid or salt thereof (b) based on weight of (a), (b) and (c), about 1 to about 35 wt. % thermoplastic resin (c) based on weight of (a), (b) and (c), and up to 60 parts filler (e) per hundred parts of (a) through (d) by weight.

9. A two-piece golf ball comprised of a core of claim 6 and a cover wherein the filler is sufficient to adjust the density of the core to about 1.18 gm/cc.

10. A two-piece golf ball comprising a cover and a core according to claim 6 , wherein the core has a dimple pattern such that when positioned in the ball and covered by the cover having a dimple pattern, the cover thickness in the dimple areas is the about the same as the cover thickness in the non-dimpled areas.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 12, 2006
From: STATZ, ROBERT JOSEPH; HAGMAN, JOHN FRANCIS; CHEN, JOHN CHU
To: E. I. DU PONT DE NEMOURS AND COMPANY
Reel/Frame 017459/0221 →
Continuity (7)
Continuation In Part 0996020800 · Sep 22, 2001
Continuation In Part 0942214200 · Oct 21, 1999
Provisional Application 6010506500 · Oct 21, 1998
Provisional Application 6010523200 · Oct 21, 1998
Provisional Application 6010519300 · Oct 22, 1998
Provisional Application 6010518100 · Oct 22, 1998
Related Publication 20050148725A1 · Jul 7, 2005