IP Library › Granted Patent US 7,803,888
Granted Patent B2
US 7,803,888 · App. 11/628,640 · Granted Sep 28, 2010

Olefin-based polymers and uses thereof

Assignee: Mitsui Chemicals, Inc.
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Quick Facts
Patent No.
US 7,803,888
App. No.
11/628,640
Granted
Sep 28, 2010
Kind
B2
Abstract

A novel olefin-based polymer has excellent thermal resistance, as well as excellent balance among various properties. The olefin-based polymer is an olefin-based polymer comprising 50 to 100% by weight of a constituent unit derived from 4-methyl-1-pentene, and 0 to 50% by weight of a constituent unit derived from at least one olefin selected from olefins having 2 to 20 carbon atoms except 4-methyl-1-pentene, and having the following properties: i) the diad isotacticity is 70% or greater, ii) the ratio (Mw/Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) as measured by gel permeation chromatography (GPC) is in the range of 1.0 to 3.5, and iii) the intrinsic viscosity [η] is 0.5 (dl/g) or greater.

Claims (41)

1. A 4-methyl-1-pentene-based polymer comprising

50 to 100% by weight of a constituent unit derived from 4-methyl-1-pentene, and 0 to 50% by weight of a constituent unit derived from at least one olefin selected from olefins having 2 to 20 carbon atoms except 4-methyl-1-pentene, and having the following properties:

i) the diad isotacticity is 70% or greater;

ii) the ratio (Mw/Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) as measured by gel permeation chromatography (GPC) is in the range of 1.0 to 3.5; and

iii) the intrinsic viscosity [η] is 1.2 (dl/g) or greater.

2. A 4-methyl-1-pentene-based copolymer comprising

50 to 99.9% by weight of a constituent unit derived from 4-methyl-1-pentene, and 0.1 to 50% by weight of a constituent unit derived from at least one olefin selected from olefins having 2 to 20 carbon atoms except 4-methyl-1-pentene, and having the following properties:

i) the diad isotacticity is 70% or greater;

ii) the ratio (Mw/Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) as measured by gel permeation chromatography (GPC) is in the range of 1.0 to 3.5; and

iii) the intrinsic viscosity [η] is 1.2 (dl/g) or greater.

3. An olefin-based polymer A comprising

90 to 100% by weight of a constituent unit derived from 4-methyl-1-pentene, and 0 to 10% by weight of a constituent unit derived from at least one olefin selected from olefins having 2 to 20 carbon atoms except 4-methyl-1-pentene, and having the following properties:

i) the diad isotacticity is 70% or greater;

ii) the melting point (Tm) measured by DSC is 225° C. or higher;

iii) the ratio (Mw/Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) as measured by gel permeation chromatography (GPC) is in the range of 1.0 to 3.5; and

iv) the proportion of the decane-soluble fraction is 1% by weight or less.

4. An olefin-based polymer B comprising

50 to 99% by weight of a constituent unit derived from 4-methyl-1-pentene, and 1 to 50% by weight of a constituent unit derived from at least one olefin selected from olefins having 2 to 20 carbon atoms except 4-methyl-1-pentene, and having the following properties:

i) the diad isotacticity is 70% or greater;

ii) the melting point (Tm) measured by DSC is below 220° C. or unrecognizable;

iii) the ratio (Mw/Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) as measured by gel permeation chromatography (GPC) is in the range of 1.0 to 3.5; and

iv) the intrinsic viscosity [η] is 1.5 (dl/g) or greater.

5. A 4-methyl-1-pentene homopolymer having the following properties:

i) the diad isotacticity is 70% or greater;

ii) the melting point (Tm) measured by DSC is 230° C. or higher;

iii) the ratio (Mw/Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) as measured by gel permeation chromatography (GPC) is in the range of 1.0 to 3.5; and

iv) the intrinsic viscosity [η] is 1.2 (dl/g) or greater.

6. A 4-methyl-1-pentene-based elastomer comprising

50 to 90% by weight of a constituent unit derived from 4-methyl-1-pentene, and 10 to 50% by weight of a constituent unit derived from at least one olefin selected from olefins having 2 to 20 carbon atoms except 4-methyl-1-pentene, and having the following properties:

i) the diad isotacticity is 70% or greater;

ii) the ratio (Mw/Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) as measured by gel permeation chromatography (GPC) is in the range of 1.0 to 3.5; and

iii) the intrinsic viscosity [η] is 1.2 (dl/g) or greater.

7. A method for preparing the polymer or elastomer according to claim 1 , comprising reacting the 4-methyl-1-pentene and the olefin, if present, in the presence of a metallocene catalyst represented by the following Formula (1) or Formula (2):

wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 , R 12 , R 13 and R 14 , which may be identical or different, are each selected from hydrogen, a hydrocarbon group and a silicon-containing hydrocarbon group; the neighboring substituents from R 1 to R 4 may be bound to each other to form a ring, and the neighboring substituents from R 5 to R 12 may be bound to each other to form a ring; A is a divalent hydrocarbon group having 2 to 20 carbon atoms, which may contain some unsaturated bonds and/or aromatic rings, and A may contain two or more cyclic structures including the ring formed by A together with Y; M is a metal selected from Group 4 of the Periodic Table of Elements; Y is carbon or silicon; Q is selected from halogen, a hydrocarbon group, an anionic ligand, and a neutral ligand which is capable of coordination with an electron lone pair and may be of identical or different combination; and j is an integer from 1 to 4.

8. An injection molded article comprising the polymer or elastomer according to claim 1 .

9. A film or sheet comprising the polymer or elastomer according to claim 1 .

10. A fiber comprising the polymer or elastomer according to claim 1 .

11. A blow molded vessel comprising the polymer or elastomer according to claim 1 .

12. A release film comprising the polymer or elastomer according to claim 1 .

13. A non-woven fabric comprising the polymer or elastomer according to claim 1 .

14. A damping material comprising the polymer or elastomer according to claim 1 .

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 6, 2006
From: KAWAHARA, NOBUO; KOJOH, SHINICHI; MATSUO, SHINGO; KANEKO, HIDEYUKI; MATSUGI, TOMOAKI; KASHIWA, NORIO; FUNAYA, MUNEHITO; HIROTA, NARITOSHI; TANAKA, TOORU; HIROSE, TOSHIYUKI; MIKAWA, NOBUHISA; KIZU, KOUICHI; OKADA, KEIJI
To: MITSUI CHEMICALS, INC.
Reel/Frame 018699/0861 →
Priority Claims (2)
JP 2004-172717 · Jun 10, 2004 · national
JP 2004-325057 · Nov 9, 2004 · national
Continuity (1)
Related Publication 20070249792A1 · Oct 25, 2007