Systems and methods of producing a crude product
Contact of a crude feed with one or more catalysts produces a total product that includes a crude product. The crude feed has a residue content of at least 0.2 grams of residue per gram of crude feed. The crude product is a liquid mixture at 25° C. and 0.101 MPa. One or more properties of the crude product may be changed by at least 10% relative to the respective properties of the crude feed. The crude product may include at least one of the catalysts.
1. A crude product comprising, per gram of crude product:
at most 0.05 grams of residue; at least 0.001 grams of hydrocarbons with a boiling range distribution of at most 204° C. (400° F.) at 0.101 MPa, at least 0.001 grams of hydrocarbons with a boiling range distribution between about 204° C. and about 300° C. at 0.101 MPa, at least 0.001 grams of hydrocarbons with a boiling range distribution between about 300° C. and about 400° C. at 0.101 MPa, and at least 0.001 grams of hydrocarbons with a boiling range distribution between about 400° C. and about 538° C. at 0.101 MPa, wherein hydrocarbons having a boiling range distribution between about 30° C. and about 538° C. comprise iso-paraffins and n-paraffins with a weight ratio of iso-paraffins to n-paraffins of at most 1.4; and
greater than 0 grams, but less than 0.01 grams of one or more catalysts including one or more transition metal sulfides, wherein the catalyst(s) contain at most 1 gram of a support material per 100 grams of catalyst, wherein the support material, if present in the catalyst(s), is selected from the group consisting of refractory oxides, zeolites, and porous carbon materials.
2. The crude product of claim 1 , wherein at least one of the catalysts comprises bartonite.
3. The crude product of claim 1 , wherein at least one of the catalysts further comprises an alkaline-earth metal and/or zinc.
4. A method of producing transportation fuel comprising:
processing a crude product, wherein the crude product has:
at most 0.05 grams of residue; at least 0.001 grams of hydrocarbons with a boiling range distribution of at most 204° C. (400° F.) at 0.101 MPa, at least 0.001 grams of hydrocarbons with a boiling range distribution between about 204° C. and about 300° C. at 0.101 MPa, at least 0.001 grams of hydrocarbons with a boiling range distribution between about 300° C. and about 400° C. at 0.101 MPa, and at least 0.001 grams of hydrocarbons with a boiling range distribution between about 400° C. and about 538° C. at 0.101 MPa wherein hydrocarbons having a boiling range distribution between about 30° C. and about 538° C. comprise iso-paraffins and n-paraffins with a weight ratio of iso-paraffins to n-paraffins of at most 1.4; and
greater than 0 grams, but less than 0.01 grams of one or more catalysts including one or more transition metal sulfides, wherein the catalyst(s) contain at most 1 gram of a support material per 100 grams of catalyst, wherein the support material, if present in the catalyst(s), is selected from the group consisting of refractory oxides, zeolites, and porous carbon materials.
5. The method of claim 4 , wherein the processing comprises distilling the crude product into one or more distillate fractions.
6. The method of claim 4 , wherein the processing comprises hydrotreating.