Method for producing ammonia on the basis of a nitrogen-hydrogen mixture from natural gas
View Patent ↗A method for producing ammonia from natural gas, fed to an autothermic reformer with an O 2 rich gas. Crude synthesis gas is produced at temperatures of 900 to 1200° C., pressures of 40 to 100 bar and in the presence of a cracking catalyst. The crude synthesis gas is led through a catalytic conversion system to convert CO to H 2 , thereby obtaining a conversion synthesis gas with a H 2 content of at least 55 vol.-% and a CO content of not more than 8 vol.-%. The conversion synthesis gas is subjected to a gas purification to remove CO 2 , CO and CH 4 , thereby producing an N 2 —H 2 mixture that is subjected to a catalytic ammonia synthesis. The ammonia produced can at least be partially converted to urea by reacting it with CO 2 .
1. A process for the catalytic production of ammonia from a nitrogen/hydrogen mixture comprising:
(a) passing natural gas, an O 2 rich gas containing at least 95% vol. of O 2 and water vapor to a reforming zone comprised of an autothermal reformer, wherein said autothermal reformer comprises a burner;
(b) reforming, in said autothermal reformer, in the presence of a reforming catalyst said natural gas, O 2 rich gas and water vapor at a temperature in the range of 900-1200° C. and a pressure of 40-100 bar to produce a raw synthesis gas comprising an H 2 content of 55-75 vol. %, a CO content of 15-30 vol. %, a CO 2 content of 5-30 vol. %, and an H 2 :CO volume ratio of 1.6-4;
(c) extracting and cooling said synthesis gas from said autothermal reformer;
(d) passing said cooled synthesis gas through a shift conversion zone for convening CO +H 2 O into CO 2 +H 2 , wherein the converted synthesis gas has an H 2 content of 55 vol. % or greater and a CO content of 8 vol. % or less;
(e) contacting said converted synthesis gas with liquid nitrogen in a multi stage gas washing process, wherein CO 2 , CO and CH 4 are removed from the convened synthesis gas and an N 2 —H 2 mixture is produced; and
(f) feeding said N 2 —H 2 mixture to an ammonia synthesis plant for the catalytic production of ammonia.
2. A process as claimed in claim 1 , wherein CO 2 is removed from the converted synthesis gas in a physical wash with methanol at temperatures in the range of −70 to −20° C.
3. A process as claimed in claim 1 , wherein CO— containing gas is separated from the synthesis gas in a gas washing stage operated with liquid nitrogen and passed on to catalytic conversion.
4. A process as claimed in claim 1 , wherein the N 2 —H 2 mixture is routed through at least two catalyst-containing reactors in the ammonia synthesis unit where the N 2 —H 2 mixture serves as a cooling fluid in a reactor for indirect catalyst cooling.
5. A process as claimed in claim 1 , wherein the synthesis gas leaving the shift conversion stage exhibits an H 2 :CO 2 volume ratio of 2.5-3.0 (calculated dry).
6. A process for the catalytic production of ammonia from a nitrogen/hydrogen mixture comprising:
(a) passing natural gas, an O 2 rich gas containing at least 95% vol. of O 2 and water vapor to a reforming zone comprised of an autothermal reformer, wherein said autothermal reformer comprises a burner;
(b) reforming, in said autothermal reformer, in the presence of a reforming catalyst said natural gas, O 2 rich gas and water vapor at a temperature in the range of 900-1200° C. and a pressure of 40-100 bar to produce a raw synthesis gas comprising an H 2 content of 55-75 vol. %, a CO content of 15-30 vol. %, a CO 2 content of 5-30 vol. %, and an H 2 :CO volume ratio of 1.6-4;
(c) extracting and cooling said synthesis gas from said autothermal reformer;
(d) passing said cooled synthesis gas through a shift conversion zone for convening CO+H 2 O into CO 2 +H 2 , wherein the converted synthesis gas has an H 2 content of 55 vol. % or greater and a CO content of 8 vol. % or less;
(e) contacting said converted synthesis gas with liquid nitrogen in a multi stage gas washing process, wherein CO 2 , CO and CH 4 are removed from the convened synthesis gas and an N 2 —H 2 mixture is produced, wherein the removed CO 2 is recovered at least partly and used for urea production; and
(f) feeding said N 2 —H 2 mixture to an ammonia synthesis plant for the catalytic production of ammonia, wherein the ammonia is at least partly convened to urea with CO 2 .
7. A process for the catalytic production of ammonia from a nitrogen/hydrogen mixture comprised of:
(a) passing natural gas, an O 2 rich gas containing at least 95% vol. of O 2 and water vapor to a reforming zone comprised of an autothermal reformer, wherein said autothermal reformer comprises a burner;
(b) reforming, in said autothermal reformer, in the presence of a reforming catalyst said natural gas, O 2 rich gas and water vapor at a temperature in the range of 900-1200° C. and a pressure of 40-100 bar to produce a raw synthesis gas comprising an H 2 content of 55-75 vol. %, a CO content of 15-30 vol. %, a CO 2 content of 5-30 vol. %, and a CO volume ratio of 1.6-4;
(c) extracting and cooling said synthesis gas from said autothermal reformer;
(d) passing said cooled synthesis gas through a shift conversion zone for converting H 2 +CO into CO 2 +H 2 , wherein the converted synthesis gas has an H 2 content of 55 vol. % or greater and a CO content of 8 vol. % or less;
(e) contacting said converted synthesis gas with liquid nitrogen in a multi stage gas washing process, wherein CO 2 , CO and CH 4 are removed from the converted synthesis gas and an N 2 —H 2 mixture is produced, wherein a natural gas stream at a pressure of about 10 to 100 bar is routed to a gas wash unit operated with liquid nitrogen in which the pressure of said natural gas stream is reduced by at least 8 bar; and
(f) feeding said N 2 —H 2 mixture to an ammonia synthesis plant for the catalytic production of ammonia.