IP Library › Granted Patent US 7,637,995
Granted Patent B2
US 7,637,995 · App. 11/211,223 · Granted Dec 29, 2009

Composition for forming a composite material

Assignee: Rohm and Haas Company
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Quick Facts
Patent No.
US 7,637,995
App. No.
11/211,223
Granted
Dec 29, 2009
Kind
B2
Abstract

A composition and method for forming a composite material comprising a mixture of component A and component B, component A comprising gypsum and an inhibitor; and component B comprising an accelerator, wherein at least one of component A and component B further comprises a polymer binder having a T g of below −23° C. or wherein the Shore D hardness of the composite material when cured is less than 70; the method comprising providing a first slurry mixture of component A and a second slurry mixture of component B and blending the first slurry mixture and the second slurry mixture to form a soft composite using a weight ratio of from 10:1 to 1:2.

Claims (71)

1. A composition for forming a composite material comprising a mixture of component A and component B,

component A comprising:

gypsum; and

an inhibitor; and

component B comprising:

an accelerator;

wherein at least one of component A and component B further comprises a predominantly acrylic aqueous emulsion polymer binder having a T g of below −23° C.

2. The composition of claim 1 wherein component A further comprises:

a defoamer;

a surfactant; and

a pH adjuster.

3. The composition of claim 1 wherein component B further comprises:

an extender;

a defoamer;

a surfactant;

a thickener; and

an activator.

4. The composition of claim 1 wherein component A comprises 60-75 weight % gypsum based on a total weight of the component A.

5. The composition of claim 1 wherein

component A comprises:

60-75 weight % gypsum;

0.1-3 weight % inhibitor;

10-30% polymer binder; and

0-14.9 weight % component A additives selected from the group consisting of a defoamer, a surfactant, a pH adjuster, and combinations thereof; and

component B comprises:

5-50 weight % polymer binder;

1-15 weight % accelerator; and

35-94 weight % component B additives selected from the group consisting of an extender, a defoamer, a surfactant, a thickener, an activator, and combinations thereof.

6. The composition of claim 1 further comprising a colorant.

7. The composition of claim 1 wherein the gypsum comprises calcium sulfate hemihydrate, the inhibitor comprises aqueous polycarboxylate, the polymer binder comprises an acrylic copolymer, and the accelerator comprises aluminum sulfate.

8. The composition of claim 2 wherein the defoamer comprises a polysiloxane, the surfactant comprises a nonionic surfactant, and the pH adjuster comprises calcium hydroxide.

9. The composition of claim 3 wherein the polymeric binder comprises an acrylic copolymer, the extender comprises alumina trihydrate, the defoamer comprises polysiloxane, the surfactant comprises a nonionic surfactant, the thickener comprises hydroxyethyl cellulose, and the activator comprise aluminum sulfate.

10. A composition for forming a composite material comprising a mixture of component A and component B,

component A comprising:

gypsum; and

an inhibitor; and

component B comprising:

an accelerator;

wherein at least one of component A and component B further comprises a polymer binder and wherein a Shore D hardness of the composite material when cured is less than 70.

11. The composition of claim 10 wherein component A further comprises:

a defoamer;

a surfactant; and

a pH adjuster; and

component B further comprises:

an extender;

a defoamer;

a surfactant;

a thickener; and

an activator.

12. The composition of claim 10 wherein the Shore D hardness is 50-70.

13. A method of forming a composite material with a polymer binder having a T g below −23° C. comprising:

providing a first slurry mixture of gypsum and an inhibitor and a second slurry mixture of at least an accelerator, at least one of the first slurry mixture and the second slurry mixture comprising a predominantly acrylic aqueous emulsion polymer binder; and

blending the first slurry mixture and the second slurry mixture to form a soft composite using a weight ration of from 10:1 to 1:2.

14. The method of claim 13 further comprising: mixing the soft composite with a hard composite material.

15. The composition of claim 1 wherein the polymeric binder is has a Tg of −35° C. to −60° C.

16. The composition of claim 1 wherein the predominantly acrylic aqueous emulsion polymer is a styrene/acrylic polymer.

17. The composition of claim 1 wherein the predominantly acrylic aqueous emulsion polymer is an all-acrylic polymer.

18. The composition of claim 1 wherein the composite material exhibits a Shore D hardness of about 50 to about 60.

19. A composition for forming a composite material comprising a mixture of component A and component B, wherein

component A comprises:

60-75 weight % gypsum;

0.1-3 weight % inhibitor;

10-30% polymer binder; and

0-14.9 weight % component A additives selected from the group consisting of a defoamer, a surfactant, a pH adjuster, and combinations thereof; and

component B comprises:

5-50 weight % polymer binder;

1-15 weight % accelerator; and

35-94 weight % component B additives selected from the group consisting of an extender, a defoamer, a surfactant, a thickener, an activator, and combinations thereof;

wherein the polymeric binder of at least one of component A and component B is a predominantly acrylic aqueous emulsion polymer having a T g of below −23° C., wherein the polymer comprises greater than 50%, by weight, of copolymerized units deriving from (meth)acrylic comonomers selected from the group consisting of(meth)acrylate esters, (meth)acrylamides, meth)acrylonitrile), (meth)acrylic acid, and combinations thereof; and

wherein the composite material exhibits a Shore D hardness when cured of less than 70.

20. The composition of claim 19 , wherein the polymer binder of component A has a T g of −35° C. to −60° C., is an all-crylic or styrene/acrylic polymer, and wherein the composite material exhibits a Shore D hardness when cured of about 50 to about 60.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 16, 2009
From: BOWE, MICHAEL DAMIAN; STONE, WILLIAM IVOR
To: ROHM AND HAAS COMPANY
Reel/Frame 023526/0135 →
Continuity (2)
Provisional Application 6060449000 · Aug 25, 2004
Related Publication 20060042519A1 · Mar 2, 2006