Method of making porous polymeric separator and lithium ion polymer battery
The present invention relates to a method of making a polymeric porous separation membrane for a lithium ion polymer battery, the method comprising: providing a porous polyolefin membrane and a polymer solution of the concentration of 1–20 weight % in an organic solvent fabricated by dissolving in an organic solvent a polymer compound that is stable in an electrolyte containing a lithium salt and can be gelled in the electrolyte, at the temperature of 10–40° C.; and fabricating a polymeric porous separation membrane by coating the polymeric porous polyolefin membrane with the polymer solution. Thus, the porous separation membrane for a lithium ion polymer battery is fabricated by using the polymer solution fabricated at the low temperatures of 10–40° C., and the size of the pores of the coated is proper, so that the containing capacity of the electrolyte and the ion conductivity are good. Further gelling at low pressure is enabled and cohesive force to the electrodes is improved. In the lithium ion battery containing the porous separation membrane, the gelling is accomplished at atmospheric pressure or at low pressure for a few hours, so that problems caused by gelling for a short period at high pressure and high temperature such as the non uniform gelling of the battery, the deformation of the separation membrane and the weakened cohesion can be avoided. Moreover, the high-rate discharge, the cycle life becomes excellent.
1. A method of making a polymeric porous separation membrane for a lithium ion polymer battery, the method comprising:
providing a porous polyolefin membrane and a polymer solution of the concentration of 1–20 weight % fabricated by dissolving a polymer compound that is stable in an electrolyte containing a lithium salt and can be gelled in the electrolyte, in an organic solvent at the temperature of 10–40° C.; and
fabricating a polymeric porous separation membrane by coating a polymer layer having cores having a size of 0.1–20 μm on the porous polyolefin membrane with the polymer solution.
2. A method of making a lithium ion polymer battery comprising:
fabricating a cathode and an anode;
providing a porous polyolefin membrane and a polymer solution of the concentration of 1–20 weight % fabricated by dissolving a polymer compound that is stable in a electrolyte containing a lithium salt and can be gelled in the electrolyte, in an organic solvent at the temperature of 10–40° C.;
fabricating a polymeric porous separation membrane by coating a polymer layer having pores having a size of 0.1–20 μm on the porous polyolefin membrane with the polymer solution;
fabricating a battery structure by using the cathode, the polymeric porous membrane and the anode;
injecting a liquid electrolyte containing a lithium salt into an aluminum pouch including battery structure;
sealing the aluminum pouch, and subjecting the sealed aluminum pouch to a gelling process at a temperature of 70 to 100° C. and under a pressure ranging from atmospheric pressure to 10 lbs/cm 2 for 1 to 48 hours.
3. A method of making a lithium ion polymer battery comprising:
fabricating a cathode and an anode;
providing a porous polyolefin membrane and a polymer solution of the concentrations of 1–20 weight % fabricated by dissolving a polymer compound that is stable in a electrolyte containing a lithium salt and can be gelled in the electrolyte, in an organic solvent at the temperature of 10–40° C.;
fabricating a polymeric porous separation membrane by coating a polymer layer having pores having a size of 0.1–20 μm on the porous polyolefin membrane with the polymer solution;
fabricating a coated cathode by coating the cathode with the polymer solution;
fabricating a coated anode by coating the anode with the polymer solution;
fabricating a battery structure by using the coated cathode, the porous polyolefin membrande and the coated anode;
injecting a liquid electrolyte containing a lithium salt into an aluminum pouch including the battery structure;
sealing the aluminum pouch, and subjecting the sealed aluminum pouch to a gelling process at a temperature of 70 to 100° C. and under a pressure ranging from atmospheric pressure to 10 lbs/cm 2 for 1 to 48 hours.