Thermoplastic elastomer compositions
A unique thermoplastic olefin composition having: (a) at least 40 percent by weight of a propylene-alpha olefin copolymer based on the total weight of polymers in the composition, the propylene-alpha olefin copolymer having at least 60 percent by weight units derived from propylene, at least 6 percent by weight units derived from an alpha olefin, a molecular weight distribution less than 3.5, and a broad composition distribution; and (b) at least 20 percent by weight of a polypropylene based on the total weight of polymers in the composition, the polypropylene having at least 93 percent by weight units derived from propylene, a molecular weight distribution of greater than 3.5, a heat of fusion greater than the heat of fusion exhibited by the propylene-alpha olefin copolymer, and a melting point T max of at least 120° C.
1. A thermoplastic olefin composition, comprising:
(a) at least 40 percent by weight of a propylene-alpha olefin copolymer based on the total weight of polymers in the composition, the propylene-alpha olefin copolymer forming a continuous phase of the composition and the propylene-alpha olefin copolymer having:
(1) at least 60 percent by weight units derived from propylene;
(2) at least 6 percent by weight units derived from an alpha olefin;
(3) a molecular weight distribution less than 3.5;
(4) a broad composition distribution;
(5) a heat of fusion of less than 40 Joules/gram; and
(6) optionally, a glass transition temperature (Tgp) less than −10° C.; and
(b) at least 20 percent by weight of a propylene impact copolymer based on the total weight of polymers in the composition, the propylene impact copolymer comprised of:
(1) a polypropylene matrix phase having a heat of fusion greater than the heat of fusion exhibited by the propylene-alpha olefin copolymer; and
(2) an elastomer phase, wherein the elastomer phase is at least 10 percent by weight of the propylene impact copolymer.
2. The thermoplastic olefin composition of claim 1 , wherein the propylene impact copolymer is from about 25 to about 50 percent by weight of the thermoplastic olefin composition.
3. The thermoplastic olefin composition of claim 1 , wherein the elastomer phase is at least 15 percent by weight of the propylene impact copolymer.
4. The thermoplastic olefin composition of claim 1 , wherein the elastomer phase comprises from 5 to 15 percent by weight of the total polymers present in the thermoplastic olefin composition.
5. The thermoplastic olefin composition of claim 1 , wherein the propylene-alpha olefin copolymer comprises a propylene-ethylene copolymer.
6. The thermoplastic olefin composition of claim 1 , wherein the propylene-alpha olefin copolymer is characterized as having 13 C NMR peaks corresponding to a regio error at about 14.6 and about 15.7 ppm, the peaks of about equal intensity.
7. The thermoplastic olefin composition of claim 1 , wherein the propylene-alpha olefin copolymer has a skewness index greater than −1.20.
8. The thermoplastic olefin composition of claim 7 , wherein the propylene-alpha olefin copolymer comprises a propylene-ethylene copolymer.
9. The thermoplastic olefin composition of claim 8 , wherein the elastomer phase of the propylene impact copolymer comprises an ethylene-propylene copolymer.
10. The thermoplastic olefin composition of claim 7 , wherein the propylene-alpha olefin copolymer comprises units derived from propylene, units derived from ethylene, and units derived from C 4 to C 20 alpha olefin.
11. The thermoplastic olefin composition of claim 1 , wherein the elastomer phase of the propylene impact copolymer has a glass transition temperature (Tge) which is lower than Tgp.
12. The thermoplastic olefin composition of claim 11 , wherein the elastomer phase of the propylene impact copolymer comprises an ethylene-propylene copolymer.
13. The thermoplastic olefin composition of claim 11 , wherein Tgp is at least 5° C. higher than Tge.
14. The thermoplastic olefin composition of claim 1 , wherein the elastomer phase of the propylene impact copolymer comprises an ethylene-propylene copolymer.
15. The thermoplastic olefin composition of claim 1 , wherein the propylene-alpha olefin copolymer comprises a propylene-ethylene copolymer having from about 10 to about 15 percent by weight units derived from ethylene.
16. The thermoplastic olefin composition of claim 1 , wherein the propylene-alpha olefin copolymer exhibits an Upper Temperature Quartile Range greater than 4° C.
17. The thermoplastic olefin composition of claim 1 , wherein the propylene-alpha olefin copolymer exhibits an Upper Temperature Quartile Range greater than 7° C.
18. The thermoplastic olefin composition of claim 1 , wherein the composition exhibit tensile 2% secant modulus less than 50,000 p.s.i., tensile strength of at least 1,000 p.s.i., tensile elongation of at least 500%, and Vicat softening temperature of at least 40° C.
19. The thermoplastic olefin composition of claim 1 , wherein the matrix phase of the propylene impact copolymer has a melting point T max of at least 120° C.