Wear-resistant coating and process for producing it
A process for producing a wear-resistant coating and to a wear-resistant coating on predetermined surfaces (2) of machine or engine parts (1) consisting of a sintered material which are exposed to frictional wear, for fuel feed units in particular, comprising at least one metal-free amorphous hydrocarbon layer (5) with sp 2 - and sp 3 -hybridized carbon applied to the predetermined surface (2) of the machine or engine part (I) for reducing friction and increasing the wear resistance of the predetermined surface (2) of the machine or engine part (1), and at least one intermediate layer of a metal-containing hydrocarbon layer formed between the predetermined surface of the machine or engine part and the amorphous hydrocarbon layer wherein the metal is a combination of W, Ti, Hf and Ge.
1. A process for producing a wear-resistant coating on predetermined surfaces of machine or engine parts comprising sintered materials which are exposed to frictional wear, in fuel feed units, comprising applying at least one metal-free amorphous hydrocarbon layer with sp 2 - and sp 3 -hybridized carbon to the predetermined surface of a machine or engine part ( 1 ) for reducing friction and increasing the wear resistance of the predetermined surface of the machine or engine part, and at least one intermediate layer of metal-containing hydrocarbon layer formed between the predetermined surface of the machine or engine part and the amorphous hydrocarbon layer wherein the metal is a combination of W, Ti, Hf and Ge.
2. The process of claim 1 , wherein the amorphous hydrocarbon layer is deposited onto the predetermined surface of the machine or engine part by means of a PVD and/or a (PA) CVD process.
3. The process of claim 1 wherein the amorphous hydrocarbon layer is formed with a hydrogen fraction of at most 20 atomic %.
4. The process of claim 1 wherein the amorphous hydrocarbon layer is formed with process-related impurities of less than 1 atomic %.
5. The process of claim 1 wherein the amorphous hydrocarbon layer is formed with a thickness of approximately 1.0 μm to 4.0 μm.
6. The process of claim 1 wherein, before depositing of the amorphous hydrocarbon layer, the predetermined surface of the machine or engine part undergoes cleaning, in various cleaning baths, with a subsequent outgassing operation in a cleaning oven.
7. The process of claim 1 wherein at least one adhesion promoting layer and/or at least one intermediate layer is formed between the predetermined surface of the machine or engine part and the amorphous hydrocarbon layer.
8. The process of claim 7 wherein at least one intermediate layer is formed with a thickness of approximately 0.5 μm to 2.0 μm.
9. The process of claim 7 wherein at least one adhesion promoting layer is formed from at least one member of the group consisting of substances, borides, carbides and nitrides of the transition metals.
10. The process of claim 7 wherein at least one adhesion promoting layer is formed with a thickness of approximately 0.1 μm to 0.5 μm.
11. The process of claim 1 wherein the amorphous hydrocarbon layer at least one intermediate layer and/or at least one adhesion promoting layer are deposited at in each case a coating temperature respectively less than the tempering temperature of the machine or engine part.