Method for producing composite of aluminum alloy and thermoplastic resin
The present invention is useful for achieving a reduction in weight and for attaining increased strength in not only electronic devices and domestic electric devices but also various parts and structures. As a pretreatment, a rib ( 3 ) is dipped in an aqueous solution of ammonia, hydrazine, a hydrazine derivative, or a water-soluble amine compound. A metal frame ( 2 ) is inserted into an injection mold for forming ribs ( 3 ) by injection molding. A thermoplastic resin composition is injected to the surface of the metal frame ( 2 ) by injection molding to form ribs ( 3 ). In the housing of a casing cover ( 1 ) thus formed, the metal frame ( 2 ) and the ribs ( 3 ) made of the thermoplastic resin composition are integrally bonded together. Thus, the housing improves strength and external appearance. Moreover, a complicated configuration and structure can be formed in the housing.
1. A method for producing a composite of an aluminum alloy and a thermoplastic resin, comprising:
providing a shaped aluminum alloy material having a surface;
treating the surface with an aqueous solution comprising a compound selected from the group consisting of ammonia, hydrazine, a hydrazine derivative, and a water soluble amine compound, in a concentration of 2 to 30%, and at a dipping time of from several minutes to 30 minutes at a temperature in the range of room temperature to 60° C.; and
molding a thermoplastic resin directly on the treated surface of the shaped aluminum alloy by injection molding, wherein the thermoplastic resin is made of one selected from the group consisting of a polyalkylene terephthalate, a copolymer consisting essentially of a polyalkylene terephthalate, and a thermoplastic resin composition containing a polyalkylene terephthalate as a component.
2. The method according to claim 1 , wherein said thermoplastic resin is polybutylene terephthalate.
3. The method according to claim 2 , wherein said polybutylene terephthalate is selected from the group consisting of polybutylene terephthalate, a polymer compound of polybutylene terephthalate and polycarbonate, a polymer compound of polybutylene terephthalate and acrylonitrile-butadiene-styrene resin, a polymer compound of polybutylene terephthalate and polyethylene terephthalate, and a polymer compound of polybutylene terephthalate and polystyrene.
4. The method according to claim 1 , further comprising:
dipping said shaped aluminum alloy material in a basic aqueous solution, before treating the surface.
5. The method according to claim 4 , wherein said basic aqueous solution is an aqueous solution of an alkali metal hydroxide.
6. The method according to claim 4 , further comprising:
neutralizing said dipped shaped aluminum alloy material in an acid aqueous solution.
7. The method according to claim 6 , wherein said thermoplastic polymer includes a high-strength fiber.
8. The method according to claim 7 , wherein said high-strength fiber comprises at least one selected from the group consisting of glass fiber, carbon fiber, and aramid fiber.
9. The method according claim 1 , further comprising dipping said shaped aluminum alloy material in an aqueous solution of a water-soluble reducing agent.
10. The method according to claim 1 , wherein the compound is ammonia.
11. The method according to claim 1 , wherein the compound is hydrazine.
12. The method according to claim 1 , wherein the compound is a water-soluble amine compound.
13. The method according to claim 12 , wherein the water-soluble amine compound is selected from the group consisting of methylamine, dimethylamine, trimethylamine, ethylamine, diethylamine, triethylamine, ethylene diamine, ethanol amine, mono-ethanol amine, aryl amine, and diethanol amine.
14. The method according to claim 1 , wherein the temperature of treating the surface with an aqueous solution is in the range of from 25 to 60 C.
15. A method for producing a composite of an aluminum alloy and a thermoplastic resin, comprising:
providing a shaped aluminum alloy material having a surface;
treating the surface with an aqueous solution comprising a compound selected from the group consisting of ammonia, hydrazine, a hydrazine derivative, and a water soluble amine compound, in a concentration of 2 to 30%, and at a temperature in the range of room temperature to 60 C; and
molding a thermoplastic resin directly on the treated surface of the shaped aluminum alloy by injection molding, wherein the thermoplastic resin is made of one selected from the group consisting of a polyalkylene terephthalate, a copolymer consisting essentially of a polyalkylene terephthalate, and a thermoplastic resin composition containing a polyalkylene terephthalate as a component.