Removal of residual sulfur compounds from a caustic stream
A process for the removal of residual sulfur compounds from a liquid caustic stream is disclosed. One embodiment of my invention adsorbs disulfides from a caustic stream using an activated carbon adsorbent while another combines both oxidation and adsorption in single step to remove residual sulfur compounds from a rich caustic stream using metal phthalocyanine supported on a solid adsorbent. This process is especially useful as a polishing step in a caustic regeneration process flow scheme.
1. A process for removing residual sulfur compounds from a caustic feed stream, comprising, in combination,
a) obtaining a caustic feed stream from a lower layer of a gravity separator, wherein caustic entering the gravity separator has been previously oxidized in an oxidization process, and wherein residual sulfur compounds in the caustic feed stream comprise less than 500 weight ppm measured as elemental sulfur;
b) introducing the caustic feed stream of step a) into a polishing unit;
c) introducing an oxidant into the polishing unit;
d) admixing and contacting the caustic feed stream and oxidant within the polishing unit in the presence of a catalyst bed comprising a metal phthalocyanine catalyst supported on a catalyst support;
e) converting mercaptans that are present as part of the sulfur compounds in the caustic feed stream to disulfides;
f) adsorbing on the catalyst support the disulfides formed in step e) and disulfides introduced into the polishing unit as part of the sulfur compounds in the caustic feed stream; and
g) removing from the polishing unit a polished caustic stream product comprising less than 20 weight ppm of sulfur compounds measured as elemental sulfur.
2. The process of claim 1 where the sulfur compounds in the caustic feed stream comprise less than 100 weight ppm measured as elemental sulfur.
3. The process of claim 1 where the sulfur compounds in the caustic feed stream comprise mercaptans and disulfides.
4. The process of claim 3 where the mercaptans comprise less than 50 weight ppm measured as elemental sulfur in the caustic feed stream.
5. The process of claim 1 where the caustic feed stream and oxidant is contacted within the polishing unit with a fixed bed of activated carbon impregnated with metal phthalocyanine.
6. The process of claim 5 where the metal is selected from the group comprising cobalt, iron and mixtures thereof.
7. The process of claim 5 where the activated carbon has a pore volume of 0.5-1.5 cc/g BJH N 2 and/or surface area of 500-2,000 m 2 /g BET.
8. The process of claim 5 where the activated carbon is wood based.
9. The process of claim 1 where the oxidant is air or at least one oxygen-containing gas.
10. The process of claim 1 where at least a portion of the catalyst support adsorbent is subjected to a regeneration process.
11. The process of claim 1 where the sulfur compounds in the polished caustic stream product comprise less than 5 weight ppm measured as elemental sulfur.