IP Library › Granted Patent US 7,811,886
Granted Patent B2
US 7,811,886 · App. 11/671,809 · Granted Oct 12, 2010

Split-gate thin film storage NVM cell with reduced load-up/trap-up effects

Assignee: Freescale Semiconductor, Inc.
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Quick Facts
Patent No.
US 7,811,886
App. No.
11/671,809
Granted
Oct 12, 2010
Kind
B2
Abstract

A semiconductor process and apparatus are disclosed for forming a split-gate thin film storage NVM device ( 10 ) by forming a select gate structure ( 3 ) on a first dielectric layer ( 2 ) over a substrate ( 1 ); forming a control gate structure ( 6 ) on a second dielectric layer ( 5 ) having embedded nanocrystals ( 15, 16 ) so that the control gate ( 6 ) is adjacent to the select gate structure ( 3 ) but separated therefrom by a gap ( 8 ); forming a floating doped region ( 4 ) in the substrate ( 1 ) below the gap ( 8 ) formed between the select gate structure and control gate structure; and forming source/drain regions ( 11, 12 ) in the substrate to define a channel region that includes the floating doped region ( 4 ).

Claims (45)

1. A method for forming a semiconductor device comprising:

forming a first gate structure on a first dielectric layer over a substrate;

forming a second gate structure on a second dielectric layer over the substrate so that the second gate structure is adjacent to the first gate structure but separated from the first gate structure by a gap formed between the first gate structure and second gate structure, where the second dielectric layer comprises a plurality of nanocrystals;

forming a floating doped region in the substrate below the gap formed between the first gate structure and second gate structure; and

forming first and second source/drain regions in the substrate adjacent to the first gate structure and second gate structure, said first and second source/drain regions defining a channel region that includes the floating doped region.

2. The method of claim 1 , where forming a floating doped region comprises:

implanting ions having a first predetermined conductivity type around the first gate structure before the second gate structure is formed, thereby forming a first implant region in the substrate that is adjacent to the first gate structure;

forming a first spacer structure on a sidewall of the first gate structure to mask a first portion of the first implant region that is adjacent to the first gate structure; and

implanting ions having a second opposite conductivity type around the first spacer structure and into the first implant region before the second gate structure is formed, thereby forming the floating doped region from the first portion of the first implant region that has not been implanted with the ions having the second opposite conductivity type.

3. The method of claim 1 , where forming a floating doped region comprises:

using a vertical implant process to selectively implant ions having a first predetermined conductivity type around the first gate structure before the second gate structure is formed, thereby forming a first implant region in the substrate that is adjacent to the first gate structure;

using an angled implant process to selectively implant ions having a second opposite conductivity type around the first gate structure and into the first implant region before the second gate structure is formed, where the first gate structure masks a first portion of the first implant region that is adjacent to the first gate structure, thereby forming the floating doped region from the first portion of the first implant region that has not been implanted with the ions having the second opposite conductivity type.

4. The method of claim 1 , where forming a floating doped region comprises:

forming a solid source spacer structure on a sidewall of the first gate structure and in contact with the substrate area adjacent to the first gate structure before the second gate structure is formed, where the solid source spacer structure comprises dopants of a predetermined conductivity type;

annealing the solid source spacer structure to drive dopants from the solid source spacer structure into the substrate before the second gate structure is formed, thereby forming the floating doped region in the substrate adjacent to the first gate structure.

5. The method of claim 1 , where forming a floating doped region comprises:

removing a portion of a gap dielectric layer formed in the gap that separates the first gate structure and second gate structure, thereby forming a remnant dielectric layer in the gap while leaving the first gate structure and second gate structure substantially intact; and

implanting ions having a first predetermined conductivity type through the remnant dielectric layer in the gap, thereby forming the floating doped region in the substrate below the gap formed between the first gate structure and second gate structure.

6. The method of claim 1 , where forming a floating doped region comprises:

selectively removing a portion of the substrate below the gap that separates the first gate structure and second gate structure while leaving the first gate structure and second gate structure substantially intact, thereby forming an opening in the substrate below the gap; and

epitaxially growing a doped semiconductor region selectively in the opening while not growing on the select and second gate structures, thereby forming the floating doped region in the substrate below the gap formed between the first gate structure and second gate structure.

7. The method of claim 1 , where forming a second gate structure comprises:

forming a first spacer structure on a sidewall of the first gate structure before the second gate structure is formed, thereby defining a first portion of the substrate below the first spacer structure;

forming a second dielectric layer comprising a plurality of nanocrystals over the first spacer structure and substrate;

depositing a polysilicon layer over the second dielectric layer; and

anisotropically etching the polysilicon layer to form the second gate structure that is adjacent to the first gate structure but separated from the first gate structure by a gap formed between the first gate structure and second gate structure and containing the first spacer structure and a portion of the second dielectric layer.

