Electrophotographic photoreceptor
An electrophotographic imaging member includes a substrate, a charge generating layer, and a charge transport layer, where the charge generating layer includes a photogenerating material and a hydroxyl group-containing polymeric compound.
1. An electrophotographic imaging member comprising, in order:
a substrate,
a conductive layer,
a charge generating layer, and
a charge transport layer,
wherein the charge generating layer comprises:
a photogenerating material and a hydroxyl group-containing polycarbonate resin comprising free hydroxyl groups in an amount of from about 10 to about 75 mol %;
a film-forming polymeric binder that is different from the hydroxyl group-containing polycarbonate resin; and
the hydroxyl group-containing polycarbonate resin comprises at least one repeating segment represented by the formula (I):
wherein R 1 is selected from the group consisting of hydrogen, alkyl, and aryl; R 2 represents a divalent linkage selected from the group consisting of alkylene optionally containing one or more heteroatoms of halogen, nitrogen, sulfur, silicon, or phosphorus, arylalkylene, and arylene; Ar 1 and Ar 2 each independently represent aromatic groups; and P represents a hydrogen atom, or a hydroxyl protective group.
2. The electrophotographic imaging member of claim 1 , wherein the hydroxyl group-containing polycarbonate resin stabilizes the photogenerating material against polymorphic change.
3. The electrophotographic imaging member of claim 1 , wherein the photogenerating material comprises titanium phthalocyanine.
4. The electrophotographic imaging member of claim 1 , wherein the photogenerating material comprises Type V titanium phthalocyanine.
5. The electrophotographic imaging member of claim 1 , wherein an average particle size of the photogenerating material is from about 10 nm to about 500 nm.
6. The electrophotographic imaging member of claim 1 , wherein the film-forming polymeric binder is selected from the group consisting of polyesters, polyamides, polyurethanes, polystyrenes, polyarylethers, polyarylsulfones, polybutadienes, polysulfones, polyethersulfones, polyethylenes, polypropylenes, polyimides, polymethylpentenes, polyphenylene sulfides, polyvinyl acetate, polysiloxanes, polyacrylates, polyvinyl acetals, polyamides, polyimides, amino resins, phenylene oxide resins, terephthalic acid resins, phenoxy resins, epoxy resins, polystyrene and acrylonitrile copolymers, polyvinylchloride, vinylchloride and vinyl acetate copolymers, acrylate copolymers, alkyd resins, cellulosic film formers, poly(amideimide), styrenebutadiene copolymers, vinylidenechloride-vinylchloride copolymers, vinylacetate-vinylidenechloride copolymers, styrene-alkyd resins, and polyvinylcarbazole.
7. The electrophotographic imaging member of claim 1 , wherein the film-forming polymeric binder does not contain hydroxyl groups.
8. The electrophotographic imaging member of claim 1 , wherein the hydroxyl group-containing polycarbonate resin comprises free hydroxyl groups in an amount of from about 15 to about 50 mol %.
9. The electrophotographic imaging member of claim 1 , wherein the charge transport layer comprises a polycarbonate resin and N,N′-diphenyl-N,N′-bis(3-methyl phenyl)-1,1′-biphenyl-4,4′-diamine.
10. A process for forming an electrophotographic imaging member comprising:
providing an electrophotographic imaging member substrate, and
applying, in order, a conductive layer, a charge generating layer and a charge transport layer over the substrate,
wherein the charge generating layer comprises:
a photogenerating material and a hydroxyl group-containing polycarbonate resin comprising free hydroxyl groups in an amount of from about 10 to about 75 mol %;
a film-forming polymeric binder that is different from the hydroxyl group-containing polycarbonate resin; and
the hydroxyl group-containing polycarbonate resin comprises at least one repeating segment represented by the formula (I):
wherein R 1 is selected from the group consisting of hydrogen, alkyl, and aryl; R 2 represents a divalent linkage selected from the group consisting of alkylene optionally containing one or more heteroatoms of halogen, nitrogen, sulfur, silicon, or phosphorus, arylalkylene, and arylene; Ar 1 and Ar 2 each independently represent aromatic groups; and P represents a hydrogen atom, or a hydroxyl protective group.
11. The process of claim 10 , wherein the hydroxyl group-containing polycarbonate resin stabilizes the photogenerating material against polymorphic change.
12. The process of claim 10 , wherein the photogenerating material comprises titanium phthalocyanine.
13. The process of claim 10 , wherein applying the charge generating layer comprises:
applying a coating solution to an underlying layer; and
drying said coating solution to form said charge generating layer.
14. The process of claim 13 , wherein the coating solution is formed by:
forming a solution of said photogenerating material and said hydroxyl group-containing polycarbonate resin in a first solvent; and
mixing said solution with the film-forming polymeric binder in a second solvent to form the coating solution.
15. An electrographic image development device, comprising an electrophotographic imaging member comprising, in order:
a substrate,
a conductive layer,
a charge generating layer, and
a charge transport layer,
wherein the charge generating layer comprises:
a photogenerating material and a hydroxyl group-containing polycarbonate resin comprising free hydroxyl groups in an amount of from about 10 to about 75 mol %;
a film-forming polymerichinder that is different from the hydroxyl group-containing polycarbonate resin; and
the hydroxyl group-containing polycarbonate resin comprises at least one repeating segment represented by the formula (I):
wherein R 1 is selected from the group consisting of hydrogen, alkyl, and aryl; R 2 represents a divalent linkage selected from the group consisting of alkylene optionally containing one or more heteroatoms of halogen, nitrogen, sulfur, silicon, or phosphorus, arylalkylene, and arylene; Ar 1 and Ar 2 each independently represent aromatic groups; and P represents a hydrogen atom, or a hydroxyl protective group.