Process for alkaline hydrolysis of carboxylic acid derivatives to carboxylic acids

1. Method for alkaline hydrolysis of carboxylic acid derivatives, wherein the carboxylic acid derivatives are carboxylic esters, to carboxylic acids, comprising

adding red mud produced by a process consisting of the Bayer process used for production of aluminum as the hydroxide ion source, for alkaline hydrolysis of the carboxylic acid derivatives.

2. Method according to claim 1 , characterized by the following steps:

a) mixing the carboxylic acid derivative and the red mud;

b) heating the mixture to a predetermined temperature value and/or mixing the mixture for the duration of a predetermined time at a predetermined pressure; and

c) separating at least a first, liquid component from at least a second, amorphous component.

3. Method according to claim 1 , characterized in that

the carboxylic acid derivative includes at least a carboxylic ester.

4. Method according to claim 3 , characterized in that

the carboxylic ester is a component of a vegetable oil.

5. Method according to claim 2 , characterized in that in step a) and/or b) water is additionally added.

6. Method according to claim 2 , characterized in that step c) includes at least a separating process.

7. Method according to claim 2 , characterized in that

the first component separated in step c) includes at least a carboxylic acid.

8. Method according to claims 2 , characterized in that

the second component separated in step c) includes at least dealkalized red mud.

9. Method according to claim 2 , characterized in that

step c) includes separation of a third component including at least a salt of a carboxylic acid.

10. Method according to claim 2 , characterized in that

after step c), a further step d) is provided, which includes washing and/or extracting the second component with a solvent.

11. Method according to claim 10 , characterized in that

the solvent includes at least hexane.

12. Method according to claim 10 , characterized in that

after step d) another step e) is provided, which includes evaporation and/or recirculation of the solvent after step d).

13. Method according to claim 2 , characterized in that

after step c) and/or optionally d) and/or optionally e), a further step f) is provided, which includes at least partial oxidation and/or reduction, and wherein the at least partial oxidation and/or reduction is controlled combustion of the second component.

14. Method according to claim 13 , characterized in that

an exothermic reaction energy developing in step f) is used for evaporation of a liquid in a further step g).

15. Method according to claim 14 , characterized in that

the vapor generated in step g) is used for heating and/or mixing of the reaction mixture in step b) and/or for generation of energy.

16. Method according to claim 13 , characterized in that

after step f) and/or optionally g) a further step h) is provided, which includes separation and/or division of solid reaction products developed in step f).

17. Method according to claim 16 , characterized in that

step h) includes separation and/or division of hematite and/or magnetite and/or jadeite and/or ilmenite and/or feldspar and/or silicates.

18. The method according to claim 4 , wherein the vegetable oil is a rape oil and/or palm oil and/or soya oil.

19. The method according to claim 6 , wherein the separating process is a decanting process.

20. The method according to claim 7 , wherein the carboxylic acid is a fatty acid.

21. The method according to claim 10 , wherein the solvent is a non-polar solvent.

22. The method according to claim 14 , wherein the liquid is water.

23. The method according to claim 15 , wherein the energy is generated by means of a gas/steam turbine.