Fibers made from copolymers of ethylene/α-olefins
A fiber is obtainable from or comprises an ethylene/α-olefin interpolymer characterized by an elastic recovery, Re, in percent at 300 percent strain and 1 cycle and a density, d, in grams/cubic centimeter, wherein the elastic recovery and the density satisfy the following relationship: Re>1481−1629(d). Such interpolymer can also be characterized by other properties. The fibers made therefrom have a relatively high elastic recovery and a relatively low coefficient of friction. The fibers can be cross-linked, if desired. Woven or non-woven fabrics can be made from such fibers.
1. A fiber obtainable from or comprising at least one ethylene/α-olefin multi-block interpolymer, wherein the ethylene/α-olefin interpolymer is characterized by one or more of the following properties:
(a) a Mw/Mn from about 1.7 to about 3.5, at least one melting point, Tm, in degrees Celsius, and a density, d, in grams/cubic centimeter, wherein the numerical values of Tm and d correspond to the relationship:
T m >−2002.9+4538.5( d )−2422.2( d ) 2 ; or
(b) a Mw/Mn from about 1.7 to about 3.5, and a heat of fusion, ΔH in J/g, and a delta quantity, ΔT, in degrees Celsius defined as the temperature difference between the tallest DSC peak and the tallest CRYSTAF peak, wherein the numerical values of ΔT and ΔH have the following relationships:
Δ T>− 0.1299(Δ H )+62.81 for Δ H greater than zero and up to 130 J/g,
Δ T≧ 48° C. for Δ H greater than 130 J/g,
wherein the CRYSTAF peak is determined using at least 5 percent of the polymer, and if less than 5 percent of the polymer has an identifiable CRYSTAF peak, then the CRYSTAF temperature is 30° C.; or
(c) an elastic recovery, Re, in percent at 300 percent strain and 1 cycle measured with a compression-molded film of the ethylene/α-olefin interpolymer, and a density, d, in grams/cubic centimeter, wherein the numerical values of Re and d satisfy the following relationship when the ethylene/α-olefin interpolymer is substantially free of a cross-linked phase:
Re> 1481−1629( d ); or
(d) a molecular fraction which elutes between 40° C. and 130° C. when fractionated using TREF, characterized in that the fraction has a molar comonomer content of at least 5 percent higher than that of a comparable random ethylene interpolymer fraction eluting between the same temperatures, wherein said comparable random ethylene interpolymer comprises the same comonomer(s) and has a melt index, density, and molar comonomer content (based on the whole polymer) within 10 percent of that of the ethylene/α-olefin interpolymer, wherein the fiber is not cross-linked.
2. The fiber of claim 1 , wherein the ethylene/α-olefin interpolymer is characterized by an elastic recovery, R e , in percent at 300 percent strain and 1 cycle measured from a compression-molded film of the ethylene/α-olefin interpolymer and a density, d, in grams/cubic centimeter, wherein the elastic recovery and the density satisfy the following relationship when the ethylene/α-olefin interpolymer is substantially free of a cross-linked phase:
R e >1481−1629( d ).
3. The fiber of claim 1 , wherein the ethylene/α-olefin interpolymer has at least one melting point, T m , in degrees Celsius and density, d, in grams/cubic centimeter, wherein the numerical values of the variables correspond to the relationship:
T m >−2002.9+4538.5( d )−2422.2( d ) 2
and wherein the interpolymer has a M w /M n from about 1.7 to about 3.5.
4. The fiber of claim 1 , wherein the ethylene/α-olefin interpolymer has a M w /M n from about 1.7 to about 3.5, and the interpolymer is characterized by a heat of fusion, ΔH, in J/g, and a delta quantity, ΔT, in degree Celsius defined as the difference between the tallest DSC peak minus the tallest CRYSTAF peak, the ΔT and ΔH meet the following relationships:
Δ T>− 0.1299(Δ H )+62.81, for Δ H greater than zero and up to 130 J/g, or
Δ T≧ 48° C., for Δ H greater than 130 J/g,
wherein the CRYSTAF peak is determined using at least 5 percent of the polymer, and if less than 5 percent of the polymer has an identifiable CRYSTAF peak, then the CRYSTAF temperature is 30° C.
5. The fiber of claim 1 , wherein the α-olefin is styrene, propylene, 1-butene, 1-hexene, 1-octene, 4-methyl-1-pentene, 1-decene, or a combination thereof.
6. The fiber of claim 1 , wherein the ethylene/α-olefin interpolymer is blended with another polymer.
7. The fiber of claim 1 , wherein the fiber is a bicomponent fiber.
8. The fiber of claim 1 , wherein the fiber has coefficient of friction of less than about 1.2, wherein the interpolymer is not mixed with any filler.
9. A fabric comprising the fiber of claim 1 .
10. The fabric of claim 9 , wherein the fabric is a nonwoven sheet comprising fibers made by solution spinning.
11. The fabric of claim 9 , wherein the fabric is elastic.
12. The fabric of claim 9 , wherein the fabric is woven.
13. The fabric of claim 9 , wherein the fabric has an MD percent recovery of at least 50 percent at 100 percent strain.
14. A yarn comprising the fiber of claim 1 .
15. The yarn of claim 14 , wherein the yarn is covered.
16. The yarn of claim 15 , where the yarn is covered by cotton yarns or nylon yarns.
17. A soft polymeric flash-spun plexifilamentary material comprising at least one ethylene/α-olefin multi-block interpolymer, wherein the ethylene/α-olefin interpolymer is characterized by one or more of the following properties:
(a) a Mw/Mn from about 1.7 to about 3.5, at least one melting point, Tm, in degrees Celsius, and a density, d, in grams/cubic centimeter, wherein the numerical values of Tm and d correspond to the relationship:
Tm >−2002.9+4538.5( d )−2422.2( d ) 2 ; or
(b) a Mw/Mn from about 1.7 to about 3.5, and a heat of fusion, ΔH in J/g, and a delta quantity, ΔT, in degrees Celsius defined as the temperature difference between the tallest DSC peak and the tallest CRYSTAF peak, wherein the numerical values of ΔT and ΔH have the following relationships:
Δ T>− 0.1299(Δ H )+62.81 for Δ H greater than zero and up to 130 J/g,
Δ T≧ 48° C. for Δ H greater than 130 J/g,
wherein the CRYSTAF peak is determined using at least 5 percent of the polymer, and if less than 5 percent of the polymer has an identifiable CRYSTAF peak, then the CRYSTAF temperature is 30° C.; or
(c) an elastic recovery, Re, in percent at 300 percent strain and 1 cycle measured with a compression-molded film of the ethylene/α-olefin interpolymer, and a density, d, in grams/cubic centimeter, wherein the numerical values of Re and d satisfy the following relationship when the ethylene/α-olefin interpolymer is substantially free of a cross-linked phase:
Re> 1481−1629( d ); or
(d) a molecular fraction which elutes between 40° C. and 130° C. when fractionated using TREF, characterized in that the fraction has a molar comonomer content of at least 5 percent higher than that of a comparable random ethylene interpolymer fraction eluting between the same temperatures, wherein said comparable random ethylene interpolymer comprises the same comonomer(s) and has a melt index, density, and molar comonomer content (based on the whole polymer) within 10 percent of that of the ethylene/α-olefin interpolymer.
18. The polymeric flash-spun plexifilamentary material of claim 17 wherein the ethylene/α-olefin interpolymer has a density of from about 0.85 g/cc to about 0.95 g/cc and a melt index of from about 0.1 g/10 mm to about 50 g/10 mm.