Processes for treating aluminium dross residues
There is provided a process for preparing aluminium chloride comprising: leaching aluminium dross residues with HCl so as to obtain a mixture comprising a solid and a liquid; and hydrochlorinating the liquid obtained from the mixture, so as to form a precipitate comprising aluminium chloride. Such a sequence can also be used for preparing alumina. In such a case, the process can further comprise the step of converting the so-obtained aluminium chloride into alumina. In the processes previously defined, the solid so-obtained can also be leached with H 2 SO 4 , thereby generating a leachate. The leachate can also eventually be hydrochlorinated so as to increase the yield of the desired product obtained i.e. alumina or aluminium chloride.
1. A process for treating aluminium dross residues comprising:
leaching aluminium dross residues with HCl so as to convert a portion of the Al atoms contained in said aluminium dross residues into aluminium chloride solubilized in a liquid and to obtain a mixture comprising a solid and said liquid, and separating said liquid from said solid;
leaching said solid with H 2 SO 4 so as to convert a portion of the Al atoms contained in said solid into aluminium sulphates and to obtain a mixture comprising another solid containing aluminium sulphates and another liquid, and separating said another solid from said another liquid;
solubilizing in water at least a portion of said aluminium sulphates contained in said another solid so as to obtain a leachate; and
hydrochlorinating said liquid and said leachate, thereby forming a precipitate comprising aluminium chloride.
2. The process of claim 1 , wherein the leaching of said dross residues with HCl is carried out at a temperature of about 20° C. to about 140° C.
3. The process of claim 1 , wherein the leaching of said dross residues with HCl is carried out at a temperature of about 40° C. to about 120° C.
4. The process of claim 1 , wherein the leaching of said dross residues is carried out by using a HCl solution having a concentration of about 10 to about 37%.
5. The process of claim 1 , wherein said at least a portion of aluminium sulphates is solubilized in water having a temperature of at least 60° C.
6. The process of claim 5 , wherein said liquid and said leachate are mixed together and are then hydrochlorinated.
7. The process of claim 6 , wherein said liquid and said leachate are hydrochlorinated with gaseous HCl.
8. The process of claim 1 , wherein the leaching of said solid with H 2 SO 4 is carried out at a temperature of about 20° C. to about 325° C.
9. The process of claim 1 , wherein the leaching of said solid with H 2 SO 4 is carried out at a temperature of about 60° C. to about 300° C.
10. The process of claim 1 , wherein the leaching of said solid is carried out by using a H 2 SO 4 solution having a concentration of about 50 to about 98%.
11. The process of claim 9 , wherein the leaching of said solid is carried out by using a H 2 SO 4 solution having a concentration of about 70 to about 98%.
12. The process of claim 1 , wherein the hydrochlorination is carried out at a temperature of about −10° C. to about 20° C.
13. The process of claim 1 , wherein the hydrochlorination is carried out at a temperature of about −5° C. to about 10° C.
14. The process of claim 1 , wherein in the hydrochlorination, at least 60% by weight of the Al atoms contained in the aluminium dross residues are converted into aluminium chloride.
15. The process of claim 13 , wherein in the hydrochlorination about 85 to about 95% by weight of the Al atoms contained in the aluminium dross residues are converted into aluminium chloride.
16. The process of claim 1 , wherein during said process at least 80% by weight of the Al atoms contained in the aluminium dross residues are extracted therefrom.
17. The process of claim 1 , wherein said dross residues comprise alumina, aluminium metal, spinel (MgAl 2 O 4 ), diaoyudaoite (NaAl 11 O 17 ), and gibbsite (Al(OH) 3 ); alumina, aluminium, aluminium nitride, sodium oxide and magnesium oxide; or mixtures thereof.
18. A process for preparing alumina comprising:
leaching aluminium dross residues with HCl so as to convert a portion of the Al atoms contained in said aluminium dross residues into aluminium chloride solubilized in a liquid and to obtain a mixture comprising a solid and said liquid, and separating said liquid from said solid;
leaching said solid with H 2 SO 4 at a temperature of about 20° C. to about 325° C. so as to convert a portion of the Al atoms contained in said solid into aluminium sulphates and to obtain a mixture comprising another solid containing aluminium sulphates and another liquid, and separating said another solid from said another liquid;
solubilizing in water at least a portion of said aluminium sulphates contained in said another solid so as to obtain a leachate;
hydrochlorinating said liquid and said leachate, thereby forming a precipitate comprising aluminium chloride; and
converting said aluminium chloride into alumina.
19. The process of claim 18 , wherein the conversion from aluminium chloride to alumina is carried out at a temperature of about 100° C. to about 1400° C.
20. The process of claim 18 , wherein the conversion from aluminium chloride to alumina is carried out at a temperature of about 200° C. to about 1300° C.
21. The process of claim 18 , wherein in the conversion from aluminium chloride to alumina, at least 50% by weight of the Al atoms contained in the aluminium dross residues are thereby obtained in the form of alumina.
22. The process of claim 18 , wherein in the conversion from aluminium chloride to alumina, about 80 to about 95% by weight of the Al atoms contained in the aluminium dross residues are thereby obtained in the form of alumina.
23. The process of claim 18 , wherein the alumina obtained has a purity of at least 90%.
24. A process for preparing alumina comprising:
leaching aluminium dross residues with HCl so as to convert a portion of the Al atoms contained in said aluminium dross residues into aluminium chloride solubilized in a liquid and to obtain a mixture comprising a solid and said liquid, and separating said liquid from said solid;
leaching said solid with H 2 SO 4 so as to convert a portion of the Al atoms contained in said solid into aluminium sulphates and to obtain a mixture comprising another solid containing aluminium sulphates and another liquid, and separating said another solid from said another liquid;
solubilizing in water at least a portion of said aluminium sulphates contained in said another solid so as to obtain a leachate; and
hydrochlorinating said liquid and said leachate, thereby forming a precipitate comprising aluminium chloride; and
converting said aluminium chloride into alumina.