High refractive index, durable hard coats
The development of new compositions and new aromatic sulfur acrylate monomers results in improved hardcoat films, and improved optical films that contain the hard coat films. The films provide improved display systems when incorporated thereon. The combination of functionalized zirconia nanoparticles with multifunctional acrylate crosslinkers and high index of refraction aromatic sulfur acrylates, about 1.58 or greater, produces abrasion resistant hard coats that have relatively high refractive indices.
1. A display system comprising a hard coat layer coupled to a substantially transparent substrate, the hard coat layer comprising:
functionalized zirconia nanoparticles;
at least one acrylate crosslinking agent; and
at least one aromatic sulfur acrylate monomer selected from the group of compounds defined by the following formula:
where R1=H or CH 3 , m,n,p, and q are independently 1-6, and Ar is any aromatic group.
2. The display system of claim 1 wherein said acrylate crossliniking agent is multifunctional and said aromatic sulfur acrylate exhibits an index of refraction of at least 1.58 or greater.
3. The display system of claim 1 wherein said aromatic sulfur acrylate is selected from the group consisting of acrylic acid 2-acryloyloxymethyl-3-(naphthalene-2-ylsulfanyl)-2-(naphthalene-2-ylsulfanylmethyl)-propyl ester and acrylic acid 2-acryloyloxymethyl-3 -phenylsulfanyl-2-phenylsulfanylmethyl-propyl ester.
4. The display system of claim 1 further comprising a low refractive index layer coupled to said hardcoat layer.
5. The display system of claim 4 wherein said low refractive index layer has a refractive index no greater than 1.5.
6. The display system of claim 4 wherein said hardcoat layer has a refractive index of at least 1.58.
7. The display system of claim 1 wherein the hard coat layer further comprises a photoinitiator.
8. The display system of claim 1 wherein said hard coat has an abrasion resistance no greater than 3.0% haze as determined by modified ASTM F 735-94.
9. The display system of claim 1 wherein the hard coat layer comprises a multifunctional acrylate with a functionality of at least 3.
10. The display system of claim 9 wherein said multifunctional acrylate is pentaerythritol triacrylate.
11. A coating composition comprising:
an aromatic sulfur acrylate selected from the group of compounds defined by the following formula:
where R1=H or CH 3 , m,n,p, and q are independently 1-6, and Ar is any aromatic group;
an acrylate crossliniker; and
functionalized zirconia nanoparticles.
12. The composition of claim 11 wherein said zirconia nanoparticles have a diameter measuring about 10-30 nanometers.