Ethylene (co) polymer and its use
An ethylene (co)polymer of the present invention is a (co)polymer with excellent moldability and mechanical properties and either an ethylene homopolymer or a copolymer of ethylene and an α-olefin of 4 to 20 carbon atoms. The (co)polymer has methyl branches measured by 13 C-NMR less than 0.1 in number per 1,000 carbon atoms and Mw/Mn measured by GPC not lower than 1.8 and lower than 4.5. The (co)polymer is either an ethylene homopolymer or a copolymer of ethylene and an α-olefin of 3 to 20 carbon atoms. The melt tension (MT) and the swell ratio (SR) satisfy the relation; log(MT)>12.9−7.15×SR; and the intrinsic viscosity ([η]) and the melt flow rate (MFR) satisfy the relation; [η]>1.85×MFR −0.192 in the case of MFR<1 and the relation; [η]>1.85×MFR −0.213 in the case of MFR≧1. Such an ethylene (co)polymer can be usable for various molding applications and especially suitable for pipes.
1. An ethylene (co)polymer composition (C3-1) comprising:
an ethylene (co)polymer (A3) being either an ethylene homopolymer or a copolymer of ethylene and an α-olefin of 3 to 20 carbon atoms, wherein
(i A3 ) the melt tension (MT (g)) at 190° C. and the swell ratio (SR) calculated from the strand diameter extruded at 190° C. satisfy the relation;
log(MT)>12.9−7.15×SR,
(ii A3 ) the intrinsic viscosity ([η] (dl/g)) measured at 135° C. in decalin and the melt flow rate (MFR (g/10 minutes)) measured under 2.16 kg load at 190° C. satisfy the relations;
[η]>1.85×MFR −0.192 in the case of MFR<1 and
[η]>1.85×MFR −0.213 in the case of MFR≧1, and
(iv A3 ) the number average molecular weight (Mn), the weight average molecular weight (Mw), and the Z average molecular weight (Mz) measured by gel permeation chromatography satisfy the relations;
Mz/Mw≧ 7/(1−5.5/( Mw/Mn )), and
Mw/Mn> 5.5;
and another un-modified polymer (B3).
2. The ethylene (co)polymer composition (C3-1) according to claim 1 , wherein the ethylene (co)polymer (A3) has a feature of
(iii A3 ) the weight average molecular weight (Mw) measured by gel permeation chromatography and the swell ratio (SR) calculated from the strand diameter extruded at 190° C. satisfy the relation;
SR>4.55−0.56×log( Mw ).
3. The ethylene (co)polymer composition (C3-1) according to claim 1 or 2 , wherein the ethylene (co)polymer (A3) has a feature of
(v A3 ) the number of the vinyl groups at the molecular terminals calculated by conversion to that per one molecular chain having the same molecular weight as the number average molecular weight is not lower than 0.50.
4. The ethylene (co)polymer composition (C3-1) according to claim 1 or 2 , wherein the ethylene (co)polymer (A3) is an ethylene homopolymer or a copolymer of ethylene and an α-olefin of 4 to 20 carbon atoms and has methyl branches measured by 13 C-NMR less than 0.1 in number per 1,000 of carbon atoms.
5. The ethylene (co)polymer composition (C3-1) according to claim 1 , wherein said another polymer (B3) is an ethylene (co)polymer (B3-1) other than an ethylene (co)polymer (A3), further wherein (B3-1) does not satisfy at least one of the foregoing requirements (i A3 ) and (ii A3 ) which the ethylene (co)polymer (A3) satisfies.