Process for producing ultrafine particles
View Patent ↗The ultrafine particle producing process introduces materials for producing ultrafine particles into a thermal plasma flame under reduced pressure to form a vapor-phase mixture, introduces a reactive gas and a cooling gas toward an end portion of the thermal plasma flame in supply amounts sufficient for quenching the vapor-phase mixture to generate the ultrafine particles and allows the resultant ultrafine particles to come into contact with the reactive gas so as to produce the ultrafine particles whose surfaces are coated with a thin film including one or more components compound derived from decomposition and/or reaction of the reactive gas, for example, an elementary carbon substance and/or a carbon. According to the process, thin film-coated ultrafine particles having high level uniformity in particle size and shape can be produced.
1. A process for producing ultrafine particles each coated with a thin film, said method comprising the steps of:
introducing materials for producing the ultrafine particles into a thermal plasma flame having a center axis, the materials being introduced along the center axis of the thermal plasma flame in a chamber under reduced pressure to form a vapor-phase mixture;
introducing a mixed gas of a reactive gas and a cooling gas toward an end portion of the thermal plasma flame through an annular slit-like nozzle on said chamber and surrounding the outer periphery of the thermal plasma flame and having a substantially conical shape with an axis that is substantially identical with the center axis of the thermal plasma flame and whose diameter is gradually reduced in a direction to the end portion of the thermal plasma flame in supply amounts sufficient for quenching the vapor-phase mixture to generate the ultrafine particles; and
allowing the resultant ultrafine particles to come into contact with the reactive gas so as to produce the ultrafine particles whose surfaces are coated with the thin film including one or more components derived from decomposition and/or reaction of the reactive gas.
2. The process for producing ultrafine particles according to claim 1 , wherein said step of introducing the materials for producing the ultrafine particles into the thermal plasma flame comprises:
a step of dispersing the materials for producing the ultrafine particles with a carrier gas; and
a step of introducing the dispersed materials for producing the ultrafine particles into the thermal plasma flame.
3. The process for producing ultrafine particles according to claim 2 , wherein particle size of said ultrafine particles is controlled by changing the supply amount of at least one of the reactive gas, the carrier gas and the cooling gas.
4. The process for producing ultrafine particles according to claim 2 , wherein a thickness of the thin film to be coated on the surfaces of the ultrafine particles is controlled by changing the supply amount of at least one of the reactive gas, the carrier gas and the cooling gas.
5. The process for producing ultrafine particles according to claim 2 , wherein the reactive gas is a hydrocarbon gas, the carrier gas is an inert gas and the thin film to be coated on the surfaces of the ultrafine particles is a thin film that includes an elementary carbon substance and/or a carbon compound.
6. The process for producing ultrafine particles according to claim 1 , wherein components that constitute the materials for producing the ultrafine particles are metals, alloys, simple oxides, composite oxides, double oxides, oxide solid solutions, hydroxides, carbonate compounds, halides, sulfides, nitrides, carbides, hydrides, metal salts, or organometallic compounds that contain at least one element selected from the group consisting of elements having atomic numbers of 12, 13, 26 to 30, 46 to 50, 62, and 78 to 83.
7. The process for producing ultrafine particles according to claim 1 , wherein the cooling gas is an inert gas.
8. The process for producing ultrafine particles according to claim 1 , wherein particle size of said ultrafine particles is controlled by changing the supply amount of at least one of the reactive gas and the cooling gas.
9. The process for producing ultrafine particles according to claim 1 , wherein a thickness of the thin film to be coated on the surfaces of the ultrafine particles is controlled by changing the supply amount of at least one of the reactive gas and the cooling gas.
10. The process for producing ultrafine particles according to claim 1 , wherein the reactive gas is a hydrocarbon gas and the thin film to be coated on the surfaces of the ultrafine particles is a thin film that includes an elementary carbon substance and/or a carbon compound.
11. The process for producing ultrafine particles according to claim 1 , wherein a total supply amount of the reactive gas and the cooling gas is set such that a gas introduced into a cooling chamber comprising a space for quenching the vapor-phase mixture has an average flow rate of 0.001 to 60 m/sec in the cooling chamber.
12. The process for producing ultrafine particles according to claim 11 , wherein the total supply amount is such that the average flow rate becomes 0.01 to 10 m/sec.