Light emitting material and organic light-emitting device
A polymer light emitting material, wherein the material has a light emitting mechanism based on transition from an excited triplet state to a ground state or transition through an excited triplet state to a ground state of an electron energy level, and the material comprises a nonionic light emitting part which constitutes a part of the polymer or is bound to the polymer. The polymer light emitting material exhibits high light emission efficiency above 5%, which is the limit of external quantum efficiency of fluorescence and can be designed so as to have a large area and hence are suitable for mass production of organic light emitting devices.
1. A polymer light-emitting material wherein the material has a light emitting mechanism based on transition from an excited triplet state to a ground state or transition through an excited triplet state to a ground state of an electron energy level, and the material comprises a nonionic light emitting part which constitutes a part of the polymer or is bound to the polymer, wherein said material is obtained by polymerizing a polymerizable composition containing at least one polymerizable light emitting compound represented by the formula (H-1) below:
wherein R 1H and R 2H each independently represents a hydrogen atom, a halogen atom, a nitro group, an amino group, a sulfonic acid group, a sulfonic acid ester group or an organic group having 1 to 20 carbon atoms which may be substituted by a hetero atom, and R 3H represents a polymerizable substituent represented by (H-3):
2. A polymer light-emitting material wherein the material has a light emitting mechanism based on transition from an excited triplet state to a ground state or transition through an excited triplet state to a ground state of an electron energy level, and the material comprises a nonionic light emitting part which constitutes a part of the polymer or is bound to the polymer, wherein said material is obtained by polymerizing a polymerizable composition containing at least one polymerizable light emitting compound represented by the formula (H-1) below:
wherein R 1H and R 2H in formula (H-1) are propanoyloxy groups, and R 3H represents a polymerizable substituent represented by (H-2) or (H-3):
3. A polymer light-emitting material wherein the material has a light emitting mechanism based on transition from an excited triplet state to a ground state or transition through an excited triplet state to a ground state of an electron energy level, and the material comprises a nonionic light emitting part which constitutes a part of the polymer or is bound to the polymer, wherein said material is obtained by polymerizing a polymerizable composition containing at least one polymerizable light emitting compound represented by the formula (H-1) below:
wherein both of R 1H and R 2H in formula (H-1) are the same polymerizable substituent as R 3H or wherein one of R 1H and R 2H is the same polymerizable substituent as R 3H and the other is a propanoyloxy group and R 3H represents a polymerizable substituent represented by (H-2) or (H-3):
4. A light emitting composition comprising the polymer light emitting material according to claim 1 , and a carrier transporting polymer compound.
5. The light emitting composition according to claim 4 , wherein the carrier transporting polymer compound is a hole transporting polymer compound.
6. The light emitting composition according to claim 4 , wherein the carrier transporting polymer compound is an electron transporting polymer compound.
7. A light emitting composition comprising the light emitting material according to claim 1 , and a carrier transporting compound.
8. The light emitting composition according to claim 7 , wherein the carrier transporting compound is a hole transporting compound.
9. The light emitting composition according to claim 7 , wherein the carrier transporting compound is an electron transporting compound.
10. A layer containing a light emitting material for organic light emitting device, wherein a light emitting material is a polymer light emitting material described in claim 1 .
11. The layer containing a light emitting material for organic light emitting device according to claim 10 , wherein the polymer light emitting material is obtained by forming a polymerizable composition containing at least one light emitting compound into a film and then polymerizing it.
12. The layer containing a light emitting material for organic light emitting device according to claim 11 , wherein the polymer light emitting material has no crosslinking structure.
13. The layer containing a light emitting material for organic light emitting device according to claim 11 , wherein the polymer light emitting material has a crosslinking structure.
14. A layer containing a light emitting material for organic light emitting device obtained by forming into a film a polymer light emitting material described in claim 1 .
15. The layer containing a light emitting material for organic light emitting device according to claim 14 , wherein the polymer light emitting material has no crosslinking structure.
16. An organic light emitting device comprising the polymer light emitting material according to claim 1 .
17. The organic light emitting device according to claim 16 , comprising a light emitting layer comprising the polymer light emitting material having on both sides or one side thereof an electron transporting layer of a coated type, and/or a hole transporting layer of a coated type.
18. The polymer light emitting material according to claim 1 , which is obtained by homopolymerizing the polymerizable compound represented by formula (H-1).
19. The polymer light emitting material according to claim 1 , which is obtained by copolymerizing the polymerizable compound represented by formula (H-1) and bisstyryloxadiazole.