Adhesive-carrying porous film for battery separator and use thereof
The invention provides an adhesive-carrying porous film for use as a battery separator, comprising: a substrate porous film, wherein when a 1 mm diameter penetrating thermomechanical analyzer probe is placed on the film under a 70 g load to measure a thickness while heating the film from room temperature at a rate of 200° C./minute to a temperature where the film thickness decreases by half when the probe was initially placed is 200° C. or more, a partially crosslinked adhesive carried on the film, the adhesive is prepared by reacting a reactive polymer having a functional group capable of reacting with an isocyanate group with a polyfunctional isocyanate so the reactive polymer is partially crosslinked, a porous film is temporarily bonded to an electrode to provide an electrode/separator laminate, the porous film in a battery functions as a separator which does not melt or break with small heat shrinkage under high temperatures.
1. An adhesive-carrying porous film for use as a battery separator, which comprises:
a substrate porous film such that when a probe of a probe penetrating thermomechanical analyzer, said probe having a diameter of 1 mm, is placed on the porous film under a load of 70 g to measure a thickness thereof while heating the porous film from room temperature at a rate of 2° C./minute, a temperature at which the thickness of the porous film decreases to a half of the thickness of the porous film when the probe was initially placed thereon is 200° C. or more; and
a partially crosslinked adhesive carried on the substrate porous film, and having a gel fraction in a range of 5 to 80%, the partially crosslinked adhesive being prepared by carrying on the substrate porous film a reactive polymer having a functional group capable of reacting with a polyfunctional isocyanate and a polyfunctional isocyanate in such a quantity sufficient for the reactive polymer to be partially crosslinked, and then by reacting the reactive polymer with the polyfunctional isocyanate.
2. The adhesive-carrying porous film according to claim 1 , wherein the substrate porous film is prepared from a polyolefin resin composition comprising a polyolefin resin having a weight average molecular weight of at least 500000 and a crosslinked product of a cross-linkable rubber having double bonds in the molecular chain.
3. The adhesive-carrying porous film according to claim 2 , wherein the cross-linkable rubber is an ethylene-propylene-ethylidene norbornene ternary copolymer.
4. The adhesive-carrying porous film according to claim 2 , wherein the cross-linkable rubber is a polynorbornene.
5. An electrode/porous film laminate comprising an electrode press-contacted to the adhesive-carrying porous film according to any one of claims 1 to 4 .
6. An electrode/porous film adherend comprising an electrode bonded to a porous film prepared by reacting a reactive polymer in the electrode/porous film laminate according to claim 5 with a polyfunctional isocyanate and further crosslinking a partially crosslinked adhesive.
7. The adhesive-carrying porous film according to claim 1 , wherein the reactive polymer has carboxyl groups or hydroxyl groups as the functional group capable of reacting with an isocyanate group.