8. The method of claim 7 , where forming a floating doped region comprises:

selectively removing the first spacer structure to form an opening between the first gate structure and second gate structure and over the first portion of the substrate while leaving the first gate structure and second gate structure substantially intact; and

implanting ions having a first predetermined conductivity type through the opening and into the first portion of the substrate, thereby forming the floating doped region in the substrate below the gap formed between the first gate structure and second gate structure.

9. The method of claim 8 , further comprising growing a dielectric layer to fill the opening at least in part by oxidizing nanocrystals in the second dielectric layer that are located in the gap formed between the first gate structure and second gate structure.

10. A method for forming a semiconductor non-volatile memory device, comprising:

forming a split-gate structure over a dielectric layer formed on a semiconductor substrate, where the split-gate structure comprises a select gate structure and an adjacent control gate structure that is separated from the select gate structure by a gap;

forming a floating doped region in the semiconductor substrate below the gap during formation of the split-gate structure; and

forming a source/drain region in the semiconductor substrate on first and second sides of the split-gate structure.

11. The method of claim 10 , where the floating doped region reduces electrical influence of gap nanocrystals formed in the gap or in the dielectric layer.

12. The method of claim 10 , where forming a split-gate structure comprises forming the control gate structure before forming the floating doped region and select gate structure.

13. The method of claim 10 , where forming a split-gate structure comprises forming the select gate structure before forming the floating doped region and the control gate structure.

14. The method of claim 10 , where forming a split-gate structure comprises forming the select gate structure and control gate structure before forming the floating doped region.

15. A method for forming a semiconductor non-volatile memory device, comprising:

forming a split-gate structure over a dielectric layer formed on a semiconductor substrate, where the split-gate structure comprises a select gate structure and an adjacent control gate structure that is separated from the select gate structure by a gap;

forming a floating doped region in the semiconductor substrate below the gap which reduces electrical influence in the semiconductor substrate of nanocrystals formed in the gap relative to nanocrystals formed in the dielectric layer under the control gate structure; and

forming a source/drain region in the semiconductor substrate on first and second sides of the split-gate structure.

16. The method of claim 15 , where forming a split-gate structure comprises forming the control gate structure before forming the floating doped region and select gate structure.

17. The method of claim 15 , where forming a split-gate structure comprises forming the select gate structure before forming the floating doped region and the control gate structure.

18. The method of claim 15 , where forming a split-gate structure comprises forming the select gate structure and control gate structure before forming the floating doped region.

Assignments (19)
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040925 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Feb 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V. F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 052917/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040928 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Jan 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 052915/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 037486 FRAME 0517. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Dec 10, 2019
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 053547/0421 →
CORRECTIVE ASSIGNMENT TO CORRECT THE TO CORRECT THE APPLICATION NO. FROM 13,883,290 TO 13,833,290 PREVIOUSLY RECORDED ON REEL 041703 FRAME 0536. ASSIGNOR(S) HEREBY CONFIRMS THE THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS.. Recorded Feb 20, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: SHENZHEN XINGUODU TECHNOLOGY CO., LTD.
Reel/Frame 048734/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE PATENTS 8108266 AND 8062324 AND REPLACE THEM WITH 6108266 AND 8060324 PREVIOUSLY RECORDED ON REEL 037518 FRAME 0292. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Feb 1, 2017
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 041703/0536 →
RELEASE OF SECURITY INTEREST Recorded Nov 7, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 040928/0001 →
RELEASE OF SECURITY INTEREST Recorded Sep 21, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V., F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 040925/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 4, 2016
From: FREESCALE SEMICONDUCTOR, INC.
To: NORTH STAR INNOVATIONS INC.
Reel/Frame 037694/0264 →
ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 13, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 037518/0292 →
ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 12, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 037486/0517 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037356/0553 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037356/0143 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037354/0640 →
SECURITY AGREEMENT Recorded Nov 6, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 031591/0266 →
SECURITY AGREEMENT Recorded Jun 18, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 030633/0424 →
SECURITY AGREEMENT Recorded May 13, 2010
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 024397/0001 →
SECURITY AGREEMENT Recorded Mar 15, 2010
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A.
Reel/Frame 024085/0001 →
SECURITY AGREEMENT Recorded Sep 19, 2007
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A.
Reel/Frame 019847/0804 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 6, 2007
From: WINSTEAD, BRIAN A.; KIRICHENKO, TARAS A.; LOIKO, KONSTANTIN V.; MURALIDHAR, RAMACHANDRAN; RAO, RAJESH A.; KANG, SUNG-TAEG; CHANG, KO-MIN; YATER, JANE
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 018859/0536 →
Continuity (1)
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