Method for producing 1-butene
A process for preparing 1-butene, which includes nonoxidatively, catalytically dehydrogenating n-butane to obtain a product gas stream of n-butane, 1-butene, 2-butene, butadiene, hydrogen, and secondary constituents; removing hydrogen and the secondary constituents to obtain a C 4 product gas stream; separating the C 4 product stream into a recycle stream of n-butane and a stream of 1-butene, 2-butene and butadiene by extractive distillation, and recirculating the recycle stream to the dehydrogenation zone; introducing the 1 -butene, 2-butene and butadiene stream into a selective hydrogenation zone and selective hydrogenation of butadiene to 1-butene and/or 2-butene to obtain a stream of 1-butene and 2-butene; introducing the 1-butene and 2-butene stream, and a circulating stream of 1-butene and 2-butene into a distillation zone and isolation of a product stream; and introducing the 2-butene-containing stream into an isomerization zone to obtain a circulating stream of 1-butene and 2-butene, and recirculating the circulating stream to the distillation zone.
1. A process for preparing 1-butene from 1-butane, which comprises:
A) providing a n-butane-containing feed gas stream a;
B) introducing the n-butane-containing feed gas stream a into at least one dehydrogenation zone and nonoxidative catalytic dehydrogenation of n-butane to give a product gas stream b comprising n-butane, 1-butene, 2-butene, butadiene, hydrogen, low-boiling secondary constituents and possibly water vapor;
C) removing hydrogen, the low-boiling secondary constituents and, if appropriate, water vapor to give a C 4 product gas stream c consisting essentially of n-butane, 1-butene, 2-butene and butadiene;
D) separating the C 4 product gas stream c into a recycle stream d1 consisting essentially of n-butane and a stream d2 comprising 1-butene, 2-butene and butadiene by extractive distillation, and recirculating the recycle stream d1 consisting essentially of n-butane to the dehydrogenation zone;
E) introducing the stream d2 comprising 1-butene, 2-butene and butadiene into a selective hydrogenation zone, and selective hydrogenating butadiene to 1-butene and/or 2-butene to give a stream e comprising 1-butene and 2-butene;
F) introducing the stream e comprising 1-butene and 2-butene and a circulating stream g comprising 1-butene and 2-butene into a distillation zone, and isolating a desired product stream f1 consisting essentially of 1-butene to leave a 2-butene-containing stream f2; and
G) introducing the 2-butene-containing stream f2, if appropriate after a purge gas stream has been separated off, into an isomerization zone and isomerization of 2-butene to 1-butene so as to give a circulating stream g comprising 1-butene and 2-butene, and recirculating, if appropriate after a purge gas stream has been separated off from the circulating gas stream g, the circulating gas stream g to the distillation zone.
2. The process according to claim 1 , wherein the nonoxidative, catalytic dehydrogenation is carried out as an autothermal dehydrogenation.
3. The process according to claim 1 , wherein the extractive distillation is carried out using an N-methylpyrrolidone/water mixture as an extractant.
4. The process according to claim 1 , wherein the low-boiling secondary constituents are separated off by a high-boiling solvent in an absorption/desorption cycle.
5. The process according to claim 2 , wherein the extractive distillation is carried out using a N-methylpyrrolidone/water mixture as an extractant.
6. The process according to claim 2 , wherein the low-boiling secondary constituents are separated off by a high-boiling solvent in an absorption/desorption cycle.
7. The process according to claim 3 , wherein the low-boiling secondary constituents are separated off by a high-boiling solvent in an absorption/desorption cycle.