Producing supported cobalt catalysts for the Fisher-Tropsch synthesis
View Patent ↗A process for producing a supported Fischer-Tropsch catalyst includes treating, in an activation stage ( 12 ), a particulate pre-reduction cobalt nitrate-based supported Fischer-Tropsch synthesis catalyst precursor containing reducible cobalt oxides, with hydrogen as a reducing gas in order to reduce the cobalt oxides over a period of time to Co, with ammonia and water being formed, the reduction including a time period when predominantly CoO is reduced to Co. Unreacted hydrogen is withdrawn ( 20 ), which thus includes water and treated to lower its dewpoint ( 14 ). At least a portion of the withdrawn unreacted hydrogen is returned to the activation stage ( 12 ) as recycle hydrogen ( 26 ). An ammonia concentration is maintained in the activation stage ( 12 ), at least during the time when predominantly CoO is reduced to Co, of less than 250 volume parts per million (‘vppm’).
1. A process for producing a supported Fischer-Tropsch catalyst, which process includes
treating, in an activation stage, a cobalt supported Fischer-Tropsch synthesis catalyst precursor containing reducible cobalt oxides, with hydrogen as a reducing gas for a period of time effective to reduce the cobalt oxides to Co, wherein ammonia and water are formed;
withdrawing unreacted hydrogen, which thus includes water, from the activation stage, treating the withdrawn unreacted hydrogen to lower its dewpoint and returning at least a portion of the withdrawn unreacted hydrogen to the activation stage as recycle hydrogen; and
maintaining an ammonia concentration in the activation stage, at least during the time when predominantly CoO is reduced to Co, of less than 250 volume parts per million (“vppm”).
2. The process as claimed in claim 1 , wherein the ammonia concentration in the activation stage is maintained, at least during the time when predominantly CoO is reduced to Co, at less than 70 vppm.
3. The process as claimed in claim 2 , wherein the ammonia concentration in the activation stage is maintained, at least during the time when predominantly CoO is reduced to Co, at less than 45 vppm.
4. The process as claimed in claim 1 , wherein maintaining the ammonia concentration in the activation stage, at least during the time when predominantly CoO is reduced to Co, at less than 250 vppm includes removing NH 3 from the unreacted hydrogen withdrawn from the activation stage.
5. The process as claimed in claim 1 , wherein water and some of the NH 3 present in the unreacted hydrogen are simultaneously removed from the unreacted hydrogen in a common process step or unit operation